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Based on the survey of the literatures on the new improvements on the equation of state (EOS) for the hard sphere fluids, we here compare lots of different EOSs and present a very accurate equation of state for this kind of fluids. The new…

Soft Condensed Matter · Physics 2025-12-08 Can Cui , Jianxiang Tian

An equation of state for a multicomponent mixture of non-additive hard spheres in $d$ dimensions is proposed. It yields a rather simple density dependence and constitutes a natural extension of the equation of state for additive hard…

Soft Condensed Matter · Physics 2007-05-23 A. Santos , M. Lopez de Haro , S. B. Yuste

A simple recipe to derive the compressibility factor of a multicomponent mixture of d-dimensional additive hard spheres in terms of that of the one-component system is proposed. The recipe is based (i) on an exact condition that has to be…

Statistical Mechanics · Physics 2019-05-23 A. Santos , S. B. Yuste , M. Lopez de Haro

The study of Mayer's cluster expansion (CE) for the partition function demonstrates a possible way to resolve the problem of the CE non-physical behavior at condensed states of fluids. In particular, a general equation of state is derived…

Statistical Mechanics · Physics 2018-10-03 M. V. Ushcats , S. Yu. Ushcats , L. A. Bulavin , V. M. Sysoev

For single components fluids, vanishing isothermal compressibility implies that the mass density is constant, but the same conclusion is unknown for multicomponent fluids. Here the volume remains affected by changes of the composition. In…

Fluid Dynamics · Physics 2024-12-09 Pierre-Etienne Druet

We analyze a system of PDEs governing the interaction between two compressible mutually noninteracting fluids and a shell of Koiter type encompassing a time dependent 3D domain filled by the fluids. The dynamics of the fluids is modelled by…

Analysis of PDEs · Mathematics 2023-02-13 Martin Kalousek , Sourav Mitra , Šárka Nečasová

In this paper we discuss the incompressible limit for multicomponent fluids in the isothermal ideal case. Both a direct limit-passage in the equation of state and the low Mach-number limit in rescaled PDEs are investigated. Using the…

Analysis of PDEs · Mathematics 2022-04-26 Pierre-Etienne Druet

We consider a system of partial differential equations describing mass transport in a multicomponent isothermal compressible fluid. The diffusion fluxes obey the Fick-Onsager or Maxwell-Stefan closure approach. Mechanical forces result into…

Analysis of PDEs · Mathematics 2020-01-27 Dieter Bothe , Pierre-Etienne Druet

In this paper, we study the dynamics of a finite number of spherical bubbles in a compressible fluid within a bounded open domain of R 3 . The fluid-bubble interaction is described by a system of nonlinear partial differential equations…

Analysis of PDEs · Mathematics 2026-04-10 Fabien Lespagnol , Matthieu Hillairet

We consider a fluid of hard spheres bearing one or two uniform circular adhesive patches, distributed so as not to overlap. Two spheres interact via a ``sticky'' Baxter potential if the line joining the centers of the two spheres intersects…

Statistical Mechanics · Physics 2009-11-13 Riccardo Fantoni , Domenico Gazzillo , Achille Giacometti , Mark A. Miller , Giorgio Pastore

A new closed virial equation of state of hard-sphere fluids is proposed which reproduces the calculated or estimated values of the first sixteen virial coefficients at the same time as giving very good accuracy when compared with computer…

Chemical Physics · Physics 2016-07-14 Jianxiang Tian , Yuanxing Gui , Angel Mulero

We study the polydisperse Baxter model of sticky hard spheres (SHS) in the modified Mean Spherical Approximation (mMSA). This closure is known to be the zero-order approximation (C0) of the Percus-Yevick (PY) closure in a density expansion.…

Statistical Mechanics · Physics 2007-05-23 Riccardo Fantoni , Domenico Gazzillo , Achille Giacometti

The equation of state for dense fluids has been derived within the framework of the Sutherland and Katz potential models. The equation quantitatively agrees with experimental data on the isothermal compression of water under extrapolation…

Chemical Physics · Physics 2012-03-15 V. Yu. Bardik , D. Nerukh , E. V. Pavlov , I. V. Zhyganiuk

We present a closed analytical formula for the scattering intensity from charged hard sphere fluids with any arbitrary number of components. Our result is an extension to ionic systems of Vrij's analogous expression for uncharged hard…

Statistical Mechanics · Physics 2009-10-30 Domenico Gazzillo , Achille Giacometti , Flavio Carsughi

The hard sphere system plays a basic role in condensed matter physics and related fields, and equation of state (EoS) is the ultimate solution to its thermodynamic properties (1-3). Dozens of EoSs have been proposed since van der Waals…

Statistical Mechanics · Physics 2007-05-23 Hongqin Liu

In this paper, we extend our study of mass transport in multicomponent isothermal fluids to the incompressible case. For a mixture, incompressibility is defined as the independence of average volume on pressure, and a weighted sum of the…

Analysis of PDEs · Mathematics 2020-05-26 Dieter Bothe , Pierre-Etienne Druet

The gravitational collapse of a barotropic perfect fluid having the Equation of State (EoS) $p=k\rho$, where $k$ is constant, is studied here in the framework of general relativity. We examine the restrictions on the Misner-Sharp mass…

General Relativity and Quantum Cosmology · Physics 2019-10-31 Karim Mosani , Dipanjan Dey , Pankaj S. Joshi

Numerical simulations of compressible fluid flows require an equation of state (EOS) to relate the thermodynamic variables of density, internal energy, temperature, and pressure. A valid EOS must satisfy the thermodynamic conditions of…

Computational Physics · Physics 2009-11-11 Gary A. Dilts

We consider an anisotropic version of Baxter's model of `sticky hard spheres', where a nonuniform adhesion is implemented by adding, to an isotropic surface attraction, an appropriate `dipolar sticky' correction (positive or negative,…

Soft Condensed Matter · Physics 2009-11-13 Domenico Gazzillo , Riccardo Fantoni , Achille Giacometti

A known `sticky-hard-sphere' model, defined starting from a hard-sphere-Yukawa potential and taking the limit of infinite amplitude and vanishing range with their product remaining constant, is shown to be ill-defined. This is because its…

Statistical Mechanics · Physics 2009-11-10 Domenico Gazzillo , Achille Giacometti
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