Related papers: Second Law of Thermodynamics, Macroscopic Observab…
Boltzmann's principleS=k*ln W is generalized to non-equilibrium Hamiltonian systems with possibly fractal distributions in phase space by the box-counting volume. The probabilities P(M) of macroscopic observables M are given by the ratio…
A geometric foundation thermo-statistics is presented with the only axiomatic assumption of Boltzmann's principle S(E,N,V)=k\ln W. This relates the entropy to the geometric area e^{S(E,N,V)/k} of the manifold of constant energy in the…
Boltzmann's principle S(E,N,V)=k\ln W relates the entropy to the geometric area e^{S(E,N,V)} of the manifold of constant energy in the N-body phase space. From the principle all thermodynamics and especially all phenomena of phase…
In the last quarter of the nineteenth century, Ludwig Boltzmann explained how irreversible macroscopic laws, in particular the second law of thermodynamics, originate in the time-reversible laws of microscopic physics. Boltzmann's analysis,…
Boltzmann's principle S(E,N,V)=k*ln W(E,N,V) relates the entropy to the geometric area e^{S(E,N,V)} of the manifold of constant energy in the N-body phase space. From the principle all thermodynamics and especially all phenomena of phase…
Boltzmann's principle S(E,N,V...)=ln W(E,N,V...) allows the interpretation of Statistical Mechanics of a closed system as Pseudo-Riemannian geometry in the space of the conserved parameters E,N,V... (the conserved mechanical parameters in…
In textbooks on statistical mechanics, one finds often arguments based on classical mechanics, phase space and ergodicity in order to justify the second law of thermodynamics. However, the basic equations of motion of classical mechanics…
People are well aware that, inherently, certain small-scale nonchaotic particle movements are not governed by thermodynamics. Usually, such phenomena are studied by kinetic theory and their energy properties are considered "trivial". In…
Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the $N-$body phase space with the given total energy. Due to Boltzmann's principle,…
Boltzmann's Principle S = k ln W was repeatedly criticized by Einstein since it lacked a proper dynamical foundation in view of the thermal motion of the particles, out of which a physical system consists. This suggests, in particular, that…
Recent research on the fundamentals of statistical mechanics has led to an interesting discovery [1-3]: With locally nonchaotic barriers, as Boltzmann's H-theorem is inapplicable, there exist nontrivial non-thermodynamic systems that can…
The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…
Boltzmann's principle is used to select the "most probable" realization (macrostate) of an isolated or closed thermodynamic system, containing a small number of particles ($N \llsp \infty$), for both classical and quantum statistics. The…
In the scientific and engineering literature, the second law of thermodynamics is expressed in terms of the behavior of entropy in reversible and irreversible processes. According to the prevailing statistical mechanics interpretation the…
We investigate the detailed properties of Observational entropy, introduced by \v{S}afr\'{a}nek et al. [Phys. Rev. A 99, 010101 (2019)] as a generalization of Boltzmann entropy to quantum mechanics. This quantity can involve multiple…
We extend stochastic thermodynamics by relaxing the two assumptions that the Markovian dynamics must be linear and that the equilibrium distribution must be a Boltzmann distribution. We show that if we require the second law to hold when…
In quantum statistical mechanics, equilibrium states have been shown to be the typical states for a system that is entangled with its environment, suggesting a possible identification between thermodynamic and von Neumann entropies. In this…
Ludwig Boltzmann had a hunch that irreversibility exhibited by a macroscopic system arises from the reversible dynamics of its microscopic constituents. He derived a nonlinear integro-differential equation - now called the Boltzmann…
Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble, whereas canonical ones fail in the most interesting, mostly inhomogeneous, situations like phase separations or away from the thermodynamic…
The result that closed systems evolve toward equilibrium is derived entirely on the basis of quantum field theory for a model system, without invoking any of the common extra-mathematical notions of particle trajectories, collapse of the…