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We study the glass transition by exploring a broad class of kinetic rules that can significantly modify the normal dynamics of super-cooled liquids, while maintaining thermal equilibrium. Beyond the usual dynamics of liquids, this class…

Soft Condensed Matter · Physics 2024-06-14 Cristina Gavazzoni , Carolina Brito , Matthieu Wyart

A key open question in the glass transition field is whether a finite temperature thermodynamic transition to the glass state exists or not. Recent simulations of coupled replicas in atomistic models have found signatures of a static…

Statistical Mechanics · Physics 2015-06-18 Juan P. Garrahan

A theory for the nonlinear energy response of a system subjected to a heat bath is developed when the temperature of the heat bath is modulated sinusoidally. The theory is applied to a model glass forming system, where the landscape is…

Statistical Mechanics · Physics 2009-11-13 Fumitaka Tagawa , Takashi Odagaki

The glass transition is considered as a phase transition in the system of topologically protected excitations in matter structure. The critical behavior of the system is considered both in statics and dynamics cases. It is shown in the…

Statistical Mechanics · Physics 2022-04-20 Mikail Vasin

We show that a glass transition, signaled by a peak in the specific heat vs. temperature, can occur because a glassy system that shows no signs of aging progresses so slowly through the energy landscape that the time needed to obtain an…

Disordered Systems and Neural Networks · Physics 2007-05-23 Clare C. Yu , Herve M. Carruzzo

The glass transition temperature and its connection to statistical properties of confined and free-standing polymer films of varying thickness containing unentangled to highly entangled bead-spring chains are studied by molecular dynamics…

Soft Condensed Matter · Physics 2023-09-21 Hsiao-Ping Hsu , Kurt Kremer

The glass-forming ability is an important material property for manufacturing glasses and understanding the long-standing glass transition problem. Because of the nonequilibrium nature, it is difficult to develop the theory for it. Here we…

Soft Condensed Matter · Physics 2021-01-26 Yunhuan Nie , Jun Liu , Jialing Guo , Ning Xu

We extend the replica liquid theory in order to describe the multiple glass transitions of binary mixtures with large size disparities, by taking into account the two-step replica symmetry breaking (2RSB). We determine the glass phase…

Soft Condensed Matter · Physics 2021-03-03 Harukuni Ikeda , Kunimasa Miyazaki , Hajime Yoshino , Atsushi Ikeda

We introduce a new quantity to probe the glass transition. This quantity is a linear generalized compressibility which depends solely on the positions of the particles. We have performed a molecular dynamics simulation on a glass forming…

Disordered Systems and Neural Networks · Physics 2007-05-23 Herve M. Carruzzo , Clare C. Yu

Tackling the low-temperature fate of supercooled liquids is challenging due to the immense timescales involved, which prevent equilibration and lead to the operational glass transition. Relating glassy behaviour to an underlying,…

Statistical Mechanics · Physics 2017-08-16 Francesco Turci , C. Patrick Royall , Thomas Speck

The glass transition refers to the non-equilibrium process by which an equilibrium liquid is transformed to a non-equilibrium disordered solid, or vice versa. Associated response functions, such as heat capacities, are markedly different on…

Soft Condensed Matter · Physics 2013-03-26 Aaron S. Keys , Juan P. Garrahan , David Chandler

In magnetic materials, spins sometimes freeze into spatially disordered glassy states. Glass forming liquids or structural glasses are found very often in three dimensions. However, in two dimensions(2D) it is believed that both spin glass…

Disordered Systems and Neural Networks · Physics 2022-07-18 Chisa Hotta , Kazumasa Ueda , Masatoshi Imada

The high cooling rate needed for preparing the metallic glass (MG) makes the nonequilibrium nature of glass formation more prominent and requires a better quenching technique than ever before. Here, we formulate the cooling process in an…

Materials Science · Physics 2023-09-19 Jian Guo Wang

The glass transition plays a central role in nature as well as in industry, ranging from biological systems such as proteins and DNA to polymers and metals. Yet the fundamental understanding of the glass transition which is a prerequisite…

Soft Condensed Matter · Physics 2017-09-27 Henriette Wase Hansen , Alejandro Sanz , Karolina Adrjanowicz , Bernhard Frick , Kristine Niss

The free-energy landscape of two peptides is evaluated at various temperatures and an estimate for its fractal dimension at these temperatures calculated. We show that monitoring this quantity as a function of temperature allows to…

Statistical Mechanics · Physics 2009-10-31 Nelson A. Alves , Ulrich H. E. Hansmann

Based on experimental evidences we present a phenomenological description of the thermal glass transition as a dynamical phase transition. Different susceptibilities calculated on the basis of this description are in good qualitative…

Disordered Systems and Neural Networks · Physics 2016-08-16 J. K. Krüger , J. Petersson , J. Baller , M. Henkel

Topological defects are typically quantified relative to ordered backgrounds. The importance of these defects to the understanding of physical phenomena including diverse equilibrium melting transitions from low temperature ordered to…

Statistical Mechanics · Physics 2019-02-19 Z. Nussinov , N. B. Weingartner , F. S. Nogueira

We give general topological rules which very accurately predict the chemical trends in glass transition temperature $T_g$ variation as a function of cross-linking. In multicomponent glasses, these chemical trends permit to distinguish…

Disordered Systems and Neural Networks · Physics 2009-10-31 Matthieu Micoulaut , Gerardo G. Naumis

Framing the glass formation within standard statistical mechanics is an outstanding problem of condensed matter theory. To provide new insight, we investigate the structural properties of the Lennard-Jones fluid in the very-low temperature…

Statistical Mechanics · Physics 2026-02-02 Bomont Jean-Marc , Bretonnet Jean-Louis , Costa Dino , Pastore Giorgio

We analyze a microscopic RNA model, which includes two widely used models as limiting cases, namely it contains terms for bond as well as for stacking energies. We numerically investigate possible changes in the qualitative and quantitative…

Quantitative Methods · Quantitative Biology 2009-11-10 Bernd Burghardt , Alexander K. Hartmann