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We use molecular dynamics simulations in two dimensions to investigate the possibility that a core-softened potential can reproduce static and dynamic anomalies found experimentally in liquid water: (i) the increase in specific volume upon…

Soft Condensed Matter · Physics 2009-10-31 A. Scala , M. Reza Sadr-Lahijany , N. Giovambattista , S. V. Buldyrev , H. E. Stanley

Nematic liquid crystals have been known for more than a century, but it was not until the 60s-70s that, with the development of room temperature nematics, they became widely used in applications. Polar nematic phases have been long-time…

Soft Condensed Matter · Physics 2021-08-17 Richard J. Mandle , Nerea Sebastián , Josu Martinez-Perdiguero , Alenka Mertelj

The influence of thermal processing on the potential energy, atomic structure, and mechanical properties of metallic glasses is examined using molecular dynamics simulations. We study the three-dimensional binary mixture, which was first…

Soft Condensed Matter · Physics 2019-12-23 Nikolai V. Priezjev

Crystallization within the discrete spheres of a block copolymer mesophase was studied by time-resolved x-ray scattering. The cubic packing of microdomains, established by self-assembly in the melt, is preserved throughout crystallization…

Soft Condensed Matter · Physics 2009-10-31 Yueh-Lin Loo , Richard A. Register , Anthony J. Ryan

Off-equilibrium dynamics of a three-dimensional lattice model with nearest- and next nearest-neighbors exclusions is studied. At equilibrium, the model undergoes a first-order fluid-solid transition. Non-equilibrium filling, through random…

Statistical Mechanics · Physics 2015-05-30 H. Levit , Z. Rotman , E. Eisenberg

We present a new reduced-order computational method for the molecular dynamics simulation of entangled polymer systems. The polymer chains are modeled as continuous Gaussian chains. Our algorithm is based on the application of the molecular…

Soft Condensed Matter · Physics 2020-09-02 Aruna Mohan , GH Fredrickson

We present Molecular Dynamics simulations of the thermal glass transition in a dense model polymer liquid. We performed a comparative study of both constant volume and constant pressure cooling of the polymer melt. Great emphasis was laid…

Statistical Mechanics · Physics 2009-10-30 C. Bennemann , W. Paul , K. Binder , B. Duenweg

We present fully atomistic Molecular Dynamics simulation results on a main-chain polymer, 1,4-Polybutadiene, in the merging region of the $\alpha$- and $beta$-relaxations. A real space analysis reveals the occurrence of localized motions…

Soft Condensed Matter · Physics 2015-06-25 Juan Colmenero , Arturo Narros , Fernando Alvarez , Arantxa Arbe , Angel J. Moreno

We study numerically the crystallization of a hard-sphere mixture with 8\% polydispersity. Although often used as a model glass former, for small system sizes we observe crystallization in molecular dynamics simulations. This opens the…

Soft Condensed Matter · Physics 2016-09-05 Matteo Campo , Thomas Speck

Performing molecular dynamics simulations for all-atom models, we characterize the conformational and structural relaxations of poly(ethylene oxide) and poly(propylene oxide) melts. The temperature dependence of these relaxation processes…

Soft Condensed Matter · Physics 2009-11-13 Michael Vogel

The glass transition in binary mixtures of star polymers is studied by mode coupling theory and extensive molecular dynamics computer simulations. In particular, we have explored vitrification in the parameter space of size asymmetry…

Star polymers can exhibit a heterogeneous dynamical behavior due to their internal structure. In this work we employ atomistic molecular dynamics simulations to study translational motion in non-entangled polystyrene and poly(ethylene…

Soft Condensed Matter · Physics 2021-02-03 Petra Bačová , Eirini Gkolfi , Laurence G. D. Hawke , Vagelis Harmandaris

Using molecular dynamics simulation we examine dynamics in sheared polycrystal states in a binary mixture containing 10% larger particles in two dimensions. We find large stress fluctuations arising from sliding motions of the particles at…

Soft Condensed Matter · Physics 2009-11-13 Toshiyuki Hamanaka , Akira Onuki

There is ample experimental evidence on the existence of several crystalline phases of C4F8, although they still have been not clearly identified. In this paper we perform a series of molecular dynamics (MD) simulations using a partially…

Soft Condensed Matter · Physics 2009-10-31 Z. Gamba , B. M. Powell

The molecular dynamics in the ambient-pressure solid phase of (1,1,2)-trichloroethane is studied by means of broadband dielectric spectroscopy and molecular dynamics simulations. The dielectric spectra of polycrystalline samples obtained by…

The long time dynamics of polymeric materials has been extensively studied in the past through various experimental techniques and computer simulations. While computer simulations typically treat generic, simplified models, experiments deal…

Soft Condensed Matter · Physics 2008-09-10 Vagelis A. Harmandaris , Kurt Kremer

By using molecular dynamics simulation, formation mechanisms of amorphous carbon in particular sp${}^3$ rich structure was researched. The problem that reactive empirical bond order potential cannot represent amorphous carbon properly was…

Materials Science · Physics 2015-06-05 Atsushi M. Ito , Arimichi Takayama , Seiki Saito , Hiroaki Nakamura

We report molecular dynamics simulations of a hydrophobic polymer-chain in aqueous solution between $260 {K}$ and $420 {K}$ at pressures of $1 {bar}$, $3000 {bar}$, and $4500 {bar}$. The simulations reveal a hydrophobically collapsed state…

Soft Condensed Matter · Physics 2017-09-13 Dietmar Paschek , Sascha Nonn , Alfons Geiger

Crystal growth and crystal coalescence processes in supercooled systems strongly depend on the concentration of crystallization centers. We perform atomistic dynamics simulations of the crystallization process in the ultrathin metallic film…

Materials Science · Physics 2019-09-04 Bulat N. Galimzyanov , Vladimir I. Ladyanov , Anatolii V. Mokshin

Below the melting temperature $T_m$ crystals are the stable phase of typical elemental or molecular systems. However, cooling down a liquid below $T_m$, crystallization is anything but inevitable. The liquid can be supercooled, eventually…

Disordered Systems and Neural Networks · Physics 2017-03-07 M. Zanatta , L. Cormier , L. Hennet , C. Petrillo , F. Sacchetti