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An apparent violation of the second law of thermodynamics occurs when an atom coupled to a zero-temperature bath, being necessarily in an excited state, is used to extract work from the bath. Here the fallacy is that it takes work to couple…

Quantum Physics · Physics 2009-11-13 G. W. Ford , R. F. O'Connell

We propose a new form of the Second Law inequality that defines a tight bound for extractable work from the non-equilibrium quantum state. In classical thermodynamics, the optimal work is given by the difference of free energy, what…

Quantum Physics · Physics 2023-02-14 Marcin Łobejko

A.E. Allahverdyan and Th. M. Nieuwenhuizen [1] in their paper "A mathematical theorem as a basis for the second law: Thomson's formulation applied to equilibriium" present a proof of the second law of thermodynamics based on quantum…

Quantum Physics · Physics 2007-05-23 Dan Solomon

The second law of thermodynamics places a limitation into which states a system can evolve into. For systems in contact with a heat bath, it can be combined with the law of energy conservation, and it says that a system can only evolve into…

Quantum Physics · Physics 2015-11-20 Piotr Ćwikliński , Michał Studziński , Michał Horodecki , Jonathan Oppenheim

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where…

Quantum Physics · Physics 2021-08-31 Philipp Strasberg , Andreas Winter

The stationary state of a quantum particle strongly coupled to a quantum thermal bath is known to be non-gibbsian, due to entanglement with the bath. For harmonic potentials, where the system can be described by effective temperatures,…

Statistical Mechanics · Physics 2009-10-31 A. E. Allahverdyan , Th. M. Nieuwenhuizen

Fluctuations of thermodynamic observables, such as heat and work, contain relevant information on the underlying physical process. These fluctuations are however not taken into account in the traditional laws of thermodynamics. While the…

Quantum Physics · Physics 2022-05-25 Timo Kerremans , Peter Samuelsson , Patrick P. Potts

Traditional discussions of the Second Law of Thermodynamics studied the limits of very specific types of devices, such as heat engines, chemical reactions, and molecules channeled by valves. Allahverdyan and Nieuwenhuizen (cond-mat/0110422)…

Statistical Mechanics · Physics 2007-05-23 Paul J. Werbos

The second law of thermodynamics tells us which state transformations are so statistically unlikely that they are effectively forbidden. Its original formulation, due to Clausius, states that "Heat can never pass from a colder to a warmer…

Several models of quantum open systems are known at present to violate, according to principles of the standard quantum theory of open systems, the second law of thermodynamics. Here, a new and rather trivial model of another type is…

Statistical Mechanics · Physics 2007-05-23 V. Capek

The Brownian motion of a quantum particle in a harmonic confining potential and coupled to a harmonic quantum thermal bath is exactly solvable. It is shown that at low enough temperatures the stationary state is non-Gibbsian due to an…

Statistical Mechanics · Physics 2007-05-23 Th. M. Nieuwenhuizen , A. E. Allahverdyan

Understanding thermodynamics far from equilibrium at the quantum scale remains a fundamental challenge, particularly in the presence of quantum coherence. Here we develop a first-principles framework for nonequilibrium quantum…

Quantum Physics · Physics 2026-02-11 Md Manirul Ali , Po-Wen Chen

We consider a single harmonic oscillator coupled to a bath at zero temperature. As is well known, the oscillator then has a higher average energy than that given by its ground state. Here we show analytically that for a damping model with…

Quantum Physics · Physics 2009-11-13 ILki Kim , Guenter Mahler

In the classical limit no work is needed to couple a system to a bath with sufficiently weak coupling strength (or with arbitrarily finite coupling strength for a linear system) at the same temperature. In the quantum domain this may be…

Quantum Physics · Physics 2009-11-13 Ilki Kim , Guenter Mahler

The first law of thermodynamics restates the law of conservation of energy. It partitions the change in energy of a system into two pieces, heat and work. While there is no ambiguity to define heat and work in classical thermodynamics,…

Quantum Physics · Physics 2023-01-19 Xue-Qun Yan , Yan-Jiao Du , Wen-Tao Hou , Xiao-Ming Liu

Quantum decoherence is seen as an undesired source of irreversibility that destroys quantum resources. Quantum coherences seem to be a property that vanishes at thermodynamic equilibrium. Away from equilibrium, quantum coherences challenge…

Quantum Physics · Physics 2013-08-13 César A. Rodríguez-Rosario , Thomas Frauenheim , Alán Aspuru-Guzik

We pointed out that the generalized second law of thermodynamics on a de Sitter universe whose energy density stochastically fluctuates due to quantum fluctuations is seemingly violated. We have shown that even in such a case, the…

General Relativity and Quantum Cosmology · Physics 2018-01-17 Naritaka Oshita

The example provided in the comment [arXiv:0803.2241] concerns a situation where the system is initially at negative temperature. It is known that in such cases the Law of Entropy Decrease holds. Nevertheless, this does not challenge the…

Quantum Physics · Physics 2008-04-09 Michele Campisi

In our recent letter [1] we discussed that thermodynamics is violated in quantum Brownian motion beyond the weak coupling limit. In his comment, Tasaki [2] derives an inequality for the relative entropy and claims, without making any…

Statistical Mechanics · Physics 2007-05-23 A. E. Allahverdyan , Th. M. Nieuwenhuizen

The Brownian motion of a harmonically bound quantum particle and coupled to a harmonic quantum bath is exactly solvable. At low enough temperatures the stationary state is non-Gibbsian due to an entanglement with the bath. This happens when…

Statistical Mechanics · Physics 2009-11-07 Theo M. Nieuwenhuizen , Armen E. Allahverdyan
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