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Using helium-3 atom scattering, we have studied the adsorption kinetics, the structure and the diffusional dynamics of atomic hydrogen on the surface of a graphene monolayer on Ni(111). Diffraction measurements reveal a 4$^\circ$ rotated…

Mesoscale and Nanoscale Physics · Physics 2022-12-15 Emanuel Bahn , Anton Tamtögl , John Ellis , William Allison , Peter Fouquet

The activity of metal catalysts depends sensitively on dynamic structural changes that occur during operating conditions. The mechanistic understanding underlying such transformations in small Pt nanoparticles (NPs) of $\sim1-5$ nm in…

The use of a novel three-dimensional graphene structure allows circumventing the limitations of the two-dimensional nature of graphene and its application in hydrogen absorption. Here we investigate hydrogen-bonding on monolayer graphene…

We performed an X-ray diffraction experiment while palladium bulk absorbed and desorbed hydrogen to investigate the behavior of the crystalline lattice during the phase transition between the $\alpha$ phase and $\beta$ phase. Fast growth of…

Hydrogen can penetrate reversibly a number of metals, occupy the interstitial sites and cause large expansion of the crystal lattice. The question discussed here is whether the kinetics of the structural response matches hydrogen…

Materials Science · Physics 2020-08-14 S. S. Das , G. Kopnov , A. Gerber

The adsorption of atomic oxygen and its inclusion into subsurface sites on Ag(210) and Ag(410) surfaces have been investigated using density functional theory. We find that--in the absence of adatoms on the first metal layer--subsurface…

Condensed Matter · Physics 2009-11-10 A. Kokalj , N. Bonini , A. Dal Corso , S. de Gironcoli , S. Baroni

We have studied the microscopic dynamics of hydrogen adsorbed to bundles of single walled carbon nanotubes using inelastic neutron scattering. Evidence is obtained for much higher storage capacities in chemically treated compared to as…

Materials Science · Physics 2009-11-10 B. Renker , H. Schober , P. Schweiss , S. Lebedkin , F. Hennrich

The paper analyzes the absorption line profile at 21 cm for the hydrogen atom in the interstellar medium. The hydrogen atom is treated as a three-level system illuminated by a powerful light source at neighboring resonances corresponding to…

Atomic Physics · Physics 2018-11-05 D. Solovyev

Recent experimental observations have reported that, rather than randomly distributed, nitrogen atoms may prefer to be located on one of the two sub-lattices of graphene. It has been suggested that such a preference may present a possible…

Mesoscale and Nanoscale Physics · Physics 2015-09-30 James A. Lawlor , Mauro S. Ferreira

Water ice's remarkable properties make it an important material across a range of disciplines. The combination of covalent and hydrogen bonds form a long-range lattice of oxygens, which hosts a disordered yet correlated hydrogen network. We…

We investigate the occurrence of waterlike thermodynamic and dynamic anomalous behavior in a one dimensional lattice gas model. The system thermodynamics is obtained using the transfer matrix technique and anomalies on density and…

Soft Condensed Matter · Physics 2015-03-11 Marco Aurélio A. Barbosa , Fernando Vito Barbosa , Fernando Albuquerque de Oliveira

The changes in the optical transmission of thin vanadium layers upon hydrogen absorption are found to be dominated by the volume changes of the layers and not directly linked to concentration. This effect is demonstrated by utilising the…

Mesoscale and Nanoscale Physics · Physics 2018-12-13 Sotirios Droulias , Oscar Granas , Ola Hartmann , Kristina Komander , Bjorgvin Hjorvarsson , Max Wolff , Gunnar Palsson

The ability of atomic hydrogen to chemisorb on graphene makes the latter a promising material for hydrogen storage. Based on scanning tunneling microscopy techniques, we report on site-selective adsorption of atomic hydrogen on convexly…

The local adsorption geometries of the (2x2)-N and the (sqrt(3)x sqrt(3))R30^o -N phases on the Ru(0001) surface are determined by analyzing low-energy electron diffraction (LEED) intensity data. For both phases, nitrogen occupies the…

Materials Science · Physics 2009-10-28 S. Schwegmann , A. P. Seitsonen , H. Dietrich , H. Bludau , H. Over , K. Jacobi , G. Ertl

We have investigated the effect of hydrostatic pressure and temperature on phase stability of hydro-nitrogen solids using dispersion corrected Density Functional Theory calculations. From our total energy calculations, Ammonium Azide (AA)…

Materials Science · Physics 2015-11-24 N. Yedukondalu , G. Vaitheeswaran , P. Anees , M. C. Valsakumar

The absorption energy of atomic hydrogen at rotated graphene bilayers is studied using ab initio methods based on the density functional theory including van der Waals interactions. We find that, due to the surface corrugation induced by…

Mesoscale and Nanoscale Physics · Physics 2017-10-06 Ivan Brihuega , Felix Yndurain

Recent experiments on the silicon terminated $3\times 2$ SiC(100) surface indicated an unexpected metallic character upon hydrogen adsorption. This effect was attributed to the bonding of hydrogen to a row of Si atoms and to the…

Materials Science · Physics 2009-11-11 R. Di Felice , C. M. Bertoni , C. A. Pignedoli , A. Catellani

This study investigates hydrogen permeation in titanium aluminium nitride (TiAlN) using ab initio density functional theory (DFT) for cubic and hexagonal crystal structures. Despite the significance of hydrogen barriers, the potential of…

Materials Science · Physics 2024-10-03 Cem Örnek , Rainer Fechte-Heinen

We report the experimental observation of sublattice-resolved resonant scattering in bilayer graphene by performing simultaneous cryogenic atomic hydrogen doping and electron transport measurements in ultrahigh vacuum. This allows us to…

Mesoscale and Nanoscale Physics · Physics 2018-10-02 Jyoti Katoch , Tiancong Zhu , Denis Kochan , Simranjeet Singh , Jaroslav Fabian , Roland K. Kawakami

Understanding high-pressure transitions in prototypical linear diatomic molecules, such as hydrogen, nitrogen, and oxygen, is an important objective in high-pressure physics. Recent ultrahigh-pressure study on hydrogen revealed that there…

Materials Science · Physics 2019-10-31 Shan Liu , Meifang Pu , Qiqi Tang , Feng Zhang , Binbin Wu , Li Lei
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