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Related papers: A new type of neutral-ionic interface in mixed-sta…

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Application of about 0.8 GPa pressure is sufficient to induce the neutral-ionic transition in the mixed stack charge-transfer crystal 2-chloro-5-methyl-$p$-phenylenediamine--2,5-dimethyl-dicyanoquinonediimine ({\CD}). The ionicity increases…

Materials Science · Physics 2009-11-07 Luca Farina , Aldo Brillante , Matteo Masino , Alberto Girlando

We report a detailed spectroscopic investigation of temperature-induced valence and structural instability of the mixed-stack organic charge-transfer (CT) crystal 4,4'-dimethyltetrathiafulvalene-chloranil (DMTTF-CA). DMTTF-CA is a…

Materials Science · Physics 2024-11-26 Paolo Ranzieri , Matteo Masino , Alberto Girlando , Marie-Helene Lemee-Cailleau

We investigated the mixed-stack charge-transfer crystal, N,N'-dimethylphenazine-TCNQ (M$_2$P-TCNQ), which is polar at room temperature and just at the neutral-to-ionic interface (ionicity $\rho \approx 0.5$). We detect the typical…

Strongly Correlated Electrons · Physics 2021-03-10 J. K. H. Fischer , G. D'Avino , M. Masino , F. Mezzadri , P. Lunkenheimer , Z. G. Soos , A. Girlando

The Temperature Induced Neutral to Ionic phase Transition (TI-NIT) is a rare phenomenon occurring in mixed stack charge transfer (CT) crystals made up of alternating $\pi$-electron Donor (D) and Acceptor (A) molecules. We were able to grow…

Materials Science · Physics 2022-03-14 Elena Ferrari , Francesco Mezzadri , Matteo Masino

A possibility was assessed to modify physico-chemical properties of ferronematic mixtures by introducing additional mesogenic and non-mesogenic components. The mixture, consisting of RM734 and DIO at the 70:30 weight ratio of the…

Layered tin selenide (SnSe) has recently emerged as a high-performance thermoelectric material with the current record for the figure of merit (ZT) observed in the high-temperature Cmcm phase. So far, access of the Cmcm phase has been…

Phase transitions in 1/4-filled quasi-one-dimensional molecular conductors are studied theoretically on the basis of extended Hubbard chains including electron-lattice interactions coupled by interchain Coulomb repulsion. We apply the…

Strongly Correlated Electrons · Physics 2007-05-23 Hitoshi Seo , Yukitoshi Motome , Takeo Kato

Photo-induced charge transfer of positive and negative charges across the interface between an ordered organic semiconductor and a polymeric insulator is observed in the field-effect experiments. Immobilization of the transferred charge in…

Materials Science · Physics 2009-11-10 V. Podzorov , M. E. Gershenson

Theory and simulations of simultaneous chemical demixing and phase ordering are performed for a mixed order parameter system with an isotropic-isotropic (I-I) phase separation that is metastable with respect to an isotropic-nematic (I-N)…

Soft Condensed Matter · Physics 2015-06-17 Ezequiel R. Soule , Cyrille Lavigne , Linda Reven , Alejandro D. Rey

Single crystals of Nd0.5Ca0.5MnO3 and Pr0.6Ca0.4MnO3 show current-induced insulator-metal transitions at low temperatures. In addition, the charge-ordering transition temperature decreases with increasing current. The electroresistive…

Materials Science · Physics 2009-11-10 Sachin Parashar , L. Sudheendra , A. R. Raju , C. N. R. Rao

Several calorimetric measurements have shown that 1-ethyl-3-methylimidazolium dicyanamide, [C2C1im][N(CN)2], is a glass-forming liquid, even though it is a low-viscous liquid at room temperature. Here we found slow crystallization during…

Chemical Physics · Physics 2021-07-28 Kalil Bernardino , Thamires A. Lima , Mauro C. C. Ribeiro

The electrostatic screening properties of ionic fluids are of paramount importance in countless physical processes. Yet, the behavior of ionic conductors out of thermal equilibrium has to date mainly been studied in the context of…

Statistical Mechanics · Physics 2023-04-19 Andrea Grisafi , Federico Grasselli

The neutral-to-ionic phase transition in the mixed-stack charge-transfer complex tetrathiafulvalene-p-chloranil (TTF-CA) has been studied by pressure-dependent infrared spectroscopy up to p=11 kbar and down to low temperatures, T = 10 K. By…

Strongly Correlated Electrons · Physics 2014-07-01 A. Dengl , R. Beyer , T. Peterseim , T. Ivek , G. Untereiner , M. Dressel

The prototype compound for the neutral-ionic phase transition, namely TTF-CA, is theoretically investigated by first-principles density functional theory calculations. The study is based on three neutron diffraction structures collected at…

Condensed Matter · Physics 2009-11-07 V. Oison , C. Katan , P. Rabiller , M. Souhassou , C. Koenig

An adiabatic transition between two equilibrium states corresponding to different stiffnesses in an infinite chain of particles is studied. Initially, the chain particles have random displacements and random velocities corresponding to a…

Statistical Mechanics · Physics 2020-11-04 Anton M. Krivtsov , Andrey S. Murachev

Selenium (Se) substitution drastically increases the transition temperature of iridium ditelluride (IrTe$_{2}$) to a diamagnetic superstructure from 278 K to 560 K. Transmission electron microscopy experiments revealed that this enhancement…

Strongly Correlated Electrons · Physics 2013-03-26 Yoon Seok Oh , J. J. Yang , Y. Horibe , S. -W. Cheong

We numerically examine the transport of skyrmions driven over weak random quenched disorder using a modified Thiele approach that includes the thermal softening of skyrmion pairwise interactions introduced by Wang et al., Phys. Rev. Appl.…

Mesoscale and Nanoscale Physics · Physics 2024-04-23 C. Reichhardt , C. J. O. Reichhardt

(TaSe$_4$)$_3$I, a compound belonging to the family of quasi-one-dimensional transition-metal tetrachalcogenides, has drawn significant attention due to a recent report on possible coexistence of two antagonistic phenomena,…

Strongly Correlated Electrons · Physics 2023-07-19 Arnab Bera , Samir Rom , Suman Kalyan Pradhan , Satyabrata Bera , Sk Kalimuddin , Tanusri Saha-Dasgupta , Mintu Mondal

The effects of multiwalled carbon nanotubes (NTs) on low-temperature phase transformations in 5CB were studied by means of differential scanning calorimetry (DSC), low-temperature photoluminescence and measurements of electrical…

Soft Condensed Matter · Physics 2015-06-15 N. Lebovka , V. Melnyk , Ye. Mamunya , G. Klishevich , A. Goncharuk , N. Pivovarova

A Wigner crystal formed with trapped ion can undergo structural phase transition, which is determined only by the mechanical conditions on a classical level. Instead of this classical result, we show that through consideration of quantum…

Strongly Correlated Electrons · Physics 2011-02-09 Zhe-Xuan Gong , G. -D. Lin , L. -M. Duan
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