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We use non-equilibrium atomistic molecular dynamics simulations of unentangled melts of linear and star polymers ($\mathrm{C_{25}H_{52}}$) to study the steady-state viscoelastic response under confinement within nanoscale hematite $\left (…

Soft Condensed Matter · Physics 2023-03-17 Ahmet Burak Yıldırım , Aykut Erbaş , Luca Biancofiore

Molecular dynamics simulations are used to investigate the conformations of a single polymer chain, represented by the Kremer-Grest bead-spring model, in a solution with a Lennard-Jones liquid as the solvent when the interaction strength…

Soft Condensed Matter · Physics 2021-11-17 Yisheng Huang , Shengfeng Cheng

We study numerically the crystallization of a hard-sphere mixture with 8\% polydispersity. Although often used as a model glass former, for small system sizes we observe crystallization in molecular dynamics simulations. This opens the…

Soft Condensed Matter · Physics 2016-09-05 Matteo Campo , Thomas Speck

The adhesion between a polymer melt and substrate is studied in the presence of chemically attached chains on the substrate surface. Extensive molecular dynamics simulations have been carried out to study the effect of temperature, tethered…

Materials Science · Physics 2016-08-31 Scott W. Sides , Gary S. Grest , Mark J. Stevens

Polymer melts represent the flow-history-dependent behavior. To clearly show this behavior, we have investigated flow behavior of an entangled polymer melt around two cylinders placed in tandem along the flow direction in a two dimensional…

Soft Condensed Matter · Physics 2015-05-30 Takahiro Murashima , Takashi Taniguchi

We map out the solid-state morphologies formed by model soft-pearl-necklace polymers as a function of bending stiffness $k_b$ spanning the range from fully flexible to rodlike chains. The ratio of Kuhn length to bead diameter ($l_K/r_0$)…

Soft Condensed Matter · Physics 2015-10-28 Hong T. Nguyen , Tyler B. Smith , Robert S. Hoy , Nikos Ch. Karayiannis

In the cell, protein complexes form relying on specific interactions between their monomers. Excluded volume effects due to molecular crowding would lead to correlations between molecules even without specific interactions. What is the…

Soft Condensed Matter · Physics 2015-05-13 Wei Wang , Wei-Xin Xu , Y. Levy , E. Trizac , P. G. Wolynes

Polymers with both soluble and insoluble blocks typically self-assemble into micelles, aggregates of a finite number of polymers where the soluble blocks shield the insoluble ones from contact with the solvent. Upon increasing…

Soft Condensed Matter · Physics 2009-11-13 J. A. Anderson , C. D. Lorenz , A. Travesset

Systems in which particles can self-assemble into mono- or bilayers can form variety of stable and metastable structures on a nanometer length scale. For this reason confinement has a particularly strong effect on such systems. We discuss…

Soft Condensed Matter · Physics 2007-05-23 A. Ciach , V. Babin , M. Tasinkevych

We generalize a recently investigated lattice model of semiflexible polymers formed under equilibrium polymerization in a solution and conduct a comprehensive investigation of its melting properties. The model is characterized by six…

Condensed Matter · Physics 2007-05-23 Sagar S. Rane , P. D. Gujrati

Configurations of a single semiflexible polymer is studied when it is pushed into a nanochannel in the case where the polymer persistence length $l_p$ is much longer than the channel diameter $D$, i.e. $l_p/D \gg 1$. Using numerical…

Statistical Mechanics · Physics 2017-06-28 Yumino Hayase , Takahiro Sakaue , Hiizu Nakanishi

We study the spontaneous nucleation and crystallization of linear and cyclic chains of flexibly connected hard spheres using extensive molecular dynamics simulations. To this end, we present a novel event-driven molecular dynamics…

Soft Condensed Matter · Physics 2012-06-27 Ran Ni , Marjolein Dijkstra

On the basis of laboratory simulation a mechanism is established for the formation of the upper mantle convection spiral plumes from a hot point in the presence of a roll-type large-scale convective flow. The observed plume has horizontal…

Fluid Dynamics · Physics 2015-03-13 A. N. Sharifulin , A. N. Poludnitsin

This study focuses on comparing the individual polymer chain dynamics in an entangled polymeric liquid under different shear and extension rates. Polymer chains under various shear rates and extension rates were simulated using a…

Chemical Physics · Physics 2021-01-15 Behrouz Behdani , Tong Mou , Cody Spratt , Slava Butcovich , Ryan Gettler , Joontaek Park

Interest in the protein folding problem has motivated a wide range of theoretical and experimental studies of the kinetics of the collapse of flexible homopolymers. In this Paper a phenomenological model is proposed for the kinetics of the…

Soft Condensed Matter · Physics 2009-10-31 A. Halperin , Paul M. Goldbart

We use Monte Carlo simulations to study polymer melts consisting of fully flexible and moderately stiff chains in the bond fluctuation model at a volume fraction $0.5$. In order to reduce the local density fluctuations, we test a…

Soft Condensed Matter · Physics 2015-06-24 Hsiao-Ping Hsu

Mesogens, which are typically stiff rodlike or disklike molecules, are able to self-organize into liquid crystal (LC) phases in a certain temperature range. Such mesogens, or LC groups, can be attached to polymer chains in various…

Soft Condensed Matter · Physics 2023-06-21 Diego Becerra , Pranav R. Jois , Lisa M. Hall

Granular packings of non-convex or elongated particles can form free-standing structures like walls or arches. For some particle shapes, such as staples, the rigidity arises from interlocking of pairs of particles, but the origins of…

Soft Condensed Matter · Physics 2020-07-06 Yuchen Zhao , Jonathan Barés , Joshua E. S. Socolar

We analyze the crystallization and collapse transition of a simple model for flexible polymer chains on simple cubic and face-centered cubic lattices by means of sophisticated chain-growth methods. In contrast to bond-fluctuation polymer…

Soft Condensed Matter · Physics 2009-11-13 Thomas Vogel , Michael Bachmann , Wolfhard Janke

Investigating thermodynamic properties of liquid-solid transitions of flexible homopolymers with elastic bonds by means of multicanonical Monte Carlo simulations, we find crystalline conformations that resemble ground-state structures of…

Soft Condensed Matter · Physics 2010-02-11 Stefan Schnabel , Thomas Vogel , Michael Bachmann , Wolfhard Janke