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We develop a quasi-chemical theory for the study of packing thermodynamics in dense liquids. The situation of hard-core interactions is addressed by considering the binding of solvent molecules to a precisely defined `cavity' in order to…

Chemical Physics · Physics 2007-05-23 Lawrence R. Pratt , Randall A. LaViolette , Maria A. Gomez , Mary E. Gentile

We develop a formalism that allows the study of correlations in space and time in both the superfluid and Mott insulating phases of the Bose-Hubbard Model. Specifically, we obtain a two particle irreducible effective action within the…

Quantum Gases · Physics 2018-12-13 Matthew R. C. Fitzpatrick , Malcolm P. Kennett

First steps towards developing a new perturbation theory for molecular liquids are taken. By choosing a new form of splitting the site-site potential functions between molecules, we will get a set of atomic fluids as the reference system…

Chemical Physics · Physics 2017-11-21 Mehrdad Khanpour

Generalized mode-coupling theory (GMCT) constitutes a systematically correctable, first-principles theory to study the dynamics of supercooled liquids and the glass transition. It is a hierarchical framework that, through the incorporation…

Statistical Mechanics · Physics 2021-02-03 Chengjie Luo , Liesbeth M. C. Janssen

For a freely evolving granular fluid, the buildup of spatial correlations in density and flow field is described using fluctuating hydrodynamics. The theory for incompressible flows is extended to the general, compressible case, including…

Statistical Mechanics · Physics 2009-10-30 T. P. C. van Noije , M. H. Ernst , R. Brito

Fluctuation and correlation observables are often measured using multi-particle correlation methods and therefore mutually probe the origins of genuine correlations present in multi-particle distribution functions. We investigate the common…

Nuclear Theory · Physics 2015-06-11 Sean Gavin , George Moschelli

A simple model is proposed for the direct correlation function (DCF) for simple fluids consisting of a hard-core contribution, a simple parametrized core correction, and a mean-field tail. The model requires as input only the free energy of…

Statistical Mechanics · Physics 2007-10-08 James F. Lutsko

In this set of lecture notes we review the mode-coupling theory of the glass transition from several perspectives. First, we derive mode-coupling equations for the description of density fluctuations from microscopic considerations with the…

Soft Condensed Matter · Physics 2010-04-16 David R. Reichman , Patrick Charbonneau

Numerical simulations of a dissipative hard sphere gas reveal a dependence of the cooling rate on correlation of the particle velocities due to inelastic collisions. We propose a coefficient which characterizes the velocity correlations in…

Statistical Mechanics · Physics 2009-11-07 Thorsten Poeschel , Nikolai V. Brilliantov , Thomas Schwager

In order to quantify the error budget in the measured probability distribution functions of cell densities, the two-point statistics of cosmic densities in concentric spheres is investigated. Bias functions are introduced as the ratio of…

Cosmology and Nongalactic Astrophysics · Physics 2016-06-08 Sandrine Codis , Francis Bernardeau , Christophe Pichon

We examine the dynamics of hard spheres and discs at high packing fractions in two and three dimensions, modeling the simplest systems exhibiting a glass transition. As it is well known, cooperativity and dynamic heterogeneity arise as…

Soft Condensed Matter · Physics 2007-05-23 Burkhard Doliwa , Andreas Heuer

We develop an effective field theory for dissipative fluids which governs the dynamics of long-lived gapless modes associated with conserved quantities. The resulting theory gives a path integral formulation of fluctuating hydrodynamics…

High Energy Physics - Theory · Physics 2017-01-30 Michael Crossley , Paolo Glorioso , Hong Liu

We have developed a theory for inhomogeneous systems that allows for incorporation of effects of mesoscopic fluctuations. A hierarchy of equations relating the correlation and direct correlation functions for the local excess $\phi({\bf…

Statistical Mechanics · Physics 2016-09-21 Alina Ciach , Wojciech T. Gozdz

For the constant-stress layer of wall turbulence, two-point correlations of velocity fluctuations are studied theoretically by using the attached-eddy hypothesis, i.e., a phenomenological model of a random superposition of energy-containing…

Fluid Dynamics · Physics 2017-06-23 H. Mouri

We give a brief introduction to the mode-coupling theory of the glass transition, a theory which was proposed a while ago to describe the dynamics of supercooled liquids. After presenting the basic equations of the theory, we review some of…

Statistical Mechanics · Physics 2008-02-03 W. Kob

We study various temporal correlation functions of a tagged particle in one-dimensional systems of interacting point particles evolving with Hamiltonian dynamics. Initial conditions of the particles are chosen from the canonical thermal…

Statistical Mechanics · Physics 2015-06-25 Anjan Roy , Abhishek Dhar , Onuttom Narayan , Sanjib Sabhapandit

We study a homogeneously driven granular fluid of hard spheres at intermediate volume fractions and focus on time-delayed correlation functions in the stationary state. Inelastic collisions are modeled by incomplete normal restitution,…

Statistical Mechanics · Physics 2013-05-29 Katharina Vollmayr-Lee , Timo Aspelmeier , Annette Zippelius

We study hydrogen-bond dynamics in liquid water at low temperatures using molecular dynamics simulations. We find that bond lifetime (``fast dynamics'') has Arrhenius temperature dependence. We also calculate the bond correlation function…

Condensed Matter · Physics 2009-10-31 Francis W. Starr , Johannes K. Nielsen , H. Eugene Stanley

A self-consistent mode coupling theory (MCT) with microscopic inputs of equilibrium pair correlation functions is developed to analyze electrolyte dynamics. We apply the theory to calculate concentration dependence of (i) time dependent ion…

Statistical Mechanics · Physics 2015-01-09 Susmita Roy , Subramanian Yashonath , Biman Bagchi

We present a statistical mechanical theory of multi-component fluids, where we consider the correlation functions of the number densities and the energy density in the grand canonical ensemble. In terms of their space integrals we express…

Statistical Mechanics · Physics 2024-05-10 Akira Onuki