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Magnetic properties of single crystals of the heterometallic complex [Cu(bpy)$_3$]$_2$[Cr(C$_2$O$_4$)$_3$]NO$_3\cdot $9H$_2$O (bpy = 2,2'-bipyridine) have been investigated. From the recorded EPR spectra, the spin-Hamiltonian parameters…

This paper reports on a detailed magnetotransport investigation of the magnetic anisotropies of (Ga,Mn)As layers produced by various sources worldwide. Using anisotropy fingerprints to identify contributions of the various higher order…

High-Sensitivity Electron Paramagnetic Resonance experiments have been carried out in fresh and stressed Mn12-Acetate single crystals for frequencies ranging from 40 GHz up to 110 GHz. The high number of crystal dislocations formed in the…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 R. Amigo , E. del Barco , Ll. Casas , E. Molins , J. Tejada , I. B. Rutel , B. Mommouton , N. Dalal , J. Brooks

We have investigated crystalline magnetic anisotropy in the electric field (EF) for the Fe-Pt surface which have a large perpendicular anisotropy, by means of the first-principles approach. The anisotropy is reduced linearly with respect to…

Materials Science · Physics 2015-05-13 Masahito Tsujikawa , Tatsuki Oda

We study theoretically Electron Paramagentic Resonance (EPR) linewidths for single crystals of the molecular magnets Fe$_8$ and Mn$_{12}$ as functions of energy eigenstates $M_s$, frequency, and temperature when a magnetic field along the…

Condensed Matter · Physics 2009-11-07 Kyungwha Park , M. A. Novotny , N. S. Dalal , S. Hill , P. A. Rikvold

We herein estimate the effect of lattice defects on the line shape of electron paramagnetic resonance (EPR) signals from a single crystal of the S=10 single-molecule magnet Mn$_{12}$ with the external magnetic field along the crystal c…

Condensed Matter · Physics 2009-11-07 Kyungwha Park , N. S. Dalal , P. A. Rikvold

First-principles calculations of the magnetic anisotropy energy for Mn- and Fe-atoms on CuN/Cu(001) surface are performed making use of the torque method. The easy magnetization direction is found to be different for Mn and Fe atoms in…

Materials Science · Physics 2015-05-13 A. B. Shick , F. Máca , A. I. Lichtenstein

We have performed Electron Spin Resonance measurements on single crystals of the doped spin-Peierls compounds CuGe$_{1-y}$Si$_y$O$_3$ and Cu$_{1-x}$M$_x$GeO$_3$ with M = Zn, Mg, Ni ($x, y\leq 0.1$). The first part of our experiments was…

Strongly Correlated Electrons · Physics 2009-11-07 B. Grenier , P. Monod , M. Hagiwara , M. Matsuda , K. Katsumata , S. Clément , J. -P. Renard , A. L. Barra , G. Dhalenne , A. Revcolevschi

Doped transition-metal dichalcogenides monolayers exhibit exciting magnetic properties for the benefit of two-dimensional spintronic devices. Using density functional theory (DFT) incorporating Hubbard-type of correction (DFT$+U$) to…

Materials Science · Physics 2021-05-12 Adlen Smiri , Sihem Jaziri , Samir Lounis , Iann C. Gerber

A detailed multifrequency high field - high frequency EPR (95-285 GHz) study has been performed on the single-molecule magnet of formula [Fe8O2(OH)12(tacn)6]Br8 9H2O, where tacn=1,4,7-triazacyclononane. Polycrystalline powder spectra have…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 Anne Laure Barra , Dante Gatteschi , Roberta Sessoli

We study gate field effects on the Mn$_{12}$O$_{12}$(COOH)$_{16}$(H$_2$O)$_4$ | graphene | GaAs heterostructure via first-principles calculations. We find that under moderate doping levels electrons can be added to but not taken from the…

Materials Science · Physics 2022-01-05 Shuanglong Liu , Maher Yazback , James N. Fry , Xiao-Guang Zhang , Hai-Ping Cheng

The electronic structure, magnetic properties and phase formation of hexagonal ferromagnetic Fe$_{3}$Sn-based alloys have been studied from first principles and by experiment. The pristine Fe$_{3}$Sn compound is known to fulfill all the…

The anisotropy splitting in the ground state of the single-molecule magnet [Mn4O3Br(OAc)3(dbm)3] is studied by inelastic neutron scattering as a function of hydrostatic pressure. This allows a tuning of the anisotropy and thus the energy…

Strongly Correlated Electrons · Physics 2009-11-10 Andreas Sieber , Gregory Chaboussant , Roland Bircher , Colette Boskovic , Hans U. Guedel , George Christou , Hannu Mutka

We present a computational study of individual and pairs of substitutional Mn impurities on the (110) surface of GaAs samples based on density functional theory. We focus on the anisotropy properties of these magnetic centers and their…

Strongly Correlated Electrons · Physics 2011-08-29 M. Fhokrul Islam C. M. Canali

We report on the micro-photoluminescence spectroscopy of InAs/GaAs quantum dots (QD) doped by a single Mn atom in a magnetic field either longitudinal or perpendicular to the optical axis. In both cases the spectral features of positive…

Materials Science · Physics 2015-05-14 Olivier Krebs , Emile Benjamin , Aristide Lemaître

We present a theoretical approach to calculate the molecular magnetic anisotropy parameters, $D_M$ and $E_M$ for single molecule magnets in any eigenstate of the exchange Hamiltonian, treating the anisotropy Hamiltonian as a perturbation.…

Strongly Correlated Electrons · Physics 2009-11-13 Rajamani Raghunathan , S. Ramasesha , Diptiman Sen

A ferromagnetic coupling between localized Mn spins was predicted in a series of \textit{ab initio} and tight binding calculations and experimentally verified for the dilute magnetic semiconductor Ga$_{1-x}$Mn$_x$N. In the limit of small Mn…

Materials Science · Physics 2020-12-30 D. Sztenkiel , K. Gas , J. Z. Domagala , D. Hommel , M. Sawicki

Using a microscopic finite-cluster tight-binding model, we investigate the trend of the magnetic anisotropy energy as a function of the cluster size for an individual Mn impurity positioned in the vicinity of the (110) GaAs surface,We…

Materials Science · Physics 2014-10-17 M R Mahani , A Pertsova , C M Canali

Electron paramagnetic resonance (EPR) measurements on single crystals of the molecular magnets Fe$_8$ and Mn$_{12}$ reveal complex nonlinearities in the linewidths as functions of energy eigenstate, frequency, and temperature. Using a…

Condensed Matter · Physics 2009-11-07 Kyungwha Park , M. A. Novotny , N. S. Dalal , S. Hill , P. A. Rikvold

To understand the effect of molecular environment on the electronic and magnetic properties of the single-molecule magnet (SMM) Mn$_{12}$, we explore two possible means for adding extra electrons to molecule. We explore both substitution of…

Materials Science · Physics 2009-11-10 Kyungwha Park , Mark R. Pederson
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