Related papers: Criticality in strongly correlated fluids
We study a model in which particles interact through a hard-core repulsion complemented by a short-ranged attractive potential, of the kind found in colloidal suspensions. Combining theoretical and numerical work we locate the line of…
We study thermal equilibrium of classical pointlike counterions confined between symmetrically charged walls at distance $d$. At very large couplings when the counterion system is in its crystal phase, a harmonic expansion of particle…
We introduce a dissipative particle dynamics scheme for the dynamics of non-ideal fluids. Given a free-energy density that determines the thermodynamics of the system, we derive consistent conservative forces. The use of these effective,…
The subtle interplay between critical phenomena and electrostatics is investigated by considering the effective force acting on two parallel walls confining a near-critical binary liquid mixture with added salt. The ion-solvent coupling can…
Supercritical fluids near the critical point are characterized by liquid-like densities and gas-like transport properties. These features are purposely exploited in different contexts ranging from natural products extraction/fractionation…
Fluids in which the interparticle potential has a hard core, is attractive at moderate separations, and repulsive at greater separations are known to exhibit novel phase behavior, including stable inhomogeneous phases. Here we report a…
The one-component Coulomb gas on the sphere, consisting on $N$ unit charges interacting via a logarithmic potential, and in the presence of two external charges each of strength proportional to $N$, is considered. There are two spherical…
We study the phase behavior of a classical system of particles interacting through a strictly convex soft-repulsive potential which, at variance with the pairwise softened repulsions considered so far in the literature, lacks a region of…
We study the behavior of systems in which the interaction contains a long-range component that does not dominate the critical behavior. Such a component is exemplified by the van der Waals force between molecules in a simple liquid-vapor…
We examine the nature of the collective excitations in a strongly anisotropic system of bosons interacting via Coulomb interaction. Such a system has often been used in the past to model the effects of quantum and classical phase…
Liquids in equilibrium exhibit two types of disorder, simple and complex. Typical simple disorder liquid are liquid nitrogen, or weakly polar liquids. Complex liquids concern those who can form long lived local assemblies, and cover a large…
We study the liquid-vapor phase diagram and the structural properties of discrete potential fluids by means of Gibbs ensemble simulations and integral equations theory. We consider three discrete fluids, namely, the square well (SW), the…
We propose here a new mechanism of droplet coarsening in phase-separating fluid mixtures. In contrast to the conventional understanding that there are no interactions between droplets in the late stage of spinodal decomposition, we…
Hard models for particle interactions have played a crucial role in the understanding of the structure of condensed matter. In particular, they help to explain the formation of oriented phases in liquids made of anisotropic molecules or…
In recent works, we proposed a hypothesis that the turbulence in gases could be produced by particles interacting via a potential, and examined the proposed mechanics of turbulence formation in a simple model of two particles for a variety…
To reach a deeper understanding of fluid interfaces it is necessary to identify a meaningful coarse-graining length that separates intrinsic fluctuations from capillary ones, given the lack of a proper statistical mechanical definition of…
Starting from a microscopic approach, we develop a covariant formalism to describe a set of interacting gases. For that purpose, we model the collision term entering the Boltzmann equation for a class of interactions and then integrate this…
We investigate, for two water models displaying a liquid-liquid critical point, the relation between changes in dynamic and thermodynamic anomalies arising from the presence of the liquid-liquid critical point. We find a correlation between…
A mechanical interaction of compressible viscoelastic fluids with viscoelastic solids in Kelvin-Voigt rheology using the concept of higher-order (so-called 2nd-grade multipolar) viscosity is investigated in a quasistatic variant. The…
The structure of liquid water at ambient conditions is studied in ab initio molecular dynamics simulations using van der Waals (vdW) density-functional theory, i.e. using the new exchange-correlation functionals optPBE-vdW and vdW-DF2.…