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Related papers: The Hartree-Fock based diagonalization - an effici…

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We present here a review of the fundamental topics of Hartree-Fock theory in Quantum Chemistry. From the molecular Hamiltonian, using and discussing the Born-Oppenheimer approximation, we arrive to the Hartree and Hartree-Fock equations for…

Chemical Physics · Physics 2008-11-25 Pablo Echenique , J. L. Alonso

We present a density matrix approach for computing global solutions of Hartree-Fock theory, based on semidefinite programming (SDP), that gives upper and lower bounds on the Hartree-Fock energy of quantum systems. Equality of the upper- and…

Chemical Physics · Physics 2014-02-11 Srikant Veeraraghavan , David A. Mazziotti

In the limit of infinite spatial dimensions a thermodynamically consistent theory, which is valid for arbitrary value of the Coulombic interaction ($U<\infty$), is built for the Hubbard model when the total auxiliary single-site problem…

Strongly Correlated Electrons · Physics 2014-02-17 A. M. Shvaika

We study the Anderson-Hubbard model in the Hartree-Fock approximation and the exact diagonalization under the coexistence of short-range interaction and diagonal disorder. We show that there exist unconventional soft gaps, where the…

Strongly Correlated Electrons · Physics 2009-01-30 Hiroshi Shinaoka , Masatoshi Imada

The energy levels of the first few low-lying states of helium and lithium atoms in intense magnetic fields up to $\approx 10^8-10^9$~T are calculated in this study. A pseudospectral method is employed for the computational procedure. The…

Quantum Physics · Physics 2014-06-11 Anand Thirumalai , Jeremy S. Heyl

We investigate the influence of electron-electron interactions on the conductance of two-dimensional disordered spinless electrons. By using an efficient numerical method which is based on exact diagonalization in a truncated basis of…

Strongly Correlated Electrons · Physics 2009-10-31 Thomas Vojta , Frank Epperlein , Michael Schreiber

We investigate the influence of interactions and geometry on ground states of clean chaotic quantum dots using the self-consistent Hartree-Fock method. We find two distinct regimes of interaction strength: While capacitive energy…

Disordered Systems and Neural Networks · Physics 2009-10-31 Kang-Hun Ahn , Klaus Richter , In-Ho Lee

We present a method to calculate many-body states of interacting carriers in million atom quantum nanostructures based on atomistic tight-binding calculations and a combination of iterative selection of configurations and perturbation…

Mesoscale and Nanoscale Physics · Physics 2020-05-27 Moritz Cygorek , Matthew Otten , Marek Korkusinski , Pawel Hawrylak

Studying the electronic structure of defects in materials is an important subject in condensed matter physics. From a mathematical point of view, nonlinear mean-field models of localized defects in insulators are well understood. We present…

Mathematical Physics · Physics 2019-10-04 Éric Cancès , Ling-Ling Cao , Gabriel Stoltz

We develop a new method of implementing the Hartree-Fock calculations. A class of Gaussian bases is assumed, which includes the Kamimura-Gauss basis-set as well as the set equivalent to the harmonic-oscillator basis-set. By using the…

Nuclear Theory · Physics 2011-07-19 H. Nakada , M. Sato

Background: The Hartree-Fock mean-field approximation is standard in combination with energy density functionals (EDF) that account for some dynamical correlations. Breaking and restoring the symmetries of the system allow for the inclusion…

Nuclear Theory · Physics 2023-11-20 Joshua Cesca , Cédric Simenel

We present a robust, ab initio method for addressing atom-light interactions and apply it to photoionization of argon. We use a close-coupling ansatz constructed on a multi-configurational Hartree-Fock description of localized states and…

Atomic Physics · Physics 2015-06-12 T. Carette , J. M. Dahlström , L. Argenti , E. Lindroth

The time-dependent Hartree-Fock (TDHF) method is an approach to simulate the mean field dynamics of electrons within the assumption that the electrons move independently in their self-consistent average field and within the space of single…

Quantum Physics · Physics 2023-09-06 Sahil Gulania , Stephen K. Gray , Yuri Alexeev , Bo Peng , Niranjan Govind

We report on numerical studies of the energy spectrum and the localization properties in the double-layer quantum Hall system at $\nu = 1$. The Coulomb interaction is treated by the Hartree-Fock approximation, and the localization…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Jun-ichiro Watanabe , Tatsuya Nakajima

We develop a new numerical method to calculate the Landauer conductance through an interacting electron system in the first order perturbation or in the self-consistent Hartree-Fock approximation. It is applied to one and two dimensional…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Yoichi Asada

In our work we construct a Hamiltonian, whose eigenstates approximate the solutions of the self-consistent Hartree-Fock equations for nonrelativistic atoms and ions. Its eigenvalues are given by completely algebraic expressions and the…

Quantum Physics · Physics 2025-06-18 N. Q. San , O. D. Skoromnik , V. V. Triguk , I. D. Feranchuk

The Hartree-Fock exchange potential is fundamental for capturing quantum mechanical exchange effects but faces critical challenges in large-scale applications due to its nonlocal and computationally intensive nature. This study introduces a…

Chemical Physics · Physics 2025-09-03 Fei Xu

We test a set of multiconfigurational wavefunction approaches for calculating the ground state electron population for a two-site Anderson model representing a molecule on a metal surface. In particular, we compare (i) a Hartree Fock like…

Chemical Physics · Physics 2022-07-19 Junhan Chen , Wenjie Dou , Joseph Subotnik

We discuss some recent results on the statistics of the Coulomb Blockade in disordered quantum dots containing spinless interacting fermions using the self-consistent Hartree-Fock approximation. We concentrate on the regime r_s >~1, with…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Paul N. Walker , Gilles Montambaux , Yuval Gefen

A simple and commonly employed approximate technique with which one can examine spatially disordered systems when strong electronic correlations are present is based on the use of real-space unrestricted self-consistent Hartree-Fock wave…

Strongly Correlated Electrons · Physics 2009-11-13 X. Chen , A. Farhoodfar , T. McIntosh , R. J. Gooding , P. W. Leung