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Kohn-Sham density functional theory (DFT) has long struggled with the accurate description of strongly correlated and open shell systems and improvements have been minor even in the newest hybrid functionals. In this Letter we treat the…

Chemical Physics · Physics 2021-04-01 Danny Gibney , Jan-Niklas Boyn , David A. Mazziotti

An alternative approach to density functional theory based on self-consistent field theory for ring polymers is applied to neutral atoms hydrogen to neon in their ground states. The spontaneous emergence of atomic shell structure and…

Quantum Physics · Physics 2026-02-05 Phil A. LeMaitre , Russell B. Thompson

By incorporating the nonempirical SCAN semilocal density functional [Sun, Ruzsinszky, and Perdew, Phys. Rev. Lett. 115, 036402 (2015)] in the underlying expression of four existing hybrid and double-hybrid models, we propose one hybrid…

Chemical Physics · Physics 2016-02-05 Kerwin Hui , Jeng-Da Chai

We study spinless fermions on a finite chain with nearest-neighbor repulsion and in the presence of a Wannier-Stark linearly-varying electric field potential. In the absence of the interaction, the eigenstates are localized for the system's…

Strongly Correlated Electrons · Physics 2025-02-10 Nair Aucar Boidi , Amnon Aharony , Ora Entin-Wohlman , Karen Hallberg , Cesar Proetto

The Breit correction, the finite-light-speed correction for the Coulomb interaction of the electron-electron interaction in $ O \left( 1/ c^2 \right) $, is introduced to density functional theory (DFT) based on the non-relativistic…

Computational Physics · Physics 2020-10-20 Tomoya Naito , Ryosuke Akashi , Haozhao Liang , Shinji Tsuneyuki

We extend the density-functional theory for superconductors (SCDFT) to take account of the dynamical structure of the screened Coulomb interaction. We construct an exchange-correlation kernel in the SCDFT gap equation on the basis of the…

Superconductivity · Physics 2014-01-08 Ryosuke Akashi , Ryotaro Arita

Accurate calculations of strongly correlated materials remain a formidable challenge in condensed matter physics, particularly due to the computational demand of conventional methods. This paper presents an efficient solver for dynamical…

Strongly Correlated Electrons · Physics 2025-12-04 Basile Herzog , Patrik Thunström , Olle Eriksson

We probe the strength of electron-electron interactions using magnetoconductivity measurements of two-dimensional non-degenerate electrons on liquid helium at 1.22 K. Our data extend to electron densities that are two orders of magnitude…

Strongly Correlated Electrons · Physics 2007-05-23 I. Karakurt , A. J. Dahm

We lay out the extension of range-separated density-functional theory to a four-component relativistic frame-work using a Dirac-Coulomb-Breit Hamiltonian in the no-pair approximation. This formalism combines a wave-function method for the…

Chemical Physics · Physics 2018-12-12 Julien Paquier , Julien Toulouse

The Perdew-Zunger (PZ) self-interaction correction (SIC) is an established tool to correct unphysical behavior in density functional approximations. Yet, PZ-SIC is well-known to sometimes break molecular symmetries. An example of this is…

Chemical Physics · Physics 2024-10-28 Sebastian Schwalbe , Wanja Timm Schulze , Kai Trepte , Susi Lehtola

We study the interactions between two negatively charged macroscopic surfaces confining positive counterions. A density-functional approach is introduced which, besides the usual mean-field interactions, takes into account the correlations…

Soft Condensed Matter · Physics 2015-06-25 A. Diehl , M. N. Tamashiro , Marcia C. Barbosa , Yan Levin

The incorporation of a strong interaction regime within the approximate, semilocal exchange-correlation functionals still remains a very challenging task for density functional theory. One of the promising attempts in this direction is the…

Other Condensed Matter · Physics 2023-09-20 Subrata Jana , Szymon Smiga , Lucian A. Constantin , Prasanjit Samal

We derive a self-consistent local variant of the Thomas-Fermi approximation for (quasi-)two-dimensional (2D) systems by localizing the Hartree term. The scheme results in an explicit orbital-free representation of the electron density and…

Strongly Correlated Electrons · Physics 2013-02-04 E. Rasanen , S. Pittalis , G. Bekcioglu , I. Makkonen

Nonlinear self-interference (SI) cancellation is essential for mitigating the impact of transmitter-side nonlinearity on overall SI cancellation performance in flexible duplex systems, including in-band full-duplex (IBFD) and sub-band…

Signal Processing · Electrical Eng. & Systems 2025-03-05 Yonghwi Kim , Kai-Kit Wong , Jianzhong , Zhang , Chan-Byoung Chae

The effect of the electron-electron cusp on the convergence of configuration interaction (CI) wave functions is examined. By analogy with the pseudopotential approach for electron-ion interactions, an effective electron-electron interaction…

Strongly Correlated Electrons · Physics 2009-11-07 David Prendergast , M. Nolan , Claudia Filippi , Stephen Fahy , J. C. Greer

In this article, we investigate the role of the self-interaction error in the simulation of collisions using time-dependent density functional theory (TDDFT) and Ehrenfest dynamics. We compare many different approximations of the exchange…

Chemical Physics · Physics 2017-05-03 Edwin E. Quashie , Bidhan C. Saha , Xavier Andrade , Alfredo A. Correa

The topology of cosmic reionization, the sizes, shapes, and connectivity of ionized bubbles is a primary observable of next-generation 21\,cm experiments. We show that this topology is sensitive to the microphysics of dark matter.…

Cosmology and Nongalactic Astrophysics · Physics 2026-04-17 Zihan Wang

We demonstrate that with two small modifications, the popular dielectric continuum model is capable of predicting, with high accuracy, ion solvation thermodynamics in numerous polar solvents, and ion solvation free energies in…

Background: Collective excitations of nuclei and their theoretical descriptions provide an insight into the structure of nuclei. Replacing traditional phenomenological interactions with unitarily transformed realistic nucleon-nucleon…

Nuclear Theory · Physics 2014-09-03 Bastian Erler , Robert Roth

Quantum electrodynamic fields possess fluctuations corresponding to transient particle/antiparticle dipoles, which can be characterized by a non-vanishing polarizability density. Here, we extend a recently proposed quantum scaling law to…

High Energy Physics - Theory · Physics 2023-01-25 Alexandre Tkatchenko , Dmitry V. Fedorov