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Three novel precipitation strengthened bcc alloys which exhibit a smooth microstructural gradient with composition have been fabricated in bulk form by induction casting. All three alloys are comprised of a mixture of disordered A2-(Fe, Cr)…

Materials Science · Physics 2021-03-23 Silas Wolff-Goodrich , Sebastian Haas , Uwe Glatzel , Christian Liebscher

We investigate the specific influence of structural disorder on the suppression of antiferromagnetic order and on the emergence of cuprate superconductivity. We single out pure disorder, by focusing on a series of…

Cu$_2$IrO$_3$ is a honeycomb iridate which has been studied recently as a candidate Kitaev quantum spin liquid. Its magnetic ground state however, has been reported to be quantum disordered, spin glassy, or magnetically ordered depending on…

Precipitation in Mg-Zn alloys was analyzed by means of first principles calculations. Formation energies of symmetrically distinct hcp Mg1-xZnx (0 < x < 1) configurations were determined and potential candidates for Guinier-Preston zones…

Materials Science · Physics 2020-10-07 S. Liu , G. Esteban-Manzanares , J. LLorca

The high strength of structural aluminium alloys depends strongly on the controlled precipitation of specific intermetallic phases, whose identity and crystal structure can be difficult to predict. Here, we investigate the Al-Pt system,…

Materials Science · Physics 2023-06-14 Shenghan Su , Laure Bourgeois , Nikhil V. Medhekar

Precipitation patterns emerging in a 2D moving front are investigated on the example of NaOH diffusing into a gel containing AlCl_3. The time evolution of the precipitate Al(OH)_3 can be observed since the precipitate redissolves in the…

Statistical Mechanics · Physics 2015-05-14 A. Volford , I. Lagzi , F. Molnar , Z. Racz

Monte Carlo simulations have been performed for aqueous charged colloidal suspensions as a function of charge density on the particles and salt concentration. We vary the charge density in our simulations over a range where a reentrant…

Soft Condensed Matter · Physics 2007-05-23 P. S. Mohanty , B. V. R. Tata

Solid-state homogeneous precipitation of nano-sized precipitates is one of the most effective processes to strengthen metal alloys, where the final density and size distribution of precipitates are largely controlled by the precipitation…

The AlCrTiV high entropy alloy undergoes an order-disorder transition from body centered cubic (Strukturbericht A2) at high temperatures to the CsCl structure (B2) at intermediate temperatures. We model this transition using first…

Materials Science · Physics 2024-07-02 Michael Widom

As pointed out by Linus Pauling in his classic work on the relationship between crystal packing and ionic radius ratio, a difference in atomic size can be accommodated more readily by an ordered structure than by a disordered one. Because…

Materials Science · Physics 2007-05-23 Dean J. Lee , Jong K. Lee

Substrate disorder effects on the scaling properties of growing crystalline surfaces in solidification or epitaxial deposition processes are investigated. Within the harmonic approach there is a phase transition into a low-temperature…

Condensed Matter · Physics 2016-08-31 Yan-Chr Tsai , Yonathan Shapir

Structural phase transitions often couple to magnetic and electronic degrees of freedom, enabling emergent phenomena in solids. In high-entropy oxides (HEOs), which typically stabilize in highly symmetric cubic phases, such transitions are…

A detailed study of the precipitation of the \gamma' (AlAg2) phase in undeformed aluminium-silver alloys has been conducted. Several previously unreported features were observed, including the formation of discrete three-dimensional…

Materials Science · Physics 2012-03-05 Julian M. Rosalie , Laure Bourgeois , Barrington C. Muddle

Formation and dynamics of an Al(OH)_3 precipitation ring is studied by diffusing NaOH into a gel containing AlCl_3. Limited feeding of the outer electrolyte (NaOH) is found to yield an intricate ring-dynamics which involves stopping and…

Chemical Physics · Physics 2007-05-23 Istvan Lagzi , Peter Papai , Zoltan Racz

Pressure-induced transitions from ordered intermetallic phases to substitutional alloys to semi-ordered phases were studied in a series of bismuth tellurides. Using angle-dispersive x-ray diffraction, the compounds Bi4Te5, BiTe, and Bi2Te…

Materials Science · Physics 2016-06-28 I. Loa , J. -W. G. Bos , R. A. Downie , K. Syassen

We apply a combinatorial approach to study the influence of Mg concentration on the precipitation kinetics in an Al-Cu-Li alloy using a diffusion couple made by linear friction welding. The precipitation kinetics is monitored in the…

We report structural evidence of dynamic reorganization in vortex matter in clean NbSe$_2$ by joint small angle neutron scattering and ac-susceptibility measurements. The application of oscillatory forces in a transitional region near the…

Superconductivity · Physics 2015-08-12 M. Marziali Bermúdez , M. R. Eskildsen , M. Bartkowiak , G. Nagy , V. Bekeris , G. Pasquini

A new family of high-strength Al-alloys has recently been developed, tailored for the powder bed fusion-laser beam process. In these alloys, Mn, Cr and Zr are incorporated in solid solution at amounts up to three times that of equilibrium…

We present Monte Carlo simulations of surface induced disordering in a model of a binary alloy on a bcc lattice which undergoes a first order bulk transition from the ordered DO3 phase to the disordered A2 phase. The data are analyzed in…

Statistical Mechanics · Physics 2009-10-31 F. F. Haas , F. Schmid , K. Binder

The bilayer perovskite La$_3$Ni$_2$O$_7$ has recently been found to enter a superconducting state under hydrostatic pressure at temperatures as high as 80 K. The onset of superconductivity is observed concurrent with a structural transition…

Superconductivity · Physics 2024-04-15 Luke C. Rhodes , Peter Wahl