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A thermodynamic framework has been developed for a class of amorphous polymers used in fused deposition modeling (FDM), in order to predict the residual stresses and the accompanying distortion of the geometry of the printed part (warping).…

Classical Physics · Physics 2021-02-09 P. Sreejith , K. Kannan , K. R. Rajagopal

Inhomogeneous polymers play an important role in various cellular processes, both in nature and in biotechnological applications. At finite temperatures, inhomogeneous polymers exhibit non-trivial thermal fluctuations. In a broader context,…

Statistical Mechanics · Physics 2017-02-02 Yohai Bar-Sinai , Eran Bouchbinder

Closed-form solutions for the modified exterior Eshelby tensor, strain concentration tensor, and effective moduli of particle-reinforced composites are presented when the interfacial damage is modeled as a linear spring layer of vanishing…

Other Condensed Matter · Physics 2019-02-11 Sangryun Lee , Youngsoo Kim , Jinyeop Lee , Seunghwa Ryu

We analyze structural and conformational properties in a simulated bead-spring model of a non-entangled, supercooled polymer melt. We explore the statics of the model via various structure factors, involving not only the monomers, but also…

Soft Condensed Matter · Physics 2009-11-10 Martin Aichele , Song-Ho Chong , Jörg Baschnagel , Matthias Fuchs

We generalize a recently investigated lattice model of semiflexible polymers formed under equilibrium polymerization in a solution and conduct a comprehensive investigation of its melting properties. The model is characterized by six…

Condensed Matter · Physics 2007-05-23 Sagar S. Rane , P. D. Gujrati

Dynamical properties of a long polymer ring in a melt of unknotted and unconcatenated rings are calculated. We re-examine and generalize the well known model of a ring confined to a lattice of topological obstacles in the light of the…

Soft Condensed Matter · Physics 2015-06-22 Jan Smrek , Alexander Y. Grosberg

The fundamental measure approach to classical density functional theory has been shown to be a powerful tool to predict various thermodynamic properties of hard-sphere systems. We employ this approach to determine not only one-particle…

Soft Condensed Matter · Physics 2015-11-02 Andreas Härtel , Matthias Kohl , Michael Schmiedeberg

This research paper comprehensively explores the effects of molecular weight and chain architecture on the interfacial and thermodynamic properties of cyclic and linear polymer blends. Utilizing the Kremer-Grest bead-spring model, the study…

Soft Condensed Matter · Physics 2025-07-11 Oluwatumininu Emmanuel Ayo-Ojo , Nkosinathi Dlamini

We review the progress that has been recently made in the application of time-dependent density functional theory to thermoelectric phenomena. As the field is very young, we emphasize open problems and fundamental issues. We begin by…

Mesoscale and Nanoscale Physics · Physics 2017-04-26 F. G. Eich , M. Di Ventra , G. Vignale

We present a new approach to study measures on ensembles of contours, polymers or other objects interacting by some sort of exclusion condition. For concreteness we develop it here for the case of Peierls contours. Unlike existing methods,…

Probability · Mathematics 2016-08-15 Roberto Fernández , Pablo A. Ferrari , Nancy L. Garcia

A monte carlo density functional theory is developed for chain molecules which both intra and intermolecularly associate. The approach can be applied over a range of chain lengths. The theory is validated for the case of an associating…

Soft Condensed Matter · Physics 2013-08-30 B. D. Marshall , A. J. Garcia-Cuellar , W. G. Chapman

We consider the adsorption of a random heteropolymer onto an interface within the model by Garel et al. [1] by taking into account self-interactions between the monomers. Within the replica trick and by using a self-consistent preaveraging…

Soft Condensed Matter · Physics 2009-11-07 Valerii A. Brazhnyi , Semjon Stepanow

After a brief discussion of the concepts of fractional exchange and fractional exclusion statistics, we report partly analytical and partly numerical results on thermodynamic properties of assemblies of particles obeying fractional…

Strongly Correlated Electrons · Physics 2011-11-10 F. M. D. Pellegrino , G. G. N. Angilella , N. H. March , R. Pucci

A simple application of classical density functional theory is derived and applied to a system of polymers grafted to a plane. The system is assumed to have symmetry in directions parallel to the grafting plane hence it being a…

Soft Condensed Matter · Physics 2016-12-02 Luke Kristopher Davis

Confined in two dimensional planes, polymer chains comprising dense monolayer solution are segregated from each other due to topological interaction. Although the segregation is inherent in two dimensions (2D), the solution may display…

Soft Condensed Matter · Physics 2022-09-26 Lei Liu , Changbong Hyeon

The density crossover scaling of various thermodynamic properties of solutions and melts of self-avoiding and highly flexible polymer chains without chain intersections confined to strictly two dimensions is investigated by means of…

Soft Condensed Matter · Physics 2012-09-03 N. Schulmann , H. Meyer , P. Polińska , J. Baschnagel , J. P. Wittmer

Using confocal microscopy we investigate the effect of attraction on the packing of polydisperse emulsions under gravity. We find that the distributions of neighbors, coordination number, and local packing fraction as a function of…

Soft Condensed Matter · Physics 2011-04-08 Ivane Jorjadze , Lea-Laetitia Pontani , Katherine Newhall , Jasna Brujic

Using the Fundamental-Measure Density Functional Theory, we have studied theoretically the phase behavior of extremely confined mixtures of parallel hard squares in slit geometry. The pore width is chosen such that configurations consisting…

Soft Condensed Matter · Physics 2020-01-09 Yuri Martinez-Raton , Enrique Velasco

The interferometric analysis of meson correlations provides a measure of the average phase space density of the mesons in the final state. This quantity is a useful indicator of the statistical properties of the system, and it can be…

Nuclear Theory · Physics 2009-10-22 George F. Bertsch

The some dynamic properties of a random heteropolymer in the condensed state are studied in the mode coupling approximation. In agreement with recent report a dynamic friction increasing is predicted for the random heteropolymer with…

Disordered Systems and Neural Networks · Physics 2007-05-23 E. Sh. Mamasakhlisov , V. F. Morozov