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The following properties are in the present literature associated with the behavior of super-cooled glass-forming liquids: faster than exponential growth of the relaxation time, dynamical heterogeneities, growing point-to-set correlation…

Statistical Mechanics · Physics 2011-01-25 Florent Krzakala , Lenka Zdeborová

We combine the swap Monte Carlo algorithm to long multi-CPU molecular dynamics simulations to analyse the equilibrium relaxation dynamics of model supercooled liquids over a time window covering ten orders of magnitude for temperatures down…

Soft Condensed Matter · Physics 2022-12-16 Camille Scalliet , Benjamin Guiselin , Ludovic Berthier

The emergence of the solid state in glass-forming materials upon cooling is accompanied by changes in both thermodynamic and viscoelastic properties and by a precipitous drop in fluidity. Here, we investigate changes in basic elastic…

Soft Condensed Matter · Physics 2023-06-14 Xiaolei Xu , Jack F. Douglas , Wen-Sheng Xu

Theoretical approaches are formulated to investigate the molecular mobility under various cooling rates of amorphous drugs. We describe the structural relaxation of a tagged molecule as a coupled process of cage-scale dynamics and…

Soft Condensed Matter · Physics 2019-12-10 Anh D. Phan , Katsunori Wakabayashi , Marian Paluch , Vu D. Lam

These lecture notes can be read in two ways. The first two Sections contain a review of the phenomenology of several physical systems with slow nonequilibrium dynamics. In the Conclusions we summarize the scenario derived from the solution…

Condensed Matter · Physics 2007-05-23 Leticia F. Cugliandolo

We investigate by means of Monte Carlo simulations the fully connected p-state Potts model for different system sizes in order to see how the static and dynamic properties of a finite model compare with the, exactly known, behavior of the…

Statistical Mechanics · Physics 2009-11-07 Claudio Brangian , Walter Kob , Kurt Binder

A model is proposed that considers aging and rejuvenation in a soft glassy material as respectively a decrease and an increase in free energy. The aging term is weighted by inverse of characteristic relaxation time suggesting greater…

Soft Condensed Matter · Physics 2015-02-25 Yogesh M. Joshi

Usually, supercooled liquids and glasses are thermodynamically unstable against crystallization. Classical nucleation theory (CNT) has been used to describe the crystallization dynamics of supercooled liquids. However, recent studies on…

Soft Condensed Matter · Physics 2023-03-15 Yuki Takaha , Hideyuki Mizuno , Atsushi Ikeda

The $\alpha$-process (segmental motion) of thin polystyrene films supported on glass substrate has been investigated in a wider frequency range from 10$^{-3}$ Hz to 10$^4$ Hz using dielectric relaxation spectroscopy and thermal expansion…

Soft Condensed Matter · Physics 2009-10-31 Koji Fukao , Yoshihisa Miyamoto

We provide broadband dielectric loss spectra of glass-forming glycerol with varying additions of LiCl. The measurements covering frequencies up to 10 THz extend well into the region of the fast beta process, commonly ascribed to caged…

Soft Condensed Matter · Physics 2013-08-07 M. Köhler , P. Lunkenheimer , Y. Goncharov , A. Loidl

We have considered the two-spin interaction spherical spin-glass model with asymmetric bonds (coupling constants). Besides the usual interactions between spins and bonds and between the spins and a thermostat with temperature $T_{\sigma}$…

Disordered Systems and Neural Networks · Physics 2009-10-31 A. E. Allahverdyan , D. B. Saakian

In this paper we develop a method introduced by one of us to study metastable states in spin glasses. We consider a `potential function' defined as the free energy of a system at a given temperature $T$ constrained to have a fixed overlap…

Condensed Matter · Physics 2009-10-28 S. Franz , G. Parisi

We study the relaxational dynamics of flux lines in high-temperature superconductors with random pinning using Langevin dynamics. At high temperatures the dynamics is stationary and the fluctuation dissipation theorem (FDT) holds. At low…

Superconductivity · Physics 2009-11-11 Sebastian Bustingorry , Leticia Cugliandolo , Daniel Dominguez

The recent experimental fabrication of ultra stable glass films via vapour deposition [Science 315, 353 (2007)] and the observation of front-like response to the annealing of these films [Phys.Rev.Lett. 102, 065503 (2009)], have raised…

Soft Condensed Matter · Physics 2011-01-20 Sébastien Léonard , Peter Harrowell

Fragility, quantifying the rapidity of variation of relaxation times, is analysed for a series of model glass formers, which differ in the softness of their interparticle interactions. In an attempt to rationalize experimental observations…

Soft Condensed Matter · Physics 2017-05-30 Anshul D. S. Parmar , Pallabi Kundu , Srikanth Sastry

Aspects of the dynamical glass transition are considered within a mean field spin glass model. At the dynamical transition the the system condenses in a state of lower entropy. The difference, the information entropy or complexity, is…

Condensed Matter · Physics 2007-05-23 Th. M. Nieuwenhuizen

The excitation-chain theory of the glass transition, proposed in an earlier publication, predicts diverging, super-Arrhenius relaxation times and, {\it via} a similarly diverging length scale, suggests a way of understanding the relations…

Statistical Mechanics · Physics 2009-11-11 J. S. Langer

We investigate by thorough Molecular Dynamics simulations the thermodynamic scaling (TS) of a polymer melt. Two distinct models, with strong and weak virial-energy correlations, are considered. Both evidence the joint TS with the same…

Soft Condensed Matter · Physics 2017-01-10 F. Puosi , O. Chulkin , S. Bernini , S. Capaccioli , D. Leporini

The dynamics of a dense binary mixture of soft dumbbells, each subject to an active propulsion force and thermal fluctuations, shows a sudden arrest, first to a translational then to a rotational glass, as one reduces temperature $T$ or the…

Soft Condensed Matter · Physics 2017-10-18 Rituparno Mandal , Pranab Jyoti Bhuyan , Pinaki Chaudhuri , Madan Rao , Chandan Dasgupta

We introduce and analytically study a generalized p-spin glass like model that captures some of the main features of attractive glasses, recently found by Mode Coupling investigations, such as a glass/glass transition line and dynamical…

Statistical Mechanics · Physics 2009-11-10 Antonio Caiazzo , Antonio Coniglio , Mario Nicodemi