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Given an arbitrary Lagrangian function on \RR^d and a choice of classical path, one can try to define Feynman's path integral supported near the classical path as a formal power series parameterized by "Feynman diagrams," although these…

Mathematical Physics · Physics 2019-11-05 Theo Johnson-Freyd

In this paper, we investigate the use of variational quantum algorithms for simulating the thermodynamic properties of dinuclear metal complexes. Our study highlights the potential of quantum computing to transform advanced simulations and…

Quantum Physics · Physics 2024-10-28 Ana Clara das Neves Silva , Clebson Cruz

We introduce a variational method for simulating the dynamics of interacting open quantum spin systems. The method is based on the spin phase-space representation and variationally targets the Husimi-$Q$ function with an ansatz based on a…

Quantum Physics · Physics 2026-04-02 Jacopo Tosca , Zejian Li , Francesco Carnazza , Cristiano Ciuti

Fractionation of isotopes among distinct molecules or phases is a quantum effect which is often exploited to obtain insights on reaction mechanisms, biochemical, geochemical and atmospheric phenomena. Accurate evaluation of isotope ratios…

Chemical Physics · Physics 2015-06-23 Bingqing Cheng , Michele Ceriotti

We investigate the relationship between ground-state (zero-temperature) quantum phase transitions in systems with variable Hamiltonian parameters and classical (temperature-driven) phase transitions in standard thermodynamics. An analogy is…

Nuclear Theory · Physics 2009-11-11 Pavel Cejnar , Stefan Heinze , Jan Dobes

Mean-field molecular dynamics based on path integrals is used to approximate canonical quantum observables for particle systems consisting of nuclei and electrons. A computational bottleneck is the sampling from the Gibbs density of the…

Numerical Analysis · Mathematics 2023-11-30 Xin Huang , Petr Plechac , Mattias Sandberg , Anders Szepessy

In the era of noisy intermediate-scale quantum computers, variational quantum algorithms are promising approaches for solving optimization tasks by training parameterized quantum circuits with the aid of classical routines informed by…

Using a recent path integral representation for the T-matrix in nonrelativistic potential scattering we investigate new variational approximations in this framework. By means of the Feynman-Jensen variational principle and the most general…

Nuclear Theory · Physics 2010-08-25 J. Carron , R. Rosenfelder

Some notable systems, such as room-temperature superconductors and materials for controlled nuclear fusion, require an accurate description of finite-temperature quantum matter. Stochastic path integral methods are finite-temperature and…

Strongly Correlated Electrons · Physics 2026-04-06 Ingvars Vitenburgs , Jarvist Moore Frost

This work is devoted to the thermodynamics of high-temperature dense hydrogen plasmas in the pressure region between $10^{-1}$ and $10^2$ Mbar. In particular we present for this region results of extensive calculations based on a recently…

Plasma Physics · Physics 2009-11-07 V. S. Filinov , M. Bonitz , W. Ebeling , V. E. Fortov

The calculation of caloric properties such as heat capacity, Joule-Thomson coefficients and the speed of sound by classical force-field-based molecular simulation methodology has received scant attention in the literature, particularly for…

Chemical Physics · Physics 2019-03-15 William R. Smith , Jan Jirsák , Ivo Nezbeda , Weikai Qi

We study the high-temperature behavior of quantum-mechanical path integrals. Starting from the Feynman-Kac formula, we derive a new functional representation of the Wigner-Kirkwood perturbation expansion for quantum Boltzmann densities. As…

Statistical Mechanics · Physics 2014-01-24 Petr Jizba , Vaclav Zatloukal

Electric field plays an important role in ferroelectric phase transition. There have been numerous phase field formulations attempting to account for electrostatic interactions subject to different boundary conditions. In this paper, we…

Computational Physics · Physics 2019-10-18 Qiang Du , Ruotai Li , Lei Zhang

A variational method is used to derive a self-consistent macro-particle model for relativistic electromagnetic kinetic plasma simulations. Extending earlier work [E. G. Evstatiev and B. A. Shadwick, J. Comput. Phys., vol. 245, pp. 376-398,…

Computational Physics · Physics 2014-04-22 A. B. Stamm , B. A. Shadwick , E. G. Evstatiev

A method for nonperturbative path integral calculation is proposed. Quantum mechanics as a simplest example of a quantum field theory is considered. All modes are decomposed into hard (with frequencies $\omega^2 >\omega^2_0$) and soft (with…

High Energy Physics - Phenomenology · Physics 2014-11-17 V. M. Belyaev

Following Feynman's treatment of the non-relativistic polaron problem, similar techniques are used to study relativistic field theories: after integrating out the bosonic degrees of freedom the resulting effective action is formulated in…

High Energy Physics - Theory · Physics 2007-05-23 R. Rosenfelder , C. Alexandrou , A. W. Schreiber

We present a variational approach for quantum simulators to realize finite temperature Gibbs states by preparing thermofield double (TFD) states. Our protocol is motivated by the quantum approximate optimization algorithm (QAOA) and…

Strongly Correlated Electrons · Physics 2019-12-04 Jingxiang Wu , Timothy H. Hsieh

Mean force kinetic theory is used to evaluate the electrical conductivity, thermal conductivity, electrothermal coefficient, thermoelectric coefficient, and shear viscosity of a two-component (ion-electron) plasma. Results are compared with…

Plasma Physics · Physics 2025-11-14 Jarett LeVan , Scott D. Baalrud

The recent advancement of quantum computer hardware offers the potential to simulate quantum many-body systems beyond the capability of its classical counterparts. However, most current works focus on simulating the ground-state properties…

Quantum Physics · Physics 2022-06-14 Chee Kong Lee , Shi-Xin Zhang , Chang-Yu Hsieh , Shengyu Zhang , Liang Shi

We develop the variational-cluster-approximation method based on the thermal-pure-quantum-state approach and apply the method to the calculations of the thermodynamic properties of the Hubbard model, thereby obtaining the temperature…

Strongly Correlated Electrons · Physics 2020-02-19 Hisao Nishida , Ryo Fujiuchi , Koudai Sugimoto , Yukinori Ohta