Related papers: Weak Long-Ranged Casimir Attraction in Colloidal C…
The influence of long-range Coulomb forces on the persistent current of a pinned Wigner crystal-ring is considered. A simple method is proposed for how to take into account Coulomb effects for the macroscopic quantum tunneling of the Wigner…
Through extensive molecular simulations we determine a phase diagram of attractive, flexible polymer chains in two and three dimensions. A surprisingly rich collection of distinct crystal morphologies appear, which can be finely tuned…
Strong short ranged positional correlations involving counterions can induce a net attractive force between negatively charged strands of DNA, and lead to the formation of ion pairs in dilute ionic solutions. But the long range of the…
Colloids immersed in a critical or near-critical binary liquid mixture and close to a chemically patterned substrate are subject to normal and lateral critical Casimir forces of dominating strength. For a single colloid we calculate these…
Based on a reconsideration of the Gibbs paradox, we show that a residual, non-extensive term in entropy turns up upon mixing identical particles, whether they are indistinguishable or not. The positive contribution from this residual…
The Casimir interactions in the solid-liquid-solid systems as a function of separation distance have been studied by the Lifshitz theory. The dielectric permittivity functions for a wide range of materials are described by Drude,…
A model system of highly asymmetric polyelectrolyte with directional short-range attractive interactions was studied by canonical Monte Carlo computer simulations. Comparison of MC data with previously published theoretical results shows…
Surface effects are generally prevailing in confined colloidal systems. Here we report on dispersed nanoparticles close to a fluid membrane. Exact results regarding the static organization are derived for a dilute solution of non-adhesive…
We report a mechanism which can lead to long range attractions between like-charged spherical macroions, stemming from the existence of metastable ionized states. We show that the ground state of a single highly charged colloid plus a few…
We theoretically study the polarizability and the interactions of neutral complexes consisting of a semi-flexible polyelectrolyte adsorbed onto an oppositely charged spherical colloid. In the systems we studied, the bending energy of the…
We describe arrangements of ions capable of producing short-range attractive interactions between pairs of charged colloidal spheres in the low temperature strongly correlated limit. For particles of radius $R$ with bare charge $Z$ and…
Using the critical Casimir force, we study the attractive-strength dependence of diffusion-limited colloidal aggregation in microgravity. By means of near field scattering we measure both the static and dynamic structure factor of the…
The phase behavior of charge-stabilized colloidal suspensions is modeled by a combination of response theory for electrostatic interparticle interactions and variational theory for free energies. Integrating out degrees of freedom of the…
We investigate the effect of excluded volume interactions on the electrolyte distribution around a charged macroion. First, we introduce a criterion for determining when hard-core effects should be taken into account beyond standard mean…
We demonstrate that an extended picture of kinetic constraints in glass-forming liquids is sufficient to explain dynamic anomalies observed in dense suspensions of strongly attracting colloidal particles. We augment a simple model of…
We consider a set of identical mobile point-like charges (counter-ions) confined to a domain with curved hard walls carrying a uniform fixed surface charge density, the system as a whole being electroneutral. Three domain geometries are…
It has been conjectured that the Pauli exclusion principle alone may be responsible for a particular geometric arrangement of confined systems of identical fermions even when there is no interaction between them. These geometric structures,…
A tight binding model of electrons interacting via bare Coulomb repulsion is numerically investigated by use of the Density Matrix Renormalization Group method which we prove applicable also to very long range potentials. From the analysis…
The existence of attractions between like-charged colloids immersed in ionic solution have been discovered in recent experiments. This phenomenon contradicts the predictions of DLVO theory and indicates a failure of mean field theory. We…
We investigate, within a local density functional theory formalism, the interactions between like-charged polyions immersed in a confined electrolyte. We obtain a simple condition for a repulsive effective pair potential, that can be…