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The equilibrium phase behaviour of hard spheres with size polydispersity is studied theoretically. We solve numerically the exact phase equilibrium equations that result from accurate free energy expressions for the fluid and solid phases,…

Soft Condensed Matter · Physics 2007-05-23 M. Fasolo , P. Sollich

We study the critical Casimir interaction between two spherical colloids immersed in a binary liquid mixture close to its critical demixing point. The surface of each colloid prefers one species of the mixture with the exception of a…

Statistical Mechanics · Physics 2020-04-22 Nima Farahmand Bafi , Piotr Nowakowski , Siegfried Dietrich

We study the equilibrium statistical mechanics of classical two-dimensional Coulomb systems living on a pseudosphere (an infinite surface of constant negative curvature). The Coulomb potential created by one point charge exists and goes to…

Condensed Matter · Physics 2007-05-23 B. Jancovici , G. Tellez

We consider a binary system of small and large spheres of finite size in a continuous medium interacting via a non-negative potential. We work in the canonical ensemble and compute upper and lower bound for the free energy at finite and…

Mathematical Physics · Physics 2023-10-24 Tong Xuan Nguyen , Giuseppe Scola , Dimitrios Tsagkarogiannis

We study the effect of solvent granularity on the effective force between two charged colloidal particles by computer simulations of the primitive model of strongly asymmetric electrolytes with an explicitly added hard sphere solvent. Apart…

Soft Condensed Matter · Physics 2009-10-31 E. Allahyarov , H. Loewen

We derive and introduce anisotropic effective pair potentials to coarse-grain solutions of semiflexible rings polymers of various lengths. The system has been recently investigated by means of full monomer-resolved computer simulations,…

Soft Condensed Matter · Physics 2015-07-21 Peter Poier , Christos N. Likos , Angel J. Moreno , Ronald Blaak

We develop a simple model, in the spirit of the Asakura-Oosawa theory, able to describe the effects of surface roughness on the depletion potential as a function of a small set of parameters. The resulting explicit expressions are easily…

Soft Condensed Matter · Physics 2017-05-29 Pietro Anzini , Alberto Parola

We investigate the effect of mobile polymer brushes on proteins embedded in biological membranes by employing both Asakura-Oosawa type of theoretical model and coarse-grained molecular dynamics simulations. The brush polymer-induced…

Soft Condensed Matter · Physics 2022-03-02 Anvy Moly Tom , Won Kyu Kim , Changbong Hyeon

Block copolymer melts self-assemble in the bulk into a variety of nanostructures, making them perfect candidates to template the position of nanoparticles. The morphological changes of block copolymers are studied in the presence of a…

Soft Condensed Matter · Physics 2019-10-31 Javier Diaz , Marco Pinna , Andrei V. Zvelindovsky , Ignacio Pagonabarraga

Spatially uniform electric fields have been used to induce instabilities in liquids and polymers, and to orient and deform ordered phases of block-copolymers. Here we discuss the demixing phase transition occurring in liquid mixtures when…

Statistical Mechanics · Physics 2015-05-13 G. Marcus , Y. Tsori

We study the depletion-induced self-assembly of indented colloids. Using state-of-the-art Monte Carlo simulation techniques that treat the depletant particles explicitly, we demonstrate that colloids assemble by a lock-and-key mechanism,…

Soft Condensed Matter · Physics 2014-01-13 Douglas J. Ashton , Robert L. Jack , Nigel B. Wilding

The spatial suppression of order parameter fluctuations in a critical media produces Critical Casimir forces acting on confining surfaces. This scenario is realized in a critical binary mixture near the demixing transition point that…

Statistical Mechanics · Physics 2014-10-03 Oleg A. Vasilyev

The dissipation rate due to inelastic collisions between equally charged, insulating particles in a dilute granular medium is calculated. It is equal to the known dissipation rate for uncharged granular media multiplied by a Boltzmann-like…

Statistical Mechanics · Physics 2007-05-23 Tim Scheffler , Dietrich E. Wolf

The effective interaction between charged colloidal particles confined between two planar like-charged walls is investigated using computer simulations of the primitive model describing asymmetric electrolytes. In detail, we calculate the…

Soft Condensed Matter · Physics 2016-08-15 E. Allahyarov , I. D'Amico , H. Löwen

The contact value theorem was originally derived for Coulomb fluids of mobile charged particles in thermal equilibrium, in the presence of interfaces carrying a {\em uniform} surface charge density and in the absence of dielectric…

Statistical Mechanics · Physics 2025-03-03 Ladislav Šamaj

The intricate interplay between colloidal particle shape and precisely engineered interaction potentials has paved the way for the discovery of unprecedented crystal structures in both two and three dimensions. Here, we make use of…

Soft Condensed Matter · Physics 2023-11-27 Fabrizio Camerin , Susana Marín-Aguilar , Marjolein Dijkstra

We investigate the anomalous dynamics of unentangled polymer melts. The proposed equation of motion formally relates the anomalous center-of-mass diffusion, as observed in computer simulations and experiments, to the nature of the effective…

Statistical Mechanics · Physics 2009-11-07 M. Guenza

We derive an analytical pair potential of mean force for Brownian molecules in the liquid-state. Our approach accounts for many-particle correlations of crowding particles of the liquid, and for diffusive transport across the spatially…

Soft Condensed Matter · Physics 2012-06-21 Alessio Zaccone , Eugene M. Terentjev

We generalize a recently investigated lattice model of semiflexible polymers formed under equilibrium polymerization in a solution and conduct a comprehensive investigation of its melting properties. The model is characterized by six…

Condensed Matter · Physics 2007-05-23 Sagar S. Rane , P. D. Gujrati

Chemically-responsive polymers are macromolecules that respond to local variations of the chemical composition of the solution by changing their conformation, with notable examples including polyelectrolytes, proteins and DNA. The polymer…

Soft Condensed Matter · Physics 2022-07-27 Marco De Corato , Marino Arroyo
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