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This paper presents a large-scale $ab$ $initio$ simulation study of amorphous silicon hydride ($a$-Si$_{\text{1-x}}$H$_{\text{x}}$) with an emphasis on the structure and properties of the material across a range of hydrogen concentration by…

Materials Science · Physics 2023-09-19 Raymond Atta-Fynn , Somilkumar J. Rathi , Harsh Arya , Parthapratim Biswas

Localized basis ab initio molecular dynamics simulation within the density functional framework has been used to generate realistic configurations of amorphous silicon carbide (a-SiC). Our approach consists of constructing a set of smart…

Disordered Systems and Neural Networks · Physics 2015-05-13 Raymond Atta-Fynn , Parthapratim Biswas

We propose a method to simulate a-Si and a-Si:H using an ab initio approach based on the Harris functional and thermally amorphisized periodically continued cells with at least 64 atoms, and calculate their radial distribution functions.…

Materials Science · Physics 2009-10-31 Ariel A. Valladares , Fernando Alvarez , Zhihua Liu , Juergen Stitcht , John Harris

We present a first-principles study of the structural, electronic, and optical properties of hydrogenated amorphous silicon (a-Si:H). To this end, atomic configurations of a-Si:H with 72 and 576 atoms respectively are generated using…

Materials Science · Physics 2017-03-31 Philippe Czaja , Urs Aeberhard , Massimo Celino , Simone Giusepponi , Michele Gusso

We present a tight-binding calculation that, for the first time, accurately describes the structural, vibrational and elastic properties of amorphous silicon. We compute the interatomic force constants and find an unphysical feature of the…

Materials Science · Physics 2009-11-10 J. L. Feldman , N. Bernstein , D. A. Papaconstantopoulos , M. J. Mehl

By means of molecular dynamics simulations based on the Billeter et al. [S. R. Billeter, A. Curioni, D. Fischer, and W. Andreoni, Phys. Rev. B {\bf 73}, 155329] environment-dependent classical force field we studied the structural features…

Disordered Systems and Neural Networks · Physics 2015-05-27 Mariella Ippolito , Simone Meloni

Rings comprising chemically bonded atoms are essential topological motifs for the structural ordering of network-forming materials. Quantification of such larger motifs beyond short-range pair correlation is essential for understanding the…

Materials Science · Physics 2023-11-15 Motoki Shiga , Akihiko Hirata , Yohei Onodera , Hirokazu Masai

We present new atomistic models of amorphous silicon (a-Si) and hydrogenated amorphous silicon (a-Si:H) surfaces. The a-Si model included 4096 atoms and was obtained using local orbital density functional theory. By analyzing a slab model…

Materials Science · Physics 2025-06-24 Kishor Nepal , Aashish Gautam , Chinonso Ugwumadu , David Drabold

Preparing realistic atom-scale models of amorphous silicon (a-Si) is a decades-old condensed matter physics challenge. Herein, we combine the Activation Relaxation Technique nouveau (ARTn) to a Moment Tensor Potential (MTP) to generate…

Disordered Systems and Neural Networks · Physics 2025-03-25 Karim Zongo , Hao Sun , Claudiane Ouellet-Plamondon , Normand Mousseau , Laurent Karim Béland

The progress of miniaturisation in integrated electronics has led to atomic and nanometre-sized dopant devices in silicon. Such structures can be fabricated routinely by hydrogen resist lithography, using various dopants such as phosphorous…

Amorphous silicon (a-Si) models are analyzed for structural, electronic and vibrational characteristics. Several models of various sizes have been computationally fabricated for this analysis. It is shown that a recently developed…

Disordered Systems and Neural Networks · Physics 2018-11-29 Dale Igram , Bishal Bhattarai , Parthapratim Biswas , D. A. Drabold

We have performed an approximate ab initio calculation of vibrational properties of hydrogenated amorphous silicon (a-Si:H) using a molecular dynamics method. A 216 atom model for pure amorphous silicon (a-Si) has been employed as a…

Disordered Systems and Neural Networks · Physics 2009-10-31 Serge M. Nakhmanson , D. A. Drabold

Since the pioneering efforts of Duwez and coworkers in 1965, when a solid amorphous phase of Pd-Si ($a$-PdSi) was obtained in the vicinity of the eutectic concentration, much work has been done. However, some points related to the atomic…

As molecular dynamics is increasingly used to characterize non-crystalline materials, it is crucial to verify that the numerical model is accurate enough, consistent with experimental data and can be used to extract various characteristics…

Disordered Systems and Neural Networks · Physics 2008-11-17 F. Gaspari , I. M. Kupchak , A. I. Shkrebtii , J. M. Perz

We present a computational study of small-angle X-ray scattering (SAXS) in amorphous silicon ($a$-Si) with particular emphasis on the morphology and microstructure of voids. The relationship between the scattering intensity in SAXS and the…

Disordered Systems and Neural Networks · Physics 2018-05-23 Durga Paudel , Raymond Atta-Fynn , David A. Drabold , Stephen R. Elliott , Parthapratim Biswas

We report on the production of ordered assemblies of silicon nanostructures by means of irradiation of a Si(100) substrate with 1.2 keV Ar ions at normal incidence. Atomic Force and High-Resolution Transmission Electron microscopies show…

Materials Science · Physics 2009-11-07 Raul Gago , Luis Vazquez , Rodolfo Cuerno , Maria Varela , Carmen Ballesteros , Jose M. Albella

A novel approach to predict the atomic densities of amorphous materials is explored on the basis of Car-Parrinello molecular dynamics (CPMD) in density functional theory. Despite that determination of the atomic density of matter is crucial…

Disordered Systems and Neural Networks · Physics 2018-01-17 Yoritaka Furukawa , Yu-ichiro Matsushita

The nanostructure of hydrogenated amorphous silicon (a Si:H) is studied by a combination of small-angle X-ray (SAXS) and neutron scattering (SANS) with a spatial resolution of 0.8 nm. The a-Si:H materials were deposited using a range of…

Materials Science · Physics 2020-11-04 Eike Gericke , Jimmy Melskens , Robert Wendt , Markus Wollgarten , Armin Hoell , Klaus Lips

We study via density functional-based molecular dynamics the structural and dynamical properties of the rare earth silicon amorphous alloy Y_xSi_{1-x} for x=0.093 and x=0.156. The Si network forms cavities in which a Y^{3+} cation is…

Materials Science · Physics 2009-10-31 V. Meregalli , M. Parrinello

Silicene is the counterpart of graphene and its potential applications as a part of the current electronics, based in silicon, make it a very important system to study. We perform molecular dynamics simulations and analyze the structure of…

Materials Science · Physics 2012-04-13 M. R. Chavez-Castillo , M. A. Rodriguez-Meza , L. Meza-Montes
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