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Chemically-responsive polymers are macromolecules that respond to local variations of the chemical composition of the solution by changing their conformation, with notable examples including polyelectrolytes, proteins and DNA. The polymer…

Soft Condensed Matter · Physics 2022-07-27 Marco De Corato , Marino Arroyo

Polymer-coated pores play a crucial role in nucleo-cytoplasmic transport and in a number of biomimetic and nanotechnological applications. Here we present Monte Carlo and Density Functional Theory approaches to identify different collective…

Soft Condensed Matter · Physics 2015-05-30 Dino Osmanovic , Joe Bailey , Anthony H. Harker , Ariberto Fassati , Bart W. Hoogenboom , Ian J. Ford

We address the response of a random heteropolymer to preferential solvation of certain monomer types at the globule-solvent interface. For each set of monomers that can comprise the molecule's surface, we represent the ensemble of allowed…

Soft Condensed Matter · Physics 2009-11-10 Philip Geissler , Eugene Shakhnovich , Alexander Grosberg

Hyperuniformity, whereby the static structure factor (or density correlator) obeys $S(q)\sim q^{\varsigma}$ with $\varsigma> 0$, emerges at criticality in systems having multiple absorbing states, such as periodically sheared suspensions.…

Statistical Mechanics · Physics 2023-10-27 Xiao Ma , Johannes Pausch , Michael E. Cates

We study the conformational properties of charged polymers in a solvent in the presence of structural obstacles correlated according to a power law $\sim x^{-a}$. We work within the continuous representation of a model of linear chain…

Soft Condensed Matter · Physics 2013-11-25 V. Blavatska , C. von Ferber

We study random heteropolymer chain with gaussian distribution of kinds of monomers. The long-range correlations between kinds of monomers were introduce. The mean-field analysis of such heteropolymer indicates the existence of infinite…

Soft Condensed Matter · Physics 2009-09-25 E. Sh. Mamasakhlisov , V. F. Morozov , M. S. Shahinian

Particle-particle correlation functions in ionic systems control many of their macroscopic properties. In this work, we use stochastic density functional theory to compute these correlations, and then we analyze their long-range behavior.…

Statistical Mechanics · Physics 2025-02-05 Haggai Bonneau , Vincent Démery , Elie Raphaël

The associative interaction, such as hydrogen bonding, can bring about versatile functionalities to polymer systems, which has been investigated by tremendous researches, but the fundamental understanding on association process is still…

Soft Condensed Matter · Physics 2025-01-20 Xiangyu Zhang , Dong Meng

Colloidal fluids can exhibit complex phase behavior and determining phase diagrams via experiments or computer simulations can be laborious. We demonstrate that the dispersion relation $\omega(k)$, obtained from dynamical density functional…

Soft Condensed Matter · Physics 2026-03-20 Michael Wassermair , Gerhard Kahl , Roland Roth , Andrew J. Archer

We develop a new quantitative molecular theory of liquid-phase dipolar polymer gels. We model monomer units of the polymer network as a couple of charged sites separated by a fluctuating distance. For the first time, within the random phase…

Soft Condensed Matter · Physics 2021-03-09 Yury A. Budkov , Nikolai N. Kalikin , Andrei L. Kolesnikov

We consider a two-dimensional Coulomb gas of positive and negative pointlike unit charges interacting via a logarithmic potential. The density (rather than the charge) correlation functions are studied. In the bulk, the form-factor theory…

Statistical Mechanics · Physics 2007-05-23 L. Šamaj , B. Jancovici

We derive a general relation between correlators of density of states fluctuations and density response functions. It applies equally to quantum chaotic systems of pure symmetry (unitary, orthogonal, and symplectic) as well as to the…

Condensed Matter · Physics 2009-10-28 N. Taniguchi , B. D. Simons , B. L. Altshuler

We consider an exclusion process on a ring in which a particle hops to an empty neighbouring site with a rate that depends on the number of vacancies $n$ in front of it. In the steady state, using the well known mapping of this model to the…

Statistical Mechanics · Physics 2014-12-30 Priyanka , Arvind Ayyer , Kavita Jain

These notes are devoted to the statistical mechanics of directed polymers interacting with one-dimensional spatial defects. We are interested in particular in the situation where frozen disorder is present. These polymer models undergo a…

Probability · Mathematics 2008-06-10 F. Toninelli

A mode-coupling theory for dense polymeric systems is developed which unifyingly incorporates the segmental cage effect relevant for structural slowing down and polymer chain conformational degrees of freedom. An ideal glass transition of…

Soft Condensed Matter · Physics 2009-11-07 S. -H. Chong , M. Fuchs

The fundamental interactions between an edge dislocation and a random solid solution are studied by analyzing dislocation line roughness profiles obtained from molecular dynamics simulations of Fe0.70Ni0.11 Cr0.19 over a range of stresses…

Conformational phases of a semiflexible off-lattice homopolymer model near an attractive substrate are investigated by means of multicanonical computer simulations. In our polymer-substrate model, nonbonded pairs of monomers as well as…

Computational Physics · Physics 2009-07-20 Monika Möddel , Michael Bachmann , Wolfhard Janke

By means of contact-density chain-growth simulations, we investigate a simple lattice model of a flexible polymer interacting with an attractive substrate. The contact density is a function of the numbers of monomer-substrate and…

Statistical Mechanics · Physics 2011-07-04 Michael Bachmann

We define a heteropolymer in a medium with random droplets. We prove that for this model we have two regimes: a delocalized one and a localized one. In the localized regime we prove tightness to the droplets, whereas in the delocalized…

Probability · Mathematics 2016-08-16 Mario V. Wüthrich

We study the adsorption of homogeneous or heterogeneous polymers onto heterogeneous planar surfaces with exponentially decaying site-site correlations, using a variational reference system approach. As a main result, we derive simple…

Soft Condensed Matter · Physics 2009-11-11 Alexey Polotsky , Friederike Schmid , Andreas Degenhard