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We investigate by means of a number of different dynamical Monte Carlo simulation methods the self-assembly of equilibrium polymers in dilute, semidilute and concentrated solutions under good-solvent conditions. In our simulations, both…

Statistical Mechanics · Physics 2009-10-31 J. P. Wittmer , P. van der Schoot , A. Milchev , J. -L. Barrat

It has been established that the entangled polymer dynamics can be reasonably described by single chain models such as tube and slip-link models. Although the entanglement effect is a result of the hard-core interaction between chains,…

Soft Condensed Matter · Physics 2015-06-11 Takashi Uneyama , Yuichi Masubuchi

The impact of confinement on self-assembly of particles interacting with short-range attraction and long-range repulsion (SALR) potential is studied for thermodynamic states corresponding to local ordering of clusters or layers in the bulk.…

Soft Condensed Matter · Physics 2014-11-17 Jakub Pękalski , Alina Ciach , Noé G. Almarza

The phase behavior is investigated for systems composed of a large number of macromolecular components N, with N greater or equal to 2. Liquid-liquid phase separation is modelled using a virial expansion up to the second order of the…

Soft Condensed Matter · Physics 2024-05-29 Arjen Bot , Erik van der Linden , Paul Venema

Finite-dimensional signatures of spinodal criticality are notoriously difficult to come by. The dynamical transition of glass-forming liquids, first described by mode-coupling theory, is a spinodal instability preempted by thermally…

Statistical Mechanics · Physics 2020-09-09 Ludovic Berthier , Patrick Charbonneau , Joyjit Kundu

Assembly and stability of mitotic spindle is governed by the interplay of various intra-cellular forces, e.g. the forces generated by motor proteins by sliding overlapping anti-parallel microtubules (MTs) polymerized from the opposite…

Biological Physics · Physics 2016-08-24 Paolo Malgaretti , Sudipto Muhuri

Bead spring models for polymers in solution are nonlinear if either the finite extensibility of the polymer, excluded volume effects or hydrodynamic interactions between polymer segments are taken into account. For such models we use a…

Soft Condensed Matter · Physics 2009-11-07 Roland Rzehak , Walter Zimmermann

We present a hybrid computational method for simulating the dynamics of macromolecules in solution which couples a mesoscale solver for the fluctuating hydrodynamics (FH) equations with molecular dynamics to describe the macromolecule. The…

Soft Condensed Matter · Physics 2007-05-23 G. Giupponi , G. De Fabritiis , P. V. Coveney

We investigate the kinetics of phase separation for a mixture of rodlike viruses (fd) and polymer (dextran), which effectively constitutes a system of attractive rods. This dispersion is quenched from a flow-induced fully nematic state into…

Soft Condensed Matter · Physics 2009-11-11 M. Paul Lettinga , Kyongok Kang , Arnout Imhof , Didi Derks , Jan K. G. Dhont

The folded node is a singularity associated with loss of normal hyperbolicity in systems where mixtures of slow and fast timescales arise due to singular perturbations. Canards are special solutions that reveal a counteractive feature of…

Dynamical Systems · Mathematics 2015-06-03 Mathieu Desroches , Mike R. Jeffrey

In this paper we establish a new efficient method for simulating polymer-solvent systems which combines a lattice Boltzmann approach for the fluid with a continuum molecular dynamics (MD) model for the polymer chain. The two parts are…

Soft Condensed Matter · Physics 2009-10-31 Patrick Ahlrichs , Burkhard Duenweg

We present Monte Carlo (MC) simulation studies of phase separation in binary (AB) mixtures with bond-disorder that is introduced in two different ways: (i) at randomly selected lattice sites and (ii) at regularly selected sites. The Ising…

Statistical Mechanics · Physics 2017-10-25 Awaneesh Singh , Amrita Singh , Anirban Chakraborti

We revisit the classical problem of a polymer confined in a slit in both of its static and dynamic aspects. We confirm a number of well known scaling predictions and analyse their range of validity by means of comprehensive Molecular…

Volcanic eruptions are driven by decompression-induced vesiculation of supersaturated volatile components in magma. The initial phase of this phenomenon has long been described as nucleation and growth. Recently, it was proposed that…

Geophysics · Physics 2025-10-09 Mizuki Nishiwaki

The local dynamical features of a PEO melt studied by MD simulations are compared to two model chain systems, namely the well-known Rouse model as well as the semiflexible chain model (SFCM) that additionally incorporates chain stiffness.…

Soft Condensed Matter · Physics 2015-05-19 Diddo Diddens , Martin Brodeck , Andreas Heuer

We investigate interfacial properties between two highly incompatible polymers of different stiffness. The extensive Monte Carlo simulations of the binary polymer melt yield detailed interfacial profiles and the interfacial tension via an…

Statistical Mechanics · Physics 2009-10-30 Marcus Mueller , Andreas Werner

The phase behaviour of binary blends composed of A$_1$B$_1$ and A$_2$B$_2$ diblock copolymers is systematically studied using the polymeric self-consistent field theory, focusing on the formation and relative stability of various spherical…

Soft Condensed Matter · Physics 2021-09-01 Jiayu Xie , Yu Li , An-Chang Shi

Single two dimensional polymers confined to a strip are studied by Monte Carlo simulations. They are described by N-step self-avoiding random walks on a square lattice between two parallel hard walls with distance 1 << D << N^\nu (\nu = 3/4…

Soft Condensed Matter · Physics 2007-05-23 Hsiao-Ping Hsu , Peter Grassberger

We study a solution of interacting semiflexible polymers with curvature energy in poor-solvent conditions on the d-dimensional cubic lattice using mean-field theory and Monte Carlo computer simulations. Building upon past studies on a…

Soft Condensed Matter · Physics 2024-07-02 Davide Marcato , Achille Giacometti , Amos Maritan , Angelo Rosa

A reasonably accurate representation of a polymer chain is provided by beads connected with rods, or stiff, inextensible springs that mimic a single Kuhn step. Due to high computational cost, coarse-grained bead-spring models are used in…

Soft Condensed Matter · Physics 2023-03-06 Praphul Kumar , Indranil Saha Dalal