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An exact analytic form for the second virial coefficient, valid for the entire range of temperature, is presented for the Lennard-Jones fluid in this paper. It is derived by making variable transformation that gives rise to the Hamiltonian…

Chemical Physics · Physics 2009-09-21 Byung Chan Eu

We derive an explicit analytic expression for the first quantum correction to the second virial coefficient of a $d$-dimensional fluid whose particles interact via the generalized Lennard-Jones $(2n,n)$ potential. By introducing an…

Statistical Mechanics · Physics 2025-12-12 Daniel Parejo , Andrés Santos

The second virial coefficient for the Mie potential is evaluated using the method of brackets. This method converts a definite integral into a series in the parameters of the problem, in this case this is the temperature $T$. The results…

Mathematical Physics · Physics 2024-10-17 Ivan Gonzalez , Igor Kondrashuk , Victor H. Moll , Daniel Salinas-Arizmendi

We study the second virial coefficient, $B(T)$, for simple real gases at high temperature. Theoretical arguments imply that there exists a certain temperature, $T_i$, for each gas, for which this coefficient is a maximum. However, the…

Condensed Matter · Physics 2008-02-03 H. Boschi-Filho , C. C. Buthers

This paper investigates the relation between the density-scaling exponent $\gamma$ and the virial potential-energy correlation coefficient $R$ at several thermodynamic state points in three dimensions for the generalized $(2n,n)$…

Soft Condensed Matter · Physics 2024-01-17 Ida M. Friisberg , Lorenzo Costigliola , Jeppe C. Dyre

The recent theoretical prediction by Maimbourg and Kurchan [arXiv:1603.05023] that for regular pair-potential systems the virial potential-energy correlation coefficient increases towards unity as the dimension $d$ goes to infinity is…

Soft Condensed Matter · Physics 2017-01-04 Lorenzo Costigliola , Thomas B. Schrøder , Jeppe C. Dyre

We calculate the second virial coefficient of spin-1/2 anyon gas in the various values of the self-adjoint extension parameter by incorporating the self-adjoint extension method into the Green's function formalism. Especially, the…

High Energy Physics - Theory · Physics 2007-05-23 Sahng-kyoon Yoo , D. K. Park

We study the thermodynamical properties of an ideal gas of non-Abelian Chern-Simons particles and we compute the second virial coefficient, considering the effect of general soft-core boundary conditions for the two-body wavefunction at…

High Energy Physics - Theory · Physics 2013-04-19 Francesco Mancarella , Andrea Trombettoni , Giuseppe Mussardo

In this paper we apply the global isomorphism approach [V.~L. Kulinskii, J. Phys. Chem. B \textbf{114} 2852 (2010)] between the Lennard-Jones fluids and Lattice Gas model to the study of the liquid-vapor equilibrium for the systems with the…

Statistical Mechanics · Physics 2013-04-26 Leonid Bulavin , Vladimir Kulinskii

From spinor and scalar 2+1 dimensional QED effective actions at finite temperature and density in a constant magnetic field background, we calculate the corresponding virial coefficients for particles in the lowest Landau level. These…

High Energy Physics - Theory · Physics 2009-11-07 P. F. Borges , H. Boschi-Filho , Marcelo Hott

We formulate a straightforward scheme of statistical mechanics for inhomogeneous systems that includes the virial series in powers of the activity for the grand free energy and density distributions. There, cluster integrals formulated for…

Soft Condensed Matter · Physics 2016-05-25 Ignacio Urrutia , Iván Paganini

We argue that recently proposed [Melnyk et al., Fluid Phase Equilibr., 2009, Vol. 279, 1] a criterion to split the pair interaction energy into two parts, one of which is forced to be responsible the most accurate as possible for excluded…

Soft Condensed Matter · Physics 2015-04-06 A. Trokhymchuk , R. Melnyk , I. Nezbeda

In a previous article \cite{kn:anirban1} a method has been introduced to derive the all order Bose-Einstein distribution of the non interacting Bosons as the solution of the Wigner equation. The process was a perturbative one where the…

Statistical Mechanics · Physics 2020-05-27 Anirban Bose

Liquids displaying strong virial-potential energy correlations conform to an approximate density scaling of their structural and dynamical observables. This scaling property does not extend to the entire phase diagram, in general. The…

Soft Condensed Matter · Physics 2020-12-23 Thibaud Maimbourg , Jeppe C. Dyre , Lorenzo Costigliola

In this paper, we generally expressed the virial expansion of ideal quantum gases by the heat kernel coefficients for the corresponding Laplace type operator. As examples, we give the virial coefficients for quantum gases in $d$-dimensional…

Statistical Mechanics · Physics 2019-04-16 Xia-Qing Xu , Mi Xie

We show that the assumption of quasiperiodic boundary conditions (those that interpolate continuously periodic and antiperiodic conditions) in order to compute partition functions of relativistic particles in 2+1 space-time can be related…

High Energy Physics - Theory · Physics 2009-10-30 P. F. Borges , H. Boschi-Filho , C. Farina

We present a systematic study of the thermodynamics of two and three-dimensional generalized Lennard-Jones ($LJ$) systems focusing on the relationship between the range of the potential, the system density and its dimension. We found that…

Statistical Mechanics · Physics 2007-05-23 M. J. Ison , A. Chernomoretz , C. O. Dorso

The general notion of distance dependent statistics in anyon-like systems is discussed. The two-body problem for such statistics is considered, the general formula for the second virial coefficient is derived and it is shown that in the…

High Energy Physics - Theory · Physics 2014-11-18 Stefan V. Mashkevich

Evaluating the propagator by the usual time-sliced manner, we use it to compute the second virial coefficient of an anyon gas interacting through the repulsive potential of the form $g/r^2 (g > 0)$. All the cusps for the unpolarized…

High Energy Physics - Theory · Physics 2008-11-26 Sahng-Kyoon Yoo , D. K. Park

The van-der-Waals version of the second virial coefficient is not far from being exact if the model parameters are appropriately chosen. It is shown how the van-der-Waals resemblance originates from the interplay of thermal averaging and…

Statistical Mechanics · Physics 2008-06-02 K. Baerwinkel , J. Schnack
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