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The crystal structure of Fe3O4 below the 122 K Verwey transition has been refined using high-resolution X-ray and neutron powder diffraction data. The refinements give direct evidence for charge ordering (CO) over four independent…

Strongly Correlated Electrons · Physics 2009-11-07 J. P. Wright , J. P. Attfield , P. G. Radaelli

Seeking to unravel the enigmatic Verwey transition and its interplay with magnetism, we have conducted comprehensive measurements on the temperature-dependent electrical resistivity and magnetic moment of stoichiometric and doped-magnetite…

Magnetite (Fe$_{3}$O$_{4}$), an archetypal transition metal oxide, has been used for thousands of years, from lodestones in primitive compasses[1] to a candidate material for magnetoelectronic devices.[2] In 1939 Verwey[3] found that bulk…

Effects of the Verwey transition on the (100) surface of magnetite were studied using scanning tunelling microscopy and spin polarized low-energy electron microsccopy. On cooling through the transition temperature Tv, the initially flat…

A controlled point-like disorder induced by low temperature 2.5 MeV electron irradiation was used to probe the nature of the Verwey transition in magnetite, $\text{Fe}_{3}\text{O}_{4}$. Two large single crystals, one with optimal transition…

Materials Science · Physics 2024-11-28 Ruslan Prozorov , Makariy A. Tanatar , Erik I. Timmons , Marcin Konczykowski , Tanya Prozorov

A thorough investigation of single crystalline magnetite using broadband dielectric spectroscopy and other methods provides evidence for relaxor-like polar order in Fe3O4. We find long-range ferroelectric order to be im-peded by the…

Strongly Correlated Electrons · Physics 2011-06-10 F. Schrettle , S. Krohns , P. Lunkenheimer , V. A. M. Brabers , A. Loidl

We investigated the electronic and vibrational properties of magnetite at temperatures from 300 K down to 10 K and for pressures up to 10 GPa by far-infrared reflectivity measurements. The Verwey transition is manifested by a drastic…

Strongly Correlated Electrons · Physics 2018-02-02 J. Ebad-Allah , L. Baldassarre , M. Sing , R. Claessen , V. A. M. Brabers , C. A. Kuntscher

We have studied the electronic structure and charge ordering (Verwey) transition of magnetite (Fe3O4) by soft x-ray photoemission. Due to the enhanced probing depth and the use of different surface preparations we are able to distinguish…

Strongly Correlated Electrons · Physics 2007-05-23 D. Schrupp , M. Sing , M. Tsunekawa , H. Fujiwara , S. Kasai , A. Sekiyama , S. Suga , T. Muro , V. A. M. Brabers , R. Claessen

We have studied experimentally the responses of high quality single crystals of stoichiometric synthetic magnetite to applied weak dc and ac magnetic fields in the range of 6 K to 60 K, far below the Verwey transition. The results can be…

Strongly Correlated Electrons · Physics 2013-11-12 Zdenek Svindrych , Zdenek Janu , Andrzej Kozlowski , Jurgen M. Honig

The magnetic properties of biologically-produced magnetite nanocrystals biomineralized by four different magnetotactic bacteria were compared to those of synthetic magnetite nanocrystals and large, high quality single crystals. The magnetic…

Motivated by recent structural data questioning the adequacy of the charge order (CO)/disorder picture for the Verwey transition (at T=T_V) in magnetite, we re-investigate this issue within a new theoretical picture. Using the…

Strongly Correlated Electrons · Physics 2007-05-23 L. Craco , M. S. Laad , E. Müller-Hartmann

Using soft-x-ray diffraction at the site-specific resonances in the Fe L23 edge, we find clear evidence for orbital and charge ordering in magnetite below the Verwey transition. The spectra show directly that the (001/2) diffraction peak…

Strongly Correlated Electrons · Physics 2010-01-25 J. Schlappa , C. Schuessler-Langeheine , C. F. Chang , H. Ott , A. Tanaka , Z. Hu , M. W. Haverkort , E. Schierle , E. Weschke , G. Kaindl , L. H. Tjeng

Magnetic and structural properties of magnetite nanoparticles stabilized in polyvinyl-alcohol thin films are investigated by using X-ray diffraction (XRD), transmission electron microscopy (TEM), electron paramagnetic resonance (EPR) and…

Tunneling transport measurements performed on single particles and on arrays of Fe3O4 (magnetite) nanocrystals provide strong evidence for the existence of the Verwey metal-insulator transition at the nanoscale. The resistance measurements…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Pankaj Poddar , Tcipi Fried , Gil Markovich , Amos Sharoni , David Katz , Tommer Wizansky , Oded Millo

We report the results of a low-temperature (300K-15K) high-pressure (up to 22GPa) Raman study of the Verwey transition in magnetite (Fe3O4). We use additional Raman modes observed below the Verwey transition to determine how the transition…

In a recent letter, E. Nazarenko et al [Phys. Rev. Lett. 97, 056403 (2006) and cond-mat/0606596] have investigated the low temperature phase of magnetite by means of resonant X-ray scattering. The paper puts forward the quantitative…

Strongly Correlated Electrons · Physics 2008-02-05 Joaquin Garcia , Gloria Subias , Javier Blasco , Ma Grazia Proietti , Hubert Renevier

We incorporate single crystal Fe$_3$O$_4$ thin films into a gated device structure and demonstrate the ability to control the Verwey transition with static electric fields. The Verwey transition temperature ($T_V$) increases for both…

Strongly Correlated Electrons · Physics 2015-06-04 Jared J. I. Wong , Adrian G. Swartz , Renjing Zheng , Wei Han , Roland K. Kawakami

Neutron powder diffraction and inelastic measurements were performed examining the 5d pyrochlore Y$_2$Ir$_2$O$_7$. Temperature dependent measurements were performed between 3.4 K and 290 K, spanning the magnetic transition at 155 K. No sign…

Strongly Correlated Electrons · Physics 2014-05-30 M. C. Shapiro , S. C. Riggs , M. B. Stone , C. R. de la Cruz , S. Chi , A. A. Podlesnyak , I. R. Fisher

Two-dimensional spin-uncompensated momentum density distributions, $\rho_{\rm s}^{2D}({\bf p})$s, were reconstructed in magnetite at 12K and 300K from several measured directional magnetic Compton profiles. Mechanical de-twinning was used…

Strongly Correlated Electrons · Physics 2009-10-13 H. Kobayashi , T. Nagao , M. Itou , S. Todo , B. Barbiellini , P. E. Mijnarends , A. Bansil , N. Sakai

We report Raman scattering data of single crystals of magnetite (Fe3O4) with Verwey transition temperatures (Tv) of 123 and 117K, respectively. Both single crystals reveal broad electronic background extending up to 900 wavenumbers (~110…

Materials Science · Physics 2013-09-19 L. Gasparov , A. Rush , G. Guntherodt , H. Berger
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