Related papers: The nonlinear viscoelastic behavior of polypropyle…
The mechanical, structural and functional properties of crystals are determined by their defects and the distribution of stresses surrounding these defects has broad implications for the understanding of transport phenomena. When the defect…
The measurement of interfacial mechanical or rheological properties in polymer blends is a challenging task, as well as providing a quantitative link between these properties and the interfacial nanostructure. Here, we perform a systematic…
Solutions of semiflexible polymers confined by repulsive planar walls are studied by density functional theory and Molecular Dynamics simulations, to clarify the competition between the chain alignment favored by the wall and the depletion…
This note addresses a three-dimensional model for isothermal stress-induced transformation in shape-memory polycrystalline materials. We treat the problem within the framework of the energetic formulation of rate-independent processes and…
In this study, we investigate the transition between the Newtonian and the viscoelastic regimes during the pinch-off of droplets of dilute polymer solutions and discuss its link to the coil-stretch transition. The detachment of a drop from…
Biopolymer looping is a dynamic process that occurs ubiquitously in cells for gene regulation, protein folding, etc. In cellular environments, biopolymers are often subject to tensions which are either static, or temporally fluctuating far…
Hyperelastic materials models are well established to describe the non-linear stress-strain relations of elastomers. In this paper, a polyurethane adhesive is considered as an exemplary material and subjected to tensile, compressive and…
We address the general question of how the molecular weight dependence of chain dynamics in unentangled polymers is modified by blending. By dielectric spectroscopy we measure the normal mode relaxation of polyisoprene in blends with a slow…
An initial-boundary value problem for the multidimensional type III thermoelaticity for a nonsimple material with a center of symmetry is considered. In the linear case, the well-posedness with and without Kelvin-Voigt and/or frictional…
Recently, a non-linear model of viscoelasticity based on Rational Extended Thermodynamics was proposed in [arXiv:2312.05116]. This theory extends the evolution of the viscous stress beyond the linear framework of the Maxwell model to the…
A {\it new} formula for the force vs extension relation is derived from the discrete version of the so called {\it worm like chain} model. This formula correctly fits some recent experimental data on polymer stretching and some numerical…
The mechanical properties of crystalline materials can be substantially modified under confinement. Such modified macroscopic properties are usually governed by the altered microstructures and internal stress fields. Here, we use a parallel…
An analytic, asymptotic approximation of the nonlinear steady-state equations for viscoelastic creeping flow, modeled by the Oldroyd-B equations with polymer stress diffusion, is derived. Near the extensional stagnation point the flow…
Constitutive equations are derived for the viscoelastic behavior of particle-reinforced rubbers at isothermal loading with finite strains. A filled rubber is thought of as a composite medium where inclusions with high and low concentrations…
Using non-equilibrium molecular dynamics simulations we study the yielding behaviour of a model cluster crystal formed by ultrasoft particles under shear. We investigate the evolution of stress as a function of strain for different shear…
We study both experimentally and theoretically the rheological behavior of isotropic bidisperse suspensions of noncolloidal particles in yield stress fluids. We focus on materials in which noncolloidal particles interact with the suspending…
A constitutive model is developed to predict the viscoelastic response of polyimide resins that are used in high temperature applications. This model is based on a thermodynamic framework that uses the notion that the `natural…
Simulations are used to examine the microscopic origins of strain hardening in polymer glasses. While traditional entropic network models can be fit to the total stress, their underlying assumptions are inconsistent with simulation results.…
The polarization and strain response of ferroelectric materials at fields below the macroscopic coercive field is of a paramount importance for the operation of many electronic devices. The response of real ferroelectric and related…
Hypothesis: While the mechanical disruption of microscopic structures in complex fluids by large shear flows has been studied extensively, the effects of applied strains on the dielectric properties of macromolecular aggregates has received…