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We develop a general theory describing the thermodynamical behavior of open quantum systems coupled to thermal baths beyond perturbation theory. Our approach is based on the exact time-local quantum master equation for the reduced open…

Quantum Physics · Physics 2022-05-31 Alessandra Colla , Heinz-Peter Breuer

A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…

Statistical Mechanics · Physics 2015-03-30 Tatsuhiko N. Ikeda , Naoyuki Sakumichi , Anatoli Polkovnikov , Masahito Ueda

The Brownian motion of a quantum particle in a harmonic confining potential and coupled to a harmonic quantum thermal bath is exactly solvable. It is shown that at low enough temperatures the stationary state is non-Gibbsian due to an…

Statistical Mechanics · Physics 2007-05-23 Th. M. Nieuwenhuizen , A. E. Allahverdyan

We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy (H-function) is not just a Lyapunov function…

Statistical Mechanics · Physics 2015-05-13 H. -H. Hasegawa , J. Ishikawa , K. Takara , D. J. Driebe

The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of entropy in irreversible adiabatic processes that take one equilibrium state to another. The entropy…

Soft Condensed Matter · Physics 2009-10-30 Elliott H. Lieb , Jakob Yngvason

Based on the recent work [1,2], we formulate the first law and the second law of stochastic thermodynamics in the framework of general relativity. These laws are established for a charged Brownian particle moving in a heat reservoir and…

General Relativity and Quantum Cosmology · Physics 2025-01-09 Tao Wang , Yifan Cai , Long Cui , Liu Zhao

Recently, there has been a considerable progress on the issue of the thermodynamic second law, which is known as the law of entropy increase or irreversibility. In particular, a novel symmetry known as the Gallavotti-Cohen symmetry is found…

Statistical Mechanics · Physics 2018-08-01 Hyunggyu Park

We show how the macroscopic state variables pressure, entropy and temperature of equilibrium thermodynamics can be consistently derived from the (quantum) chaotic spectral structure of one or two particles in two-dimensional domains. This…

This paper is a non-technical, informal presentation of our theory of the second law of thermodynamics as a law that is independent of statistical mechanics and that is derivable solely from certain simple assumptions about adiabatic…

Mathematical Physics · Physics 2009-10-31 Elliott H. Lieb , Jakob Yngvason

We derive a generalization of the Second Law of Thermodynamics that uses Bayesian updates to explicitly incorporate the effects of a measurement of a system at some point in its evolution. By allowing an experimenter's knowledge to be…

Statistical Mechanics · Physics 2017-04-04 Anthony Bartolotta , Sean M. Carroll , Stefan Leichenauer , Jason Pollack

Statistical mechanics descriptions of the second law of thermodynamics generally imply point-like particles driven by a dissipative overall mechanism for their simultaneous time-evolution. As the number of involved particles grows larger,…

General Physics · Physics 2016-02-16 Hans R. Moser

The Gibbs distribution universally characterizes states of thermal equilibrium. In order to extend the Gibbs distribution to non-equilibrium steady states, one must relate the self-information $\mathcal{I}(x) = -\log(P_\text{ss}(x))$ of…

Statistical Mechanics · Physics 2023-04-04 Nahuel Freitas , Massimiliano Esposito

We prove the second law of thermodynamics and the nonequilibirum fluctuation theorem for pure quantum states.The entire system obeys reversible unitary dynamics, where the initial state of the heat bath is not the canonical distribution but…

Statistical Mechanics · Physics 2017-09-13 Eiki Iyoda , Kazuya Kaneko , Takahiro Sagawa

We establish quantum thermodynamics for open quantum systems weakly coupled to their reservoirs when the system exhibits degeneracies. The first and second law of thermodynamics are derived, as well as a finite-time fluctuation theorem for…

Statistical Mechanics · Physics 2017-03-08 Gregory Bulnes Cuetara , Massimiliano Esposito , Gernot Schaller

There is a current interest in quantum thermodynamics in the context of open quantum systems. An important issue is the consistency of quantum thermodynamics, in particular the second law of thermodynamics, i.e., the flow of heat from a hot…

Quantum Physics · Physics 2024-07-30 Hans C. Fogedby

The second law of thermodynamics for adiabatic operations -- constraints on state transitions in closed systems under external control -- is one of the fundamental principles of thermodynamics. On the other hand, it is recently established…

Statistical Mechanics · Physics 2026-02-09 Yuuya Chiba , Yasushi Yoneta , Ryusuke Hamazaki , Akira Shimizu

We develop a Lindblad framework for quantum stochastic thermodynamics to study the nonequilibrium thermodynamics of open quantum systems. Our approach adopts the local quantum detailed balance condition, ensuring thermodynamic consistency…

Quantum Physics · Physics 2025-02-28 Jin-Fu Chen

We present a general framework for systems which are prepared in a non-stationary non-equilibrium state in the absence of any perturbation, and which are then further driven through the application of a time-dependent perturbation. We…

Statistical Mechanics · Physics 2012-12-06 Gatien Verley , David Lacoste

Quantum Thermodynamics is a continuous dialogue between two independent theories: Thermodynamics and Quantum Mechanics. Whenever the two theories addressed the same phenomena new insight has emerged. We follow the dialogue from equilibrium…

Quantum Physics · Physics 2018-06-04 Robert Alicki , Ronnie Kosloff

In textbooks on statistical mechanics, one finds often arguments based on classical mechanics, phase space and ergodicity in order to justify the second law of thermodynamics. However, the basic equations of motion of classical mechanics…

Statistical Mechanics · Physics 2014-08-28 Barbara Drossel