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We develop a scheme for building the scalar exchange-correlation (xc) kernel of time-dependent density functional theory (TDDFT) from the tensorial kernel of time-dependent {\em current} density functional theory (TDCDFT) and the Kohn-Sham…

Materials Science · Physics 2009-11-13 V. U. Nazarov , J. M. Pitarke , Y. Takada , G. Vignale , Y. -C. Chang

The idea of exciton condensation in solids was introduced in 1960's with the analogy to superconductivity in mind. While exciton supercurrents have been realized only in artificial quantum-well structures so far, the application of the…

Strongly Correlated Electrons · Physics 2015-07-30 Jan Kunes

In organic semiconductors working under ambient circumstance, there are remarkable quantum effects lack of comprehensive understanding, and an exotic composite particle named charge transfer (CT) exciton is normally regarded as the key…

Mesoscale and Nanoscale Physics · Physics 2021-12-07 Yao Yao

In this work we perform electron energy-loss spectroscopy (EELS) of freestanding graphene with high energy and momentum resolution to disentangle the quasielastic scattering from the excitation gap of Dirac electrons close to the optical…

Time-dependent density-functional theory (TDDFT) is a computationally efficient first-principles approach for calculating optical spectra in insulators and semiconductors, including excitonic effects. We show how exciton wave functions can…

Materials Science · Physics 2020-12-29 Jared R. Williams , Nicolas Tancogne-Dejean , Carsten A. Ullrich

Time-dependent density functional theory is extended to include dissipative systems evolving under a master equation, providing a Hamiltonian treatment for molecular electronics. For weak electric fields, the isothermal conductivity is…

Materials Science · Physics 2007-05-23 Kieron Burke , Roberto Car , Ralph Gebauer

Exciton formation leads to J-bands in solid pentacene. Describing these exciton bands represents a challenge for both time-dependent (TD) density-functional theory (DFT) and for its semiempirical analogue, namely for TD density-functional…

Monolayer transition metal dichalcogenides (TMDs) exhibit a remarkably strong Coulomb interaction that manifests in tightly bound excitons. Due to the complex electronic band structure exhibiting several spin-split valleys in the conduction…

The nonlocal correlation mechanism between excitonic pairs is considered for a two dimensional exciton system. On the base of the unitary decomposition of the usual electron operator, we include the electron phase degrees of freedom into…

Strongly Correlated Electrons · Physics 2015-08-04 V. Apinyan , T. K. Kopeć

The charge-density response of extended materials is usually dominated by the collective oscillation of electrons, the plasmons. Beyond this feature, however, intriguing many-body effects are observed. They cannot be described by one of the…

Materials Science · Physics 2018-12-20 Martin Panholzer , Matteo Gatti , Lucia Reining

We investigate a number of formal properties of the adiabatic strictly-correlated electrons (SCE) functional, relevant for time-dependent potentials and for kernels in linear response time-dependent density functional theory. Among the…

Strongly Correlated Electrons · Physics 2016-08-24 Giovanna Lani , Simone di Marino , Augusto Gerolin , Robert van Leeuwen , Paola Gori-Giorgi

The optical excitation spectra and excitonic resonances are investigated in systematically functionalized SiC with Fluorine and/or Chlorine utilizing density functional theory in combination with many-body perturbation theory. The latter is…

Materials Science · Physics 2017-11-22 L. B. Drissi , F. Z. Ramadan , S. Lounis

We elucidate the close relationship between spontaneous time-reversal symmetry breaking and the physics of excitonic instabilities in strongly correlated multiband systems. The underlying mechanism responsible for the spontaneous breaking…

Strongly Correlated Electrons · Physics 2014-01-17 Wei Liu , Alexander Punnoose

Using exact numerical techniques we investigate the nature of excitonic (electron-hole) bound states and the development of exciton coherence in the one-dimensional half-filled extended Falicov-Kimball model. The ground-state phase diagram…

Strongly Correlated Electrons · Physics 2014-01-15 S. Ejima , T. Kaneko , Y. Ohta , H. Fehske

A fundamental property of a quantum system driven by an external field is that when the field is turned off the positions of its response frequencies are independent of the time at which the field is turned off. We show that this leads to…

Chemical Physics · Physics 2015-05-29 Johanna I. Fuks , Kai Luo , Ernesto D. Sandoval , Neepa T. Maitra

Excitons, Coulomb-driven bound states of electrons and holes, are typically composed of integer charges. However, in bilayer systems influenced by charge fractionalization, a more exotic form of interlayer exciton can emerge, where pairing…

Mesoscale and Nanoscale Physics · Physics 2025-01-14 Naiyuan J. Zhang , Ron Q. Nguyen , Navketan Batra , Xiaoxue Liu , Kenji Watanabe , Takashi Taniguchi , D. E. Feldman , J. I. A. Li

We present an exact expression for the frequency-dependent Kohn-Sham exact-exchange (EXX) kernel for periodic insulators, which can be employed for the calculation of electronic response properties within time-dependent (TD)…

Materials Science · Physics 2016-08-31 Yong-Hoon Kim , Andreas Goerling

Using first-principles GW plus Bethe-Salpeter equation calculations, we identify anomalously strong excitonic effects in several vacancy-ordered double perovskites Cs2MX6 (M = Ti, Zr; X = I, Br). Giant exciton binding energies about 1 eV…

Computational Physics · Physics 2023-06-21 Fan Zhang , Weiwei Gao , Greis J. Cruz , Yi-yang Sun , Peihong Zhang , Jijun Zhao

We present here a formalism based on time-dependent density-functional theory (TDDFT) to describe characteristics of both intra- and inter-valley excitons in semiconductors, the latter of which had remained a challenge. Through the usage of…

Materials Science · Physics 2023-05-10 Jia Shi , Volodymyr Turkowski , Duy Le , Talat S. Rahman

In this work, we analyze the excitonic gap generation in the strong-coupling regime of thin films of three-dimensional time-reversal-invariant topological insulators. We start by writing down the effective gauge theory in 2+1-dimensions…

Strongly Correlated Electrons · Physics 2017-09-13 N. Menezes , C. Morais Smith , Giandomenico Palumbo