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Condensation of fluctuations is an interesting phenomenon conceptually distinct from condensation on average. One stricking feature is that, contrary to what happens on average, condensation of fluctuations may occurr even in the absence of…

Statistical Mechanics · Physics 2014-07-31 Marco Zannetti , Federico Corberi , Giuseppe Gonnella

Electrolyte solutions play an important role in energy storage devices, whose performance highly relies on the electrokinetic processes at sub-micron scales.\ Although fluctuations and stochastic features become more critical at small…

Soft Condensed Matter · Physics 2022-06-08 Mingge Deng , Faisal Tushar , Luis Bravo , Anindya Ghoshal , George Karniadakis , Zhen Li

Building on the recently derived inhomogeneous mode-coupling theory, we extend the generalised mode-coupling theory of supercooled liquids to inhomogeneous environments. This provides a first-principles-based, systematic and rigorous way of…

Statistical Mechanics · Physics 2023-01-11 Corentin C. L. Laudicina , Chengjie Luo , Kunimasa Miyazaki , Liesbeth M. C. Janssen

Green-Kubo and Einstein expressions for the transport coefficients of a fluid in a nonequilibrium steady state can be derived using the Fluctuation Theorem and by assuming the probability distribution of the time-averaged dissipative flux…

Statistical Mechanics · Physics 2009-10-31 Debra J. Searles , Denis J. Evans

We develop a field-theoretical description of dynamical heterogeneities and fluctuations in supercooled liquids close to the (avoided) MCT singularity. Using quasi-equilibrium arguments we eliminate time from the description and we…

Statistical Mechanics · Physics 2011-09-23 Silvio Franz , Giorgio Parisi , Federico Ricci-Tersenghi , Tommaso Rizzo

We derive the fluctuating hydrodynamic equation for the number and momentum densities exactly from the underdamped Langevin equation. This derivation is an extension of the Kawasaki-Dean formula in underdamped case. The steady state…

Statistical Mechanics · Physics 2009-03-02 Takenobu Nakamura , Akira Yoshimori

We consider subtle correlations in the scattering of fluid by randomly placed obstacles, which have been suggested to lead to a diverging dispersion coefficient at long times for high Peclet numbers, in contrast to finite mean-field…

Statistical Mechanics · Physics 2009-11-07 Michael W. Deem , Jeong-Man Park

The spreading of density fluctuations in two-dimensional driven diffusive systems is marginally anomalous. Mode coupling theory predicts that the diffusivity in the direction of the drive diverges with time as $(\ln t)^{2/3}$ with a…

Statistical Mechanics · Physics 2018-03-23 Joachim Krug , Robert A. Neiss , Andreas Schadschneider , Johannes Schmidt

The element of metastability is incorporated in the fluctuating nonlinear hydrodynamic description of the mode coupling theory (MCT) of the liquid-glass transition. This is achieved through the introduction of the defect density variable…

Condensed Matter · Physics 2009-10-22 Joonhyun Yeo , Gene F. Mazenko

We report recent progress on the test of mode coupling theory for molecular liquids (MMCT) for molecules of arbitrary shape. The MMCT equations in the long time limit are solved for supercooled water including all molecular degrees of…

Soft Condensed Matter · Physics 2007-05-23 C. Theis , F. Sciortino , A. Latz , R. Schilling , P. Tartaglia

Fluctuation theorems have a very special place in the study of non equilibrium dynamics of physical systems. The form in which it is used most extensively is the Gallavoti-Cohen Fluctuation Theorem which is in terms of the distribution of…

Classical Physics · Physics 2015-12-01 G. S. Agarwal , Sushanta Dattagupta

We begin by placing the Generalized Lagrangian Mean (GLM) equations for a compressible adiabatic fluid into the Euler-Poincar\'e (EP) variational framework of fluid dynamics, for an averaged Lagrangian. We then derive a set of approximate…

Chaotic Dynamics · Physics 2015-06-26 Darryl D. Holm

Using the generalized Langevin equation formalism and the process of contraction of the description we derive a general memory function equation for the thermal fluctuations of the local density of a simple atomic liquid. From the analysis…

Starting from a generalized elastic model which accounts for the stochastic motion of several physical systems such as membranes, (semi)flexible polymers and fluctuating interfaces among others, we derive the fractional Langevin equation…

Statistical Mechanics · Physics 2012-03-16 Alessandro Taloni , Aleksei Chechkin , Joseph Klafter

The statistical mechanical basis of the fluctuation theory of mixtures is reviewed. An overview of the statistical mechanical relations between the microscopic properties of a system and its macroscopic properties is presented. The…

Statistical Mechanics · Physics 2018-11-20 G. Ali Mansoori , Enrico Matteoli

A simple manner to describe the diffusive relaxation of a colloidal fluid adsorbed in a porous medium is to model the porous medium as a set of spherical particles fixed in space at random positions with prescribed statistical structural…

We discuss several approaches to generalized solutions of problems describing the motion of inviscid fluids. We propose a new concept of dissipative solution to the compressible Euler system based on a careful analysis of possible…

Analysis of PDEs · Mathematics 2019-07-04 Dominic Breit , Eduard Feireisl , Martina Hofmanova

We study fluctuations of small noise multiscale diffusions around their homogenized deterministic limit. We derive quantitative rates of convergence of the fluctuation processes to their Gaussian limits in the appropriate Wasserstein metric…

Probability · Mathematics 2024-11-05 Solesne Bourguin , Konstantinos Spiliopoulos

We evaluate the exponentially rare fluctuations of the ionic current for a dilute electrolyte by means of macroscopic fluctuation theory. We consider the fluctuating hydrodynamics of a fluid electrolyte described by a stochastic…

Statistical Mechanics · Physics 2025-07-25 Jafar Farhadi , David T. Limmer

An internal energy function of the mass density, the volumetric entropy and their gradients at n-order generates the representation of multi-gradient fluids. Thanks to Hamilton's principle, we obtain a thermodynamical form of the equation…

Fluid Dynamics · Physics 2018-03-19 Henri Gouin