English
Related papers

Related papers: New Phase Transition in Polymer Solutions with Mul…

200 papers

Understanding the phase behaviour of mixtures continues to pose challenges, even for systems that might be considered "simple". Here we consider a very simple mixture of two colloidal and one non-adsorbing polymer species which can be…

We present a neutron spectroscopy based method to study quantitatively the partial miscibility and phase behaviour of an organic photovoltaic active layer made of conjugated polymer:small molecule blends, presently illustrated with the…

Materials Science · Physics 2021-09-20 Mohamed Zbiri , Peter A. Finn , Christian B. Nielsen , Anne A. Y. Guilbert

We investigate the influence of a non-ionic surfactant like polymer on phospholipid vesicles. Our results from cryogenic transmission electron microscopy (cryo-TEM), dynamic light scattering (DLS), small angle neutron and X-ray scattering…

High-entropy oxides (HEOs) are a promising class of multicomponent ceramics with tunable structural and electronic properties. In this study, we investigate the local electronic structure of rare-earth HEOs in the (Ce, Sm, Pr, La, Y)O2…

Structural transitions and the melting behavior of crystalline poly(ethylene oxide),(CH2-CH2-O)n, (PEO) has been investigated using fully atomistic, constant pressure-constant temperature (NPT) molecular dynamics (MD) simulations. Melting…

Materials Science · Physics 2009-11-10 M. Krishnan , S. Balasubramanian

Porous polymer films of Poly(ethylene oxide)(PEO) are synthesized by solution casting technique using gamma irradiated: (a) PEO powder (S-series) and (b) PEO - methanol solution (L-series). Pore phase forms instantaneously during…

Applied Physics · Physics 2018-06-13 Subir K. Patla , Madhumita Mukhopadhyay , Abhra Giri , Ruma Ray , Sujata Tarafdar

The effect of quenched disorder in the one-dimensional asymmetric exclusion process is reviewed. Both particlewise and sitewise disorder generically induces phase separation in a range of densities. In the particlewise case the existence of…

Statistical Mechanics · Physics 2011-05-20 Joachim Krug

Disordered metasurfaces provide a versatile platform for harnessing near- and far-field scattered light. Most research has focused on either particulate topologies composed of individual, well-identified metaatoms or, to a lesser extent,…

A living polymers transition is found in molecular dynamics simulations of a charge-symmetric size-asymmetric electrolyte with no anisotropic interactions. The fluid has strong polymeric character at low temperatures, where it consists of…

Statistical Mechanics · Physics 2007-05-23 Sorin Bastea

An extension of the relativistic density functional approach to the equation of state for strongly interacting matter is suggested which generalizes a recently developed modified excluded-volume mechanism to the case of temperature and…

Nuclear Theory · Physics 2018-02-16 Stefan Typel , David Blaschke

We present a non-isothermal mesoscopic model for investigation of the phase transition dynamics of thermoresponsive polymers. Since this model conserves energy in the simulations, it is able to correctly capture not only the transient…

Chemical Physics · Physics 2015-04-28 Zhen Li , Yu-Hang Tang , Xuejin Li , George Em Karniadakis

Hypothesis: Multi-component droplet evaporation has received significant attention in recent years due to the broad range of applications such as material science, environmental monitoring, and pharmaceuticals. The selective evaporation…

Fluid Dynamics · Physics 2023-05-23 Hao Zeng , Yuki Wakata , Xing Chao , Mingbo Li , Chao Sun

A change of solute dispersion regime with the flow velocity has been studied both at the macroscopic and pore scales in a transparent array of capillary channels using an optical technique allowing for simultaneous local and global…

Fluid Dynamics · Physics 2007-05-23 Maria Veronica D'Angelo , Harold Auradou , Catherine Allain , Jean-Pierre Hulin

We study the effect of the crowded nature of the cellular cytoplasm on the translocation of a polymer through a pore in a membrane. By systematically treating the entropic penalty due to crowding, we show that the translocation dynamics are…

Soft Condensed Matter · Physics 2009-11-13 Ajay Gopinathan , Yong Woon Kim

Recent experimental observations of anisotropic conductivity in stretched polymer electrolytes films of the polyethylene oxide family are discussed. The main experimental observations, enhancement of the ionic diffusion and conductivity in…

Soft Condensed Matter · Physics 2007-05-23 Oliver Duerr , Wolfgang Dieterich , Philipp Maas , Abraham Nitzan

A polymer chain tethered to a surface may be compact or extended, adsorbed or desorbed, depending on interactions with the surface and the surrounding solvent. This leads to a rich phase diagram with a variety of transitions. To investigate…

Soft Condensed Matter · Physics 2009-11-13 Jutta Luettmer-Strathmann , Federica Rampf , Wolfgang Paul , Kurt Binder

In conflict with standard notions of thermodynamics, mesoscopically-sized inclusions (``clusters'') of a solute-rich liquid have been observed in equilibrated solutions of proteins and other molecules. According to a complexation scenario…

Soft Condensed Matter · Physics 2025-09-11 Ilya Davydov , Vassiliy Lubchenko

The nanoscale fluctuation dynamics of semi dilute high molecular weight polymer solutions of Polyethylenoxide (PEO) in D2O under non-equilibrium flow conditions were studied by the neutron spin-echo technique. The sample cell was in…

Fluid Dynamics · Physics 2011-06-16 Maikel C. Rheinstadter , Rainer Sattler , Wolfgang Haeussler , Christian Wagner

Ion conducting polymers have a biphasic character with crystalline as well as amorphous phases. There is moreover, a dynamic disorder due to motion of polymer chain segments. The PEO-NH$_4$ClO$_4$ system undergoes a crossover from a…

Condensed Matter · Physics 2009-10-31 Sarmishtha Mandal , S. Tarafdar , Aninda Jiban Bhattacharyya

The phase transitions in dense neutron matter with triplet pairing have been investigated. The spectrum of phases of the $^3P_2$-$^3F_2$ model, which adequately describes pairing in this system, is identified and classified with the aid of…

Nuclear Theory · Physics 2009-09-29 J. W. Clark , V. A. Khodel , M. V. Zverev