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We discuss a general approach to a realistic theory of the electronic structure in materials containing correlated d- or f- electrons. The main feature of this approach is the taking into account the energy dependence of the electron…

Strongly Correlated Electrons · Physics 2009-10-30 A. I. Lichtenstein , M. I. Katsnelson

We show that incorporation of strong electron correlations into the Kohn-Sham scheme of band structure calculations leads to a modification of the standard model of the lanthanides and that this procedure removes the existing discrepancy…

Strongly Correlated Electrons · Physics 2015-06-24 U. Lundin , I. Sandalov , O. Eriksson , B. Johansson

Atoms and ions of Lanthanides have multiple opens shells along with an open $4f^k$ subshell. This paper studies the effect of electron correlation in such systems and how wave functions can be determined for the accurate prediction of…

Atomic Physics · Physics 2019-06-04 Charlotte Froese Fischer , Michel R. Godefroid

The electronic structure of lanthanide and actinide compounds is often characterized by orbital ordering of localized $f$-electrons. Density-functional theory (DFT) studies of such systems using the currently available LDA+$U$ method are…

Strongly Correlated Electrons · Physics 2015-11-17 Fei Zhou , Vidvuds Ozolins

The electronic structures of several actinide solid systems are calculated using the self-interaction corrected local spin density approximation. Within this scheme the $5f$ electron manifold is considered to consist of both localized and…

Strongly Correlated Electrons · Physics 2007-05-23 L. Petit , A. Svane , Z. Szotek , W. M. Temmerman

We propose a self-consistent method for electronic structure calculations of correlated systems, which combines the local spin-density approximation (LSDA) and the dynamical mean field theory (DMFT). The LSDA part is based on the exact…

Strongly Correlated Electrons · Physics 2007-05-23 L. Chioncel , L. Vitos , I. A. Abrikosov , J. Kollar , M. I. Katsnelson , A. I. Lichtenstein

A novel approach to investigation of correlation effects in the electronic structure of magnetic crystals which takes into account a frequency dependence of the self energy (so called ``LDA++ approach'') is developed. The fluctuation…

Strongly Correlated Electrons · Physics 2009-10-31 M. I. Katsnelson , A. I. Lichtenstein

An exchange-correlation energy functional beyond the local density approximation, based on the exchange-correlation kernel of the homogeneous electron gas and originally introduced by Kohn and Sham, is considered for electronic structure…

Condensed Matter · Physics 2016-08-31 Maurizia Palummo , Giovanni Onida , Rodolfo Del Sole

Coulomb interactions that occur in electronic structure calculations are correlated by allowing basis function components of the interacting densities to polarize, thereby reducing the magnitude of the interaction. Exchange integrals of…

Chemical Physics · Physics 2022-05-16 Jerry L. Whitten

Including on-site electronic interactions described by the multi-orbital Hubbard model we study the correlation effects in the electronic structure of bulk palladium. We use a combined density functional and dynamical mean field theory,…

Strongly Correlated Electrons · Physics 2016-05-04 A. Östlin , W. H. Appelt , I. Di Marco , W. Sun , M. Radonjic , M. Sekania , L. Vitos , O. Tjernberg , L. Chioncel

We present a method for calculating the electronic structure of correlated materials based on a truly first-principles LDA+U scheme. Recently we suggested how to calculate U from first-principles, using a method which we named constrained…

Strongly Correlated Electrons · Physics 2010-06-17 K. Karlsson , F. Aryasetiawan , O. Jepsen

The calculation of electronic properties of materials is an important task of solid state theory, albeit particularly difficult if electronic correlations are strong, for example in transition metals, their oxides and in f-electron systems.…

Strongly Correlated Electrons · Physics 2009-09-29 K. Held

Effects of electron correlation on the electronic structure and magnetic properties of the Gd(0001) surface are investigated using of the full-potential linearized augmented plane wave implementation of correlated band theory ("LDA+U"). The…

Strongly Correlated Electrons · Physics 2009-10-31 A. B. Shick , W. E. Pickett , C. S. Fadley

Ab initio calculation of the electronic properties of materials is a major challenge for solid state theory. Whereas the experience of forty years has proven density functional theory (DFT) in a suitable, e.g. local approximation (LDA) to…

Strongly Correlated Electrons · Physics 2009-11-13 K. Held , O. K. Andersen , M. Feldbacher , A. Yamasaki , Y. -F. Yang

We give a detailed description of a recently proposed first principles approach to the electronic structure of strongly correlated materials. The method combines the GW approximation with dynamical mean field theory. It is designed to…

Strongly Correlated Electrons · Physics 2007-05-23 Ferdi Aryasetiawan , Silke Biermann , Antoine Georges

The strength of electronic correlation effects in the spin-dependent electronic structure of ferromagnetic bcc Fe(110) has been investigated by means of spin and angle-resolved photoemission spectroscopy. The experimental results are…

A new scheme of first-principles computation for strongly correlated electron systems is proposed. This scheme starts from the local-density approximation (LDA) at high-energy band structure, while the low-energy effective Hamiltonian is…

Materials Science · Physics 2007-05-23 Yoshiki Imai , Igor V. Solovyev , Masatoshi Imada

The ultimate goal of electronic structure calculations is to make the left and right hand sides of the titled ``equation'' as close as possible. This requires high-precision treatment of relativistic, correlation, and quantum…

Chemical Physics · Physics 2022-10-10 Wenjian Liu

A self-consistent calculation scheme for correlated electron systems is created based on the density-functional theory (DFT). Our scheme is a multi-reference DFT (MR-DFT) calculation in which the electron charge density is reproduced by an…

Strongly Correlated Electrons · Physics 2009-11-13 Koichi Kusakabe , Naoshi Suzuki , Shusuke Yamanaka , Kizashi Yamaguchi

We present results for the electronic structure of alpha uranium using a recently developed quasiparticle self-consistent GW method (QSGW). This is the first time that the f-orbital electron-electron interactions in an actinide has been…

Strongly Correlated Electrons · Physics 2009-07-21 Athanasios N. Chantis , R. C. Albers , M. D. Jones , Mark van Schilfgaarde , Takao Kotani
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