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Evidence for another phase transition at 120 K in the metallic pyrochlore oxide Cd2Re2O7, following the structural transition at 200 K and followed by the superconducting transition at 1.0 K, is given through resistivity, magnetoresistance,…

Strongly Correlated Electrons · Physics 2009-11-07 Zenji Hiroi , Jun-Ichi Yamaura , Yuji Muraoka , Masafumi Hanawa

Superconducting and structural phase transitions in a pyrochlore oxide Cd2Re2O7 are studied under high pressure by x-ray diffraction and electrical resistivity measurements. A rich P-T phase diagram is obtained, which contains at least two…

We report the first pyrochlore oxide superconductor Cd2Re2O7. Resistivity,magnetic susceptibility,and specific heat measurements on single crystals evidence a bulk superconductivity at 1 K. Another phase transition found at 200 K suggests…

Superconductivity · Physics 2019-08-17 M. Hanawa , Y. Muraoka , T. Tayama , T. Sakakibara , J. Yamaura , Z. Hiroi

It is shown that both structural phase transitions in Cd2Re2O7, which occur at T_{s1}=200 K and T_{s2}=120 K, are due to an instability of the Re tetrahedral network with respect to the same doubly degenerate long-wavelength phonon mode.…

Superconductivity · Physics 2009-11-10 I. A. Sergienko , S. H. Curnoe

We report the X-ray study for the pyrochlore oxide Cd2Re2O7. Two symmetry-lowering structural transitions were observed at Ts1=200K and Ts2=120K. The former is of the second order from the ideal cubic pyrochlore structure with space group…

Strongly Correlated Electrons · Physics 2009-11-07 Jun-Ichi Yamaura , Zenji Hiroi

We report the superconducting properties of the pyrochlore oxide Cd2Re2O7. The bulk superconducting transition temperature Tc is about 1.0 K, and the upper critical field Hc2 determined by the measurement of specific heat under magnetic…

Superconductivity · Physics 2009-11-07 Z. Hiroi , M. Hanawa

Single crystal X-ray diffraction measurements have been carried out on Cd_2Re_2O_7 near and below the phase transition it exhibits at Tc' ~195 K. Cd_2Re_2O_7 was recently discovered as the first, and to date only, superconductor with the…

Strongly Correlated Electrons · Physics 2009-11-07 J. P. Castellan , B. D. Gaulin , J. van Duijn , M. J. Lewis , M. D. Lumsden , R. Jin , J. He , S. E. Nagler , D. Mandrus

The superconducting pyrochlore oxide Cd2Re2O7 (Tc = 1 K), which is now considered as a candidate of the spin-orbit-coupled metal, shows an inversion-symmetry-breaking structural transition at Ts1 = 200 K. Ts1 decreases with increasing…

Strongly Correlated Electrons · Physics 2018-04-30 Yasuhito Matsubayashi , Takumi Hasegawa , Norio Ogita , Jun-ichi Yamaura , Zenji Hiroi

Electronic properties of the metallic pyrochlore oxide Cd2Re2O7 are studied by means of electrical resistivity and Hall measurements. Semimetallic band structures are revealed as expected from band structure calculations. It is found that…

Strongly Correlated Electrons · Physics 2009-11-07 Z. Hiroi , M. Hanawa , Y. Muraoka , H. Harima

Rattling-induced superconductivity in the {\beta}-pyrochlore oxide KOs2O6 is investigated under high pressure up to 5 GPa. Resistivity measurements in a high-quality single crystal reveal a gradual decrease in the superconducting transition…

The superconducting pyrochlore oxide Cd2Re2O7 is revisited with a particular emphasis on the sample-quality issue. The compound has drawn attention as the only superconductor (Tc = 1.0 K) that has been found in the family of…

Superconductivity · Physics 2017-12-27 Zenji Hiroi , Jun-ichi Yamaura , Tatsuo C. Kobayashi , Yasuhito Matsubayashi , Daigorou Hirai

Another phase transition that is probably of first order is found in the beta-pyrochlore oxide superconductor KOs2O6 with a superconducting transition temperature Tc of 9.6 K. It takes place at Tp=7.5 K in the superconducting state in a…

Superconductivity · Physics 2015-06-25 Z Hiroi , S Yonezawa , J Yamaura

We report the observation of superconductivity in high-quality Cd$_2$Re$_2$O$_7$ single crystals with room-temperature pyrochlore structure. Resistivity and ac susceptibility measurements establish an onset transition temperature…

Superconductivity · Physics 2009-11-07 R. Jin , J. He , S. McCall , C. S. Alexander , F. Drymiotis , D. Mandrus

We examine the resistivity and thermopower of single crystal specimens of the pyrochlore oxide Cd2Re2O7 at pressures up to 2GPa. Thermopower proves to be a sensitive tool in the study of the phase diagram of Cd2Re2O7. The 200K…

Strongly Correlated Electrons · Physics 2009-11-10 N. Barisic , L. Forro , D. Mandrus , R. Jin , J. He , P. Fazekas

We make the first report that a metallic pyrochlore oxide \Cd2Re2O7, exhibits type II superconductivity at 1.1 K. The pyrochlore oxide is known to be a geometrical frustrated system, which includes the tetrahedral network of magnetic ions.…

Strongly Correlated Electrons · Physics 2016-08-16 H. Sakai , K. Yoshimura , H. Ohno , H. Kato , S. Kambe , R. E. Walstedt , T. D. Matsuda , Y. Haga , Y. Ōnuki

The 5d-transition metal pyrochlore oxide Cd2Re2O7, which was recently suggested to be a prototype of the spin-orbit-coupled metal [Phys. Rev. Lett. 115, 026401 (2015)], exhibits an inversion-symmetry breaking (ISB) transition at 200 K and a…

Strongly Correlated Electrons · Physics 2017-01-13 Jun-ichi Yamaura , Keiki Takeda , Yoichi Ikeda , Naohisa Hirao , Yasuo Ohishi , Tatsuo C. Kobayashi , Zenji. Hiroi

We report a density-functional theory study of the structural and electronic properties of Cd2V2O7 under high-pressure conditions. The calculations have been performed by using first-principle calculations with the CRYSTAL program. The…

Materials Science · Physics 2022-05-23 Daniel Diaz-Anichtchenko , Daniel Errandonea

Pressure dependence of superconducting transition temperature $T_{\rm c}$ has been determined through the DC magnetic measurements under pressure up to $P$=10 GPa for $\beta$-pyrochlore oxides AOs$_2$O$_6$ with A=Cs ($T_{\rm c}$=3.3 K), Rb…

Superconductivity · Physics 2009-11-13 K. Miyoshi , Y. Takaichi , Y. Takamatsu , M. Miura , J. Takeuchi

We report a structural transition found in Ca10(Ir4As8)(Fe2-xIrxAs2)5, which exhibits superconductivity at 16 K. The c-axis parameter is doubled below a structural transition temperature of approximately 100 K, while the tetragonal symmetry…

This article reports the experimentally clarified crystal structure of a recently discovered sulfur hydride in high temperature superconducting phase which has the highest critical temperature Tc over 200 K which has been ever reported. For…

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