Related papers: Boltzmann's Approach to Statistical Mechanics
The ergodic hypothesis outgrew from the ancient conception of motion as periodic or quasi periodic. It did cause a revision of our views of motion, particularly through Boltzmann and Poincar\'e: we discuss how Boltmann's conception of…
Statistical mechanics can only be ultimately justified in terms of microscopic dynamics (classical, quantum, relativistic, or any other). It is known that Boltzmann-Gibbs statistics is based on the hypothesis of exponential sensitivity to…
The thermodynamic limit in statistical thermodynamics of many-particle systems is an important but often overlooked issue in the various applied studies of condensed matter physics. To settle this issue, we review tersely the past and…
When thermodynamics is understood as the science (or art) of constructing effective models of natural phenomena by choosing a minimal level of description capable of capturing the essential features of the physical reality of interest, the…
The irreversible entropy increase described by the second law of thermodynamics is fundamentally tied to thermalization and the emergence of equilibrium. In the first part of our work (Ref: arXiv.2503.04152), we constructed an isolated gas…
It is widely believed that the underlying reality behind statistical mechanics is a deterministic and unitary time evolution of a many-particle wave function, even though this is in conflict with the irreversible, stochastic nature of…
We have presented first an axiomatic derivation of Boltzmann entropy on the basis of two axioms consistent with two basic properties of thermodynamic entropy. We have then studied the relationship between Boltzmann entropy and information…
Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs'…
This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…
In 1916 Einstein introduced the first rules for a quantum theory of electromagnetic radiation, and he applied them to a model of matter in thermal equilibrium with radiation to derive Planck's black-body formula. Einstein's treatment is…
Boltzmann's principle S(E,N,V...)=ln W(E,N,V...) allows the interpretation of Statistical Mechanics of a closed system as Pseudo-Riemannian geometry in the space of the conserved parameters E,N,V... (the conserved mechanical parameters in…
We briefly review Boltzmann-Gibbs and nonextensive statistical mechanics as well as their connections with Fokker-Planck equations and with existing central limit theorems. We then provide some hints that might pave the road to the proof of…
The fundamental assumption of statistical mechanics is that the system is equally likely in any of the accessible microstates. Based on this assumption, the Boltzmann distribution is derived and the full theory of statistical thermodynamics…
An ensemble of classical subsystems interacting with surrounding particles has been considered. In general case, a phase volume of the subsystems ensemble was shown to be a function of time. The evolutional equations of the ensemble are…
Within the general formalism of quantum theory irreversibility and the arrow of time in the evolution of various physical systems are studied. Irreversible behavior often manifests itself in the guise of entropy production. This motivates…
Recently, a thermodynamic definition of time has been introduced. This definition is useful to find approach some open problems in physics. But, it was obtained by a phenomenological approach and a logical inconsistency appears in the…
The formation of large-scale vortices is an intriguing phenomenon in two-dimensional turbulence. Such organization is observed in large-scale oceanic or atmospheric flows, and can be reproduced in laboratory experiments and numerical…
We prove the eventological $H$-theorem that complements the Boltzmann H-theorem from statistical mechanics and serves as a mathematical excuse (mathematically no less convincing than the Boltzmann H-theorem for the second law of…
The paper moves a step towards the full integration of statistical mechanics and information theory. Starting from the assumption that the thermodynamical system is composed by particles whose quantized energies can be modelled as…
This pedagogical comment highlights three misconceptions concerning the usefulness of the concept of negative temperature; being derived from the usual, often termed Boltzmann, definition of entropy. First, both the Boltzmann and Gibbs…