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Physical quantities obtained from the microcanonical entropy surfaces of classical spin systems show typical features of phase transitions already in finite systems. It is demonstrated that the singular behaviour of the microcanonically…

Statistical Mechanics · Physics 2009-11-10 Hans Behringer

It is discussed how phase transitions of first order (with phase separation and surface tension), continuous transitions and (multi)-critical points can be defined and classified for finite systems from the topology of the energy surface…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross , E. Votyakov

Microcanonical thermodynamics (MT) is analysed for phase transitions of first and second order in finite systems. The transiton temperature, the latent heat and the surface tension of first order transitions can easily be determined by MT…

Nuclear Theory · Physics 2007-05-23 D. H. E. Gross

Using the theory of large deviations, we analyze the phase transition structure of the Curie-Weiss-Potts spin model, which is a mean-field approximation to the Potts model. This analysis is carried out both for the canonical ensemble and…

Statistical Mechanics · Physics 2007-05-23 Marius Costeniuc , Richard S. Ellis , Hugo Touchette

Mean-field models, while they can be cast into an {\it extensive} thermodynamic formalism, are inherently {\it non additive}. This is the basic feature which leads to {\it ensemble inequivalence} in these models. In this paper we study the…

Statistical Mechanics · Physics 2007-05-23 Julien Barre' , David Mukamel , Stefano Ruffo

Microcanonical analysis is a powerful method for studying phase transitions of finite-size systems. This method has been used so far only for studying phase transitions of equilibrium systems, which can be described by microcanonical…

Statistical Mechanics · Physics 2016-06-08 Julian Lee

Microcanonical thermodynamics (MCTh) is contrasted to canonical thermodynamics (CTh). At phase transitions of 1.order the two ensembles are NOT equivalent even in the thermodynamic limit . Energy fluctuations do not vanish and phase…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Systems with long-range as well with short-range interactions should necessarily have a convex entropy S(E) at proper phase transitions of first order, i.e. when a separation of phases occurs. Here the microcanonical heat capacity c(E)=…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

We compare the transition barrier that accompanies a first-order phase transition in the canonical and microcanonical ensemble. This is directly encoded in the probability distributions of standard Metropolis Monte Carlo simulations and a…

Statistical Mechanics · Physics 2017-12-06 Wolfhard Janke , Philipp Schierz , Johannes Zierenberg

The investigation of phase coexistence in systems with multi-component order parameters in finite systems is discussed, and as a generic example, Monte Carlo simulations of the two-dimensional q-state Potts model (q=30) on LxL square…

Statistical Mechanics · Physics 2013-03-18 A. Tröster , K. Binder

Microcanonical statistics can be well applied to non-extensive systems like nuclei, atomic clusters and systems at phase transitions of first order with inhomogeneous configurations like phase separation. No thermodynamic limit has to be…

Condensed Matter · Physics 2007-05-23 D. H. E. Gross

The pattern of isentropes in the vicinity of a first-order phase transition is proposed as a key for a sub-classification. While the confinement--deconfinement transition, conjectured to set in beyond a critical end point in the QCD phase…

High Energy Physics - Phenomenology · Physics 2016-05-25 Falk Wunderlich , Roman Yaresko , Burkhard Kampfer

We investigate the nature of the phase transition of the ferromagnetic Potts model with invisible states. The ferromagnetic Potts model with invisible states can be regarded as straightforward extension of the standard ferromagnetic Potts…

Statistical Mechanics · Physics 2011-05-31 Shu Tanaka , Ryo Tamura , Naoki Kawashima

In contrast to the canonical ensemble where thermodynamic functions are smooth for all finite system sizes, the microcanonical entropy can show nonanalytic points also for finite systems, even if the Hamiltonian is smooth. The relation…

Statistical Mechanics · Physics 2007-05-23 Lapo Casetti , Michael Kastner

We introduce a systematic classification method for the analogs of phase transitions in finite systems. This completely general analysis, which is applicable to any physical system and extends towards the thermodynamic limit, is based on…

Statistical Mechanics · Physics 2015-05-28 Stefan Schnabel , Daniel T. Seaton , David P. Landau , Michael Bachmann

In this paper, we draw attention to the problem of phase transitions in systems with locally affine microcanonical entropy, in which partial equivalence of (microcanonical and canonical) ensembles is observed. We focus on a very simple spin…

Statistical Mechanics · Physics 2020-02-19 Agata Fronczak , Piotr Fronczak , Grzegorz Siudem

We present the first detailed numerical study in three dimensions of a first-order phase transition that remains first-order in the presence of quenched disorder (specifically, the ferromagnetic/paramagnetic transition of the site-diluted…

Statistical Mechanics · Physics 2008-02-13 L. A. Fernandez , A. Gordillo-Guerrero , V. Martin-Mayor , J. J. Ruiz-Lorenzo

Systems with long range interactions in general are not additive, which can lead to an inequivalence of the microcanonical and canonical ensembles. The microcanonical ensemble may show richer behavior than the canonical one, including…

Statistical Mechanics · Physics 2015-06-24 Freddy Bouchet , Julien Barre

A first order phase transition is found in a model which was introduced originally by Murthy and Shankar [Phys. Rev. B 60, 6517 (1999)] to describe systems of generalised exclusion statistics. I characterise the phase transition in the…

Statistical Mechanics · Physics 2007-11-15 Dragos-Victor Anghel

Aggregation transitions in disordered mesoscopic systems play an important role in several areas of knowledge, from materials science to biology. The lack of a thermodynamic limit in systems that are intrinsically finite makes the…

Statistical Mechanics · Physics 2022-02-25 L. F. Trugilho , L. G. Rizzi