English
Related papers

Related papers: Phase Behavior of Bent-Core Molecules

200 papers

Swimming bacteria in passive nematics in the form of lyotropic liquid crystals are defined as a new class of active matter known as living liquid crystals in recent studies. It has also been shown that liquid crystal solutions are promising…

Soft Condensed Matter · Physics 2021-09-01 Pranay Bimal Sampat , Shradha Mishra

We construct a tensor model for nematic phases of bent-core molecules from molecular theory. The form of free energy is determined by molecular symmetry, which includes the couplings and derivatives of a vector and two second-order tensors,…

Soft Condensed Matter · Physics 2018-08-24 Jie Xu , Fangfu Ye , Pingwen Zhang

Orientational and positional ordering properties of liquid crystal monolayers are examined by means of Fundamental-Measure Density Functional Theory. Particles forming the monolayer are modeled as hard parallelepipeds of square section of…

Soft Condensed Matter · Physics 2015-06-19 Yuri Martinez-Raton , Szabolcs Varga y Enrique Velasco

Smectic-C elastomers can be prepared by crosslinking, e.g., liquid crystal polymers, in the smectic-A phase followed by a cooling through the smectic-A to smectic-C phase transition. This transition from $D_{\infty h}$ to $C_{2h}$ symmetry…

Soft Condensed Matter · Physics 2009-11-10 Olaf Stenull , T. C. Lubensky

Nematic liquid crystals confined to geometrically as well as chemically patterned substrate on one end and a flat substrate with strong anchoring on the other is studied using non-Boltzmann Monte Carlo methods. We observe significant…

Soft Condensed Matter · Physics 2010-10-18 D. Jayasri , Regina Jose , K. P. N. Murthy , V. S. S. Sastry

We present a neutron scattering analysis of the structure of the smectic liquid crystal octylcyanobiphenyl (8CB) confined in one-dimensional nanopores of porous silicon films (PS). The smectic transition is completely suppressed, leading to…

Soft Condensed Matter · Physics 2016-08-16 Régis Guégan , Denis Morineau , Claude Loverdo , Wilfried Béziel , Mohammed Guendouz

I consider the effects of polymers on the smectic phase of a host liquid crystal matrix. Focusing on the regime in which the polymers are predominately confined between the smectic layers, I find that the presence of the polymers can lead…

Soft Condensed Matter · Physics 2009-10-28 Leo Radzihovsky

Samarium substituted bismuth ferrite (BiFeO3) ceramics prepared by sol-gel synthesis method were studied using both local scale and microscopic measurement techniques in order to clarify an evolution of the crystal structure of the…

NMR measurements on a selectively deuteriated liquid crystal dimer CB-C9-CB exhibiting two nematic phases show that the molecules in the lower temperature nematic phase, Nx, experience a chiral environment and are ordered about a unique…

Soft Condensed Matter · Physics 2014-07-09 Anke Hoffmann , Alexandros G. Vanakaras , Alexandra Kohlmeier , Georg H. Mehl , Demetri J. Photinos

High-resolution X-ray scattering studies of the nonpolar thermotropic liquid crystal 4-n-pentylphenylthiol-4'-n-octyloxybenzoate (\bar{8}S5) in aerosil gel nano-networks reveal that the aerosil-induced disorder significantly alters both the…

Soft Condensed Matter · Physics 2015-05-28 B. Freelon , M. Ramazanoglu , P. J. Chung , P. Valdivia , C. W. Garland , R. J. Birgeneau

We apply a recently proposed density functional for mixtures of parallel hard cylinders, based on Rosenfeld's fundamental measure theory, to study the effect of length-polydispersity on the relative stability between the smectic and…

Soft Condensed Matter · Physics 2015-05-13 Yuri Martinez-Raton , Jose A. Cuesta

The liquid crystalline 11OS5 compound, forming the nematic phase and a few smectic phases, is investigated by broadband dielectric spectroscopy and infra-red spectroscopy. The dielectric relaxation times, ionic conductivity, and positions…

Liquid crystalline phases of matter permeate nature and technology, with examples ranging from cell membranes to liquid-crystal displays. Remarkably, electronic liquid crystal phases can exist in two-dimensional electron systems (2DES) at…

Mesoscale and Nanoscale Physics · Physics 2017-11-20 Q. Qian , J. Nakamura , S. Fallahi , G. C. Gardner , M. J. Manfra

We perform extensive Monte Carlo simulations of a two-dimensional bent hard-needle model in both its chiral zig-zag and its achiral bow-shape configurations and present their phase diagrams. We find evidence for a variety of stable phases:…

Statistical Mechanics · Physics 2016-04-15 Raffaele Tavarone , Patrick Charbonneau , Holger Stark

We use density-functional theory, of the fundamental-measure type, to study the relative stability of the biaxial nematic phase, with respect to non-uniform phases such as smectic and columnar, in fluids made of hard board-like particles…

Soft Condensed Matter · Physics 2017-09-13 Yuri Martinez-Raton , Szabolcs Varga , Enrique Velasco

Phase behaviours of liquid crystals under external fields, conjugate to the nematic order and smectic order, are studied within the framework of mean field approximation developed by McMillan. It is found that phase diagrams, of temperature…

Soft Condensed Matter · Physics 2009-11-10 Masashi Torikai , Mamoru Yamashita

We report a novel multi-scale simulation methodology to quantitatively predict the thermodynamic behaviour of polymer mixtures, that exhibit phases with broken orientational symmetry. Our system consists of a binary mixture of oligomers and…

Soft Condensed Matter · Physics 2021-12-07 William S. Fall , Hima Bindu Kolli , Biswaroop Mukherjee , Buddhapriya Chakrabarti

We study the phase behaviour of cholesteric liquid crystal shells with different geometries. We compare the cases of tangential and no anchoring at the surface, focussing on the former case, which leads to a competition between the…

Soft Condensed Matter · Physics 2023-03-01 Giuseppe Negro , Livio Nicola Carenza , Giuseppe Gonnella , Davide Marenduzzo , Enzo Orlandini

Small-angle neutron scattering (SANS) profiles revealed the existence of magnetic textures like liquid crystals in the low-temperature helical phase of Fe0.7Co0.3Si, isomorphous of MnSi.

We develop the scaled particle theory to describe the thermodynamic properties and orientation ordering of a binary mixture of hard spheres (HS) and hard spherocylinders (HSC) confined in a disordered porous medium. Using this theory the…

Soft Condensed Matter · Physics 2019-02-12 M. Hvozd , T. Patsahan , M. Holovko