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Using the recently developed version of the GW method employing the one-site approximation and self-consistent quasiparticle basis set we calculated the electronic structure of 3d and 4d transition metals at experimental atomic volumes. The…

Strongly Correlated Electrons · Physics 2007-08-16 K. D. Belashchenko , V. P. Antropov , N. E. Zein

The fully self-consistent $GW$ (sc$GW$) method with the iterative solution of Dyson equation provides a consistent approach for describing the ground and excited states without any dependence on the mean-field reference. In this work, we…

Chemical Physics · Physics 2024-01-23 Vibin Abraham , Gaurav Harsha , Dominika Zgid

We present and benchmark a self-energy approach for quasiparticle energy calculations that goes beyond Hedin's $GW$ approximation by adding the full second-order self-energy (FSOS-$W$) contribution. The FSOS-$W$ diagram involves two…

Materials Science · Physics 2021-05-18 Yanyong Wang , Patrick Rinke , Xinguo Ren

Ab initio techniques for studying the optical and vibrational properties of materials are well-established, but only a few recent studies have focused on the interaction between excitons and atomic vibrations. In this paper, we revisit the…

Materials Science · Physics 2026-03-17 Rafael R. Del Grande , David A. Strubbe

Confined geometries such as semiconductor quantum dots are promising candidates for fabricating quantum computing devices. When several quantum dots are in proximity, spatial correlation between electrons in the system becomes significant.…

Mesoscale and Nanoscale Physics · Physics 2023-05-24 Dung. N. Pham , Sathwik Bharadwaj , L. R. Ram-Mohan

We introduce Gutzwiller wave functions for multi-band models with general on-site Coulomb interactions. As these wave functions employ correlators for the exact atomic eigenstates they are exact both in the non-interacting and in the atomic…

Strongly Correlated Electrons · Physics 2012-07-28 J. Bünemann , W. Weber , F. Gebhard

We formulate a Hartree-Fock-LAPW method for electronic band structure calculations. The method is based on the Hartree-Fock-Roothaan approach for solids with extended electron states and closed core shells where the basis functions of…

Materials Science · Physics 2016-08-31 A. V. Nikolaev , P. N. Dyachkov

The self-consistent GW band gaps are known to be significantly overestimated. We show that this overestimation is, to a large extent, due to the neglect of the contribution of the lattice polarization to the screening of the…

Materials Science · Physics 2015-06-15 Silvana Botti , Miguel A. L. Marques

GW calculations with fully self-consistent G and W -- based on the iterative solution of the Dyson equation -- provide an approach for consistently describing ground and excited states on the same quantum mechanical level. We show that for…

Materials Science · Physics 2012-09-27 Fabio Caruso , Patrick Rinke , Xinguo Ren , Matthias Scheffler , Angel Rubio

Similar to other electron correlation methods, many-body perturbation theory methods based on Green functions, such as the so-called $GW$ approximation, suffer from the usual slow convergence of energetic properties with respect to the size…

The $GW$ approximation has recently gained increasing attention as a viable method for the computation of deep core-level binding energies as measured by X-ray photoelectron spectroscopy (XPS). We present a comprehensive benchmark study of…

Chemical Physics · Physics 2022-06-14 Jiachen Li , Ye Jin , Patrick Rinke , Weitao Yang , Dorothea Golze

The GW method is a many-body approach capable of providing quasiparticle bands for realistic systems spanning physics, chemistry, and materials science. Despite its power, GW is not routinely applied to large complex materials due to its…

Materials Science · Physics 2020-01-29 Minjung Kim , Glenn J. Martyna , Sohrab Ismail-Beigi

This study examines how the GW approximation, one of the techniques covered by Green's functions and on many-body approximations (GFMBA), fares compared to the treatment of the Hubbard model solved using an exact diagonalization (ED)…

Strongly Correlated Electrons · Physics 2022-12-08 Antoine Honet , Luc Henrard , Vincent Meunier

We present a comparison of various approximations to self-consistency in the GW method, including the one-shot G0W0 method, different quasiparticle self-consistency schemes, and the fully self-consistent GW (scGW) approach. To ensure an…

Strongly Correlated Electrons · Physics 2025-10-17 Gaurav Harsha , Vibin Abraham , Ming Wen , Dominika Zgid

We present an approach for GW calculations of quasiparticle energies with quasi-quadratic scaling by approximating high-energy contributions to the Green's function in its Lehmann representation with effective stochastic vectors. The method…

Materials Science · Physics 2023-12-07 Aaron R. Altman , Sudipta Kundu , Felipe H. da Jornada

We describe a recent implementation of the combined GW and dynamical mean field (DMFT) method "GW+DMFT" for the two-dimensional Hubbard model with on-site and nearest-neighbor repulsion. We clarify the relation of the GW+DMFT scheme to…

Strongly Correlated Electrons · Physics 2013-04-01 Thomas Ayral , Silke Biermann , Philipp Werner

The GW method, which can describe accurately electronic excitations, is one of the most widely used ab initio electronic structure technique and allows the physics of both molecular and condensed phase materials to be studied. However, the…

The electronic structure of surfaces and interfaces plays a key role in the properties of quantum devices. Here, we study the electronic structure of realistic Al/InAs/Al heterojunctions using a combination of density functional theory…

Mesoscale and Nanoscale Physics · Physics 2024-11-06 H. Ness , F. Corsetti , D. Pashov , B. Verstichel , G. W. Winkler , M. van Schilfgaarde , R. M. Lutchyn

Several widely used methods for the calculation of band structures and photo emission spectra, such as the GW approximation, rely on Many-Body Perturbation Theory. They can be obtained by iterating a set of functional differential equations…

Strongly Correlated Electrons · Physics 2012-01-31 Giovanna Lani , Pina Romaniello , Lucia Reining

We propose a pseudopotential for the electron-electron Coulomb interaction to improve the efficiency of many-body electronic structure calculations. The pseudopotential accurately replicates the scattering properties of the Coulomb…

Strongly Correlated Electrons · Physics 2015-09-02 J. H. Lloyd-Williams , R. J. Needs , G. J. Conduit