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Structural features of the charge/orbital ordering (CO/OO) in single-layered manganites Pr1-xCa1+xMnO4 have been investigated systematically by transmission electron microscopy. Analyses of electron diffraction patterns as well as…

Strongly Correlated Electrons · Physics 2007-06-06 X. Z. Yu , R. Mathieu , T. Arima , Y. Kaneko , J. P. He , M. Uchida , T. Asaka , T. Nagai , K. Kimoto , A. Asamitsu , Y. Matsui , Y. Tokura

We have investigated the specific heat and resistivity of a single crystal of Pr_{0.63}Ca_{0.37}MnO_3 around the charge ordering (CO) transition temperature, T_{CO}, in the presence of high magnetic fields (<=12T) which can melt the charge…

Strongly Correlated Electrons · Physics 2007-05-23 K. S. Nagapriya , A. K. Raychaudhuri , Bhavtosh Bansal , V. Venkataraman , Sachin Parashar , C. N. R. Rao

In the manganite Nd0.5Ca0.5MnO3, charge ordering occurs at much higher temperature than the antiferromagnetic order (TCO=250K,TN=160K). The magnetic behavior of the phase TN<T<TCO is puzzling: its magnetization and susceptibility are…

Strongly Correlated Electrons · Physics 2016-08-31 F. millange , S. de Brion , G. Chouteau

We present a detailed study on the charge ordering (CO) transition in GdBaCo2O5 system by combining high resolution synchrotron powder/single crystal diffraction with electron paramagnetic resonance (EPR) experiments as a function of…

Strongly Correlated Electrons · Physics 2015-06-16 M. Allieta , M. Scavini , L. Lopresti , M. Coduri , L. Loconte , S. Cappelli , C. Oliva , P. Ghigna , P. Pattison , V. Scagnoli

Rare earth perovskites ($R^{3+}$M$^{3+}$O$_3$), with $e_g^1$ electronic occupation of the M $d$ states, display different types of metal-insulator transition. For manganites (M=Mn), metal-insulator transition is usually induced by the…

Strongly Correlated Electrons · Physics 2025-04-04 Subhadeep Bandyopadhyay , Philippe Ghosez

The interplay of charge, spin, and lattice degrees of freedom in matter leads to various forms of ordered states through phase transitions. An important subclass of these phenomena of complex materials is charge ordering (CO), mainly driven…

Strongly Correlated Electrons · Physics 2018-08-15 Arvind Yogi , C. I. Sathish , Hasung Sim , Matthew J. Coak , Y. Noda , Je-Geun Park

We report a x-ray resonant diffraction study of the perovskite Pr0.6Ca0.4MnO3. At the Mn K-edge, this technique is sensitive to details of the electronic structure of the Mn atoms. We discuss the resonant x-ray spectra measured above and…

Strongly Correlated Electrons · Physics 2009-11-10 S. Grenier , J. P. Hill , Doon Gibbs , K. J. Thomas , M. v. Zimmermann , C. S. Nelson , V. Kiryukhin , Y. Tokura , D. Casa , T. Gog , C. Venkataraman

We studied the crystal and magnetic structure of the La$_{1-x}$Ca$_{x}$MnO$_{3}$ compound for $(0.11\leq x\leq 0.175)$ using stoichiometric samples. For $x<0.13$ the system's ground state is insulating canted antiferromagnetic. For $0.13\le…

Strongly Correlated Electrons · Physics 2009-11-11 M. Pissas , I. Margiolaki , G. Papavassiliou , D. Stamopoulos , D. Argyriou

We report a temperature-dependent neutron diffraction (ND) study on polycrystalline monoclinic BaIrO$_3$ which is famous for charge density wave (CDW) and weak ferromagnetic phase transitions at T$_C$$\sim$180 K simultaneously. A Rietveld…

Strongly Correlated Electrons · Physics 2023-08-17 Bin Chang , Jinwon Jeong , Han-Jin Noh , Seongsu Lee

Measurements of the electrical and thermal conductivities, thermopower and paramagnetic susceptibility have been performed on single crystal samples of Bi1/2Sr1/2MnO3 and complemented with the X-ray powder diffraction data. A pronounced…

Strongly Correlated Electrons · Physics 2009-11-07 J. Hejtmanek , K. Knizek , Z. Jirak , M. Hervieu , C. Martin , M. Nevriva , P. Beran

By means of synchrotron x-ray and electron diffraction, we studied the structural changes at the charge order transition $T_{CO}$=176 K in the mixed-valence quadruple perovskite (NaMn$_3$)Mn$_4$O$_{12}$. Below $T_{CO}$ we find satellite…

Strongly Correlated Electrons · Physics 2015-06-23 A. Prodi , A. Daoud-Aladine , F. Gozzo , B. Schmitt , O. Lebedev , G. van Tendeloo , E. Gilioli , F. Bolzoni , H. Aruga-Katori , H. Takagi , M. Marezio , A. Gauzzi

It is argued that both transitions observed in 50%-doped manganites, at the N\'{e}el temperature ($T_{\rm N}$) and the so-called charge ordering temperature ($T_{\rm CO}$), are magnetic. $T_{\rm N}$ corresponds to the order-disorder…

Strongly Correlated Electrons · Physics 2007-05-23 I. V. Solovyev

Structural phase transition studies employing low-temperature transmission electron microscopy, and low-temperature x-ray diffraction have been carried out on nearly stoichiometric ({\delta}=0.01) and off-stoichiometric ({\delta}=0.12)…

Strongly Correlated Electrons · Physics 2014-03-10 Aga Shahee , R. J. Choudhary , R. Rawat , N. P. Lalla

New metal-ordered manganites RBaMn_{2}O_{6} have been synthesized and investigated in the structures and electromagnetic properties. RBaMn_{2}O_{6} can be classified into three groups from the structural and electromagnetic properties. The…

Strongly Correlated Electrons · Physics 2009-11-07 T. Nakajima , H. Kageyama , H. Yoshizawa , Y. Ueda

Low as well as high-temperature electron and x-ray diffraction studies have been carried out on a rare-earth free B-site disordered electron-doped manganite SrMn0.875.Mo0.125O3-{\delta} in the temperature range of 83K to 637K. These studies…

Strongly Correlated Electrons · Physics 2015-03-23 Aga Shahee , N. P. Lalla

A comprehensive study of Ge1-xMnxCo2O4 (GMCO) system was conducted using neutron powder diffraction (NPD), x-ray diffraction (XRD), Scanning electron microscopy, magnetometry, and heat capacity measurements. Comparative analysis with…

Single Crystals of Nd$_{1-x}$Ca$_{1+x}$MnO$_{4}$ have been prepared by the traveling floating-zone method, and possible evidence of a charge -orbital density wave in this material presented earlier [PRB68,092405 (2003)] using High…

Strongly Correlated Electrons · Physics 2015-06-25 Sher Alam , A. T. M. N. Islam , T. Nagai , M. Xu , Javed Ahmad , Y. Matsui , I. Tanaka

Density waves are inherent to the phase diagrams of materials that exhibit unusual, and sometimes extraordinarily useful properties, such as superconductivity and colossal magnetoresistance. While the pure charge density waves (CDW) are…

We observe how the charge-ordering (CO) temperature of Nd1/2Sr1/2MnO3 decreases with the external pressure p from 160 K at p = 0 down to 30 K at p ~ 4.5 GPa, by measuring the values p, T where the far-infrared spectral weight of the…

Strongly Correlated Electrons · Physics 2011-04-12 P. Maselli , D. Nicoletti , A. Nucara , F. M. Vitucci , A. Irizawa , K. Shoji , T. Nanba , P. Calvani

The low temperature phase of single crystals of Nd$_{0.5}$Ca$_{0.5}$MnO$_3$ and Gd$_{0.5}$Ca$_{0.5}$MnO$_3$ manganites is investigated by squid magnetometry. Nd$_{0.5}$Ca$_{0.5}$MnO$_3$ undergoes a charge-ordering transition at…

Materials Science · Physics 2016-08-31 R. Mathieu , P. Nordblad , A. R. Raju , C. N. R. Rao
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