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Using large deviation theory and principles of stochastic optimal control, we show that rare molecular dynamics trajectories conditioned on assembling a specific target structure encode a set of interactions and external forces that lead to…

Soft Condensed Matter · Physics 2021-01-14 Avishek Das , David T. Limmer

We propose a Deep Variational Clustering (DVC) framework for unsupervised representation learning and clustering of large-scale medical images. DVC simultaneously learns the multivariate Gaussian posterior through the probabilistic…

Computer Vision and Pattern Recognition · Computer Science 2021-09-23 Farzin Soleymani , Mohammad Eslami , Tobias Elze , Bernd Bischl , Mina Rezaei

Spinodal decomposition in multicomponent alloys has attracted increasing attention due to its beneficial effect on their mechanical and functional properties and potential applications. Both based on the Cahn-Hillard equation, the reference…

Materials Science · Physics 2024-05-21 Hengwei Luan , You Wu , Jingyi Kang , Liufei Huang , J. H. Luan , Jinfeng Li , Yang Shao , Ke-fu Yao , Jian Lu

Chemical short-range order (SRO) provides new opportunities for tuning alloy properties, but conventional computational thermodynamics frameworks such as CALPHAD, based on Bragg-Williams mean-field approximations, cannot properly describe…

Materials Science · Physics 2025-08-12 Chuliang Fu

The sharp optical resonances of NV- centers in diamond at cryogenic temperatures offer powerful new capabilities for material characterization, but extracting the most detailed information typically requires careful calibration of…

Materials Science · Physics 2025-11-06 Jason Shao , Richard Monge , Tom Delord , Carlos A. Meriles

We consider the nonsmooth convex composition optimization problem where the objective is a composition of two finite-sum functions and analyze stochastic compositional variance reduced gradient (SCVRG) methods for them. SCVRG and its…

Optimization and Control · Mathematics 2019-08-01 Tianyi Lin , Chenyou Fan , Mengdi Wang

Approximate full configuration interaction (FCI) calculations have recently become tractable for systems of unforeseen size thanks to stochastic and adaptive approximations to the exponentially scaling FCI problem. The result of an FCI…

Strongly Correlated Electrons · Physics 2017-10-25 Susi Lehtola , Norm M. Tubman , K. Birgitta Whaley , Martin Head-Gordon

A unified construction of the $H^m$-nonconforming virtual elements of any order $k$ is developed on any shape of polytope in $\mathbb R^n$ with constraints $m\leq n$ and $k\geq m$. As a vital tool in the construction, a generalized Green's…

Numerical Analysis · Mathematics 2019-10-17 Long Chen , Xuehai Huang

Convolutional dictionary learning (CDL) estimates shift invariant basis adapted to multidimensional data. CDL has proven useful for image denoising or inpainting, as well as for pattern discovery on multivariate signals. As estimated…

Machine Learning · Computer Science 2019-01-29 Thomas Moreau , Alexandre Gramfort

We employ chordal decomposition to reformulate a large and sparse semidefinite program (SDP), either in primal or dual standard form, into an equivalent SDP with smaller positive semidefinite (PSD) constraints. In contrast to previous…

Optimization and Control · Mathematics 2020-08-07 Yang Zheng , Giovanni Fantuzzi , Antonis Papachristodoulou , Paul Goulart , Andrew Wynn

Deep clustering (DC) has become the state-of-the-art for unsupervised clustering. In principle, DC represents a variety of unsupervised methods that jointly learn the underlying clusters and the latent representation directly from…

Machine Learning · Computer Science 2020-05-22 Lele Cao , Sahar Asadi , Wenfei Zhu , Christian Schmidli , Michael Sjöberg

An externally corrected coupled cluster (CC) method, where an adaptive configuration interaction (ACI) wave function provides the external cluster amplitudes, named ACI-CC, is presented. By exploiting the connection between configuration…

Chemical Physics · Physics 2023-09-27 Gustavo J. R. Aroeira , Madeline M. Davis , Justin M. Turney , Henry F. Schaefer

We introduce Variational Latent Mode Decomposition (VLMD), a new algorithm for extracting oscillatory modes and associated connectivity structures from multivariate signals. VLMD addresses key limitations of existing Multivariate Mode…

Machine Learning · Computer Science 2025-05-26 Manuel Morante , Naveed ur Rehman

Precise stoichiometry control in single-crystal growth is essential for both technological applications and fundamental research. However, conventional growth methods often face challenges such as non-stoichiometry, compositional gradients,…

Materials Science · Physics 2025-04-14 Yingdong Guan , Suguru Yoshida , Jairo Obando-Guevara , Seng Huat Lee , Heike Pfau , Zhiqiang Mao

Deep latent variable models (DLVMs) are designed to learn meaningful representations in an unsupervised manner, such that the hidden explanatory factors are interpretable by independent latent variables (aka disentanglement). The…

Machine Learning · Computer Science 2025-01-28 Surojit Saha , Sarang Joshi , Ross Whitaker

We investigate the estimation of multivariate extreme models with a discrete spectral measure using spherical clustering techniques. The primary contribution involves devising a method for selecting the order, that is, the number of…

Methodology · Statistics 2025-02-20 Shiyuan Deng , He Tang , Shuyang Bai

A novel data-driven method of modal analysis for complex flow dynamics, termed as reduced-order variational mode decomposition (RVMD), has been proposed, combining the idea of the separation of variables and a state-of-the-art nonstationary…

Fluid Dynamics · Physics 2022-09-27 Zi-Mo Liao , Zhiye Zhao , Liang-Bing Chen , Zhen-Hua Wan , Nan-Sheng Liu , Xi-Yun Lu

Isotopic fluctuations in fragment formation are investigated in a quasi-analytical description of the spinodal decomposition scenario. By exploiting the fluctuation-dissipation relations the covariance matrix of density fluctuations is…

Nuclear Theory · Physics 2008-11-26 M. Colonna , F. Matera

Mixture models are a natural choice in many applications, but it can be difficult to place an a priori upper bound on the number of components. To circumvent this, investigators are turning increasingly to Dirichlet process mixture models…

Statistics Theory · Mathematics 2018-06-22 Łukasz Rajkowski

Stein variational gradient descent (SVGD) is a prominent particle-based variational inference method used for sampling a target distribution. SVGD has attracted interest for application in machine-learning techniques such as Bayesian…

Machine Learning · Computer Science 2024-02-26 Yuya Kawamura , Satoshi Takabe