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We investigate the universality of entanglement kinetics in polymer melts. We compare predictions of a recently developed constitutive equation for disentanglement to molecular dynamics simulations of both united-atom polyethylene and…

Soft Condensed Matter · Physics 2024-07-09 Benjamin E. Dolata , Marco A Galvani Cunha , Thomas O'Connor , Austin Hopkins , Peter D. Olmsted

Active matter agents consume internal energy or extract energy from the environment for locomotion and force generation. Already rather generic models, such as ensembles of active Brownian particles, exhibit phenomena, which are absent at…

Soft Condensed Matter · Physics 2020-07-27 Roland G. Winkler , Gerhard Gompper

We study polymer-polymer phase separation in a common good solvent by means of Monte Carlo simulations of the bond-fluctuation model. Below a critical, chain-length dependent concentration, no phase separation occurs. For higher…

Soft Condensed Matter · Physics 2009-11-11 Lei Guo , Erik Luijten

In the modeling of dislocations one is lead naturally to energies concentrated on lines, where the integrand depends on the orientation and on the Burgers vector of the dislocation, which belongs to a discrete lattice. The dislocations may…

Analysis of PDEs · Mathematics 2016-11-14 Sergio Conti , Adriana Garroni , Annalisa Massaccesi

Complex systems having metastable elements often demonstrate nearly log-time relaxations and a kind of aging: repeated stimuli weaken the system's relaxational response. Granular matter is known to exhibit a wealth of such behaviors, for…

Soft Condensed Matter · Physics 2014-06-16 V. Y. Zaitsev , V. E. Gusev , V. Tournat , P. Richard

We develop a simple yet comprehensive nonlinear model to describe relaxation phenomena in amorphous glass-formers near the glass transition temperature. The model is based on the two-state, two-(time)scale (TS2) framework, and describes the…

Soft Condensed Matter · Physics 2024-03-12 Valeriy V. Ginzburg , Oleg V. Gendelman , Alessio Zaccone

We analyze static properties of a strongly confined semiflexible polymer, i.e. either trapped in a closed space or compressed by external forces, in an athermal solvent. Like a flexible polymer case, we can resort to an analogy with the…

Soft Condensed Matter · Physics 2009-11-13 Takahiro Sakaue

Polymers are among the most important materials in the modern society being found almost in every activity of our daily life. Understanding their chemical and physical properties lead to improvements of their usage. The correlation…

Soft Condensed Matter · Physics 2021-02-02 B. V. Costa

Single partially confined collapsed polymers are studied in two dimensions. They are described by self-avoiding random walks with nearest-neighbour attractions below the $\Theta$-point, on the surface of an infinitely long cylinder. For the…

Statistical Mechanics · Physics 2009-11-07 Hsiao-Ping Hsu , Peter Grassberger

Relaxation in glasses is often approximated by a stretched-exponential form: $f(t) = A \exp [-(t/\tau)^{\beta}]$. Here, we show that the relaxation in a model of sheared non-Brownian suspensions developed by Cort\'e et al. [Nature Phys. 4,…

Soft Condensed Matter · Physics 2017-02-02 Joseph D. Paulsen , Sidney R. Nagel

We report extensive simulations of the relaxation dynamics of a self-avoiding polymer confined inside a cylindrical pore. In particular, we concentrate on examining how confinement influences the scaling behavior of the global relaxation…

Soft Condensed Matter · Physics 2009-11-13 A. Arnold , B. Bozorgui , D. Frenkel , B. -Y. Ha , S. Jun

The energy dependence of the relaxation rate of hot electrons due to interaction with the Fermi sea is studied. We consider 2D and 3D systems, quasi-1D quantum wires with multiple transverse bands, as well as single-channel 1D wires. Our…

Mesoscale and Nanoscale Physics · Physics 2018-05-29 M. Bard , I. V. Protopopov , A. D. Mirlin

We study the dynamical behavior of a square lattice Ising model with exchange and dipolar interactions by means of Monte Carlo simulations. After a sudden quench to low temperatures we find that the system may undergo a coarsening process…

Statistical Mechanics · Physics 2009-09-02 S. A. Cannas , M. F. Michelon , D. A. Stariolo , F. A. Tamarit

We present an extensive set of simulation results for the stress relaxation in equilibrium and step-strained bead-spring polymer melts. The data allow us to explore the chain dynamics and the shear relaxation modulus, $G(t)$, into the…

Soft Condensed Matter · Physics 2015-05-18 Ji Xuan Hou , Carsten Svaneborg , Ralf Everaers , Gary S. Grest

The research is important for a molecular theory of liquid and has a wide interest as an example solving the problem when dynamic parameters of systems can be indirectly connected with their equilibrium properties. In frameworks of the…

Statistical Mechanics · Physics 2007-05-23 Andrei N. Yakunin

We investigate aging in glassy systems based on a simple model, where a point in configuration space performs thermally activated jumps between the minima of a random energy landscape. The model allows us to show explicitly a subaging…

Statistical Mechanics · Physics 2009-10-31 Bernd Rinn , Philipp Maass , Jean-Philippe Bouchaud

We attempt to give a bird's eye view of the physical mechanisms leading to anomalous relaxation, and the relation of this phenomenon with anomalous diffusion and transport. Whereas in some cases these two notions are indeed deeply related,…

Disordered Systems and Neural Networks · Physics 2007-05-23 Jean-Philippe Bouchaud

Entangled polymers are an important class of materials for their toughness, processability, and functionalizability. However, physically detailed modeling of highly entangled polymers can prove challenging, especially as one considers…

Soft Condensed Matter · Physics 2024-10-28 Vickie Chen , Brandon Wang , Joseph D. Peterson

This paper considers an undirected polymer chain on $\mathbb{Z}^d$, $d \geq 2$, with i.i.d.\ random charges attached to its constituent monomers. Each self-intersection of the polymer chain contributes an energy to the interaction…

Mathematical Physics · Physics 2018-02-14 Quentin Berger , Frank den Hollander , Julien Poisat

We investigate the relaxation energies and excited state geometries of the light emitting polymer, poly(para-phenylene). We solve the Pariser-Parr-Pople-Peierls model using the density matrix renormalization group method. We find that the…

Strongly Correlated Electrons · Physics 2009-11-10 Eric E. Moore , William Barford , Robert J. Bursill
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