Related papers: Binding of Similarly Charged Plates: A Global Anal…
We present an analytical approach to the strong coupling regime of similarly and highly charged plates in the presence of counter-ions. The procedure is physically transparent and based on an exact expansion around the ground state formed…
We are interested in rationalizing the phenomenon of like-charge attraction between charged bodies, such as a pair of colloids, in the strong coupling regime. The two colloids are modelled as uniformly charged parallel plates, neutralized…
We predict the nature (attractive or repulsive) and range (exponentially screened or long-range power law) of the electrostatic interactions of oppositely charged and planar plates as a function of the salt concentration and surface charge…
Within a mean field treatment of the interaction between two oppositely charged plates in a salt free solution, the distance at which a transition from an attractive to a repulsive regime appears can be computed analytically. The mean field…
Despite decades of intensive studies, the effective interactions between strongly charged colloids still remain elusive. Here we show that a strongly charged surface with a layer of condensed counter- ions behaves effectively as a…
We compare weak and strong coupling theory of counterion-mediated electrostatic interactions between two asymmetrically charged plates with extensive Monte-Carlo simulations. Analytical results in both weak and strong coupling limits…
By a combination of Monte Carlo simulations and analytical calculations, we investigate the effective interactions between highly charged planar interfaces, neutralized by mobile counterions (salt-free system). While most previous analysis…
The Poisson-Boltzmann (PB) theory is extensively used to gain insight on charged colloids and biological systems as well as to elucidate fundamental properties of intermolecular forces. Many works were devoted in the past to study PB…
Monte Carlo simulations were employed to study two negative rods confined between two parallel plates. The system is immersed in a 1-1 restricted primitive model electrolyte. Ion distributions and forces per unit of area (pressures) on rods…
The screening of plate-plate interactions by counterions is an age-old problem. We revisit this classic question when counterions exhibit a distribution of charges. While it is expected that the long-distance regime of interactions is…
Charged soft-matter systems--such as colloidal dispersions and charged polymers--are dominated by attractive forces between constituent like-charged particles when neutralizing counterions of high charge valency are introduced. Such…
We study the interactions between two negatively charged macroscopic surfaces confining positive counterions. A density-functional approach is introduced which, besides the usual mean-field interactions, takes into account the correlations…
We propose a new mechanism for binding of two equally charged carriers in a double-layer system subjected by a magnetic field of a special form. A field configuration for which the magnetic fields in adjacent layers are equal in magnitude…
By a length scale analysis, we study the equilibrium interactions between two like-charge planes confining neutralising counter-ions. At large Coulombic couplings, approaching the two charged bodies leads to an unbinding of counter-ions, a…
Like-charged macroions attract each other as a result of strong electrostatic correlations in the presence of multivalent counterions or at low temperatures. We investigate the effective electrostatic interaction between i) two like-charged…
In mixtures of colloids and nonadsorbing polyelectrolytes, a Donnan potential arises across the region between surfaces that are depleted of polyelectrolyte and the rest of the system. This Donnan potential tends to shift the…
The interaction force between likely charged particles/surfaces is usually repulsive due to the Coulomb interaction. However, the counterintuitive like-charge attraction in electrolytes has been frequently observed in experiments, which has…
We consider an overall neutral system consisting of two similarly charged plates and their oppositely charged counterions and analyze the electrostatic interaction between the two surfaces beyond the mean-field Poisson-Boltzmann…
A simple field theory approach is developed to model the properties of charged, dielectric bodies and their associated counterions. This predictive theory is able to accurately describe the properties of systems (as compared to computer…
Monte Carlo simulations were employed to study two charged rods confined between two unlike charged plates, all immersed in a model electrolyte. Recently, it was shown that two rods immersed in a multivalent counterion solution may show…