Related papers: Accurate effective pair potentials for polymer sol…
Inverse methods of statistical mechanics are becoming productive tools in the design of materials with specific microstructures or properties. While initial studies have focused on solid-state design targets (e.g, assembly of colloidal…
The penetrable-square-well (PSW) pair interaction potential is defined as $\phi (r)=\epsilon_r$ if the two interacting particles are overlapped ($r<\sigma$), $\phi(r)=-\epsilon_a$ inside a corona ($\sigma <r<\lambda$), and $\phi(r)=0$…
We present a computer simulation of entangled polymer solutions at equilibrium. The chains repel each other via a soft Gaussian potential, appropriate for semi-dilute solutions at the scale of a correlation blob. The key innovation to…
Using a density functional based interface displacement model we determine the effective interaction potential between two spherical particles which are immersed in a homogeneous fluid such as the vapor phase of a one-component substance or…
This contribution briefly reviews some recent work demonstrating the partial breakdown of the colloidal fluid <--> atomic fluid analogy. The success of liquid state theory for atomic fluids stems in part from the van der Waals picture,…
When a colloid is mixed with a depletant such as a non-adsorbing polymer, one observes attractive effective interactions between the colloidal particles. If these particles are anisotropic, analysis of these effective interactions is…
Self-avoiding walks and self-avoiding trails, two models of a polymer coil in dilute solution, have been shown to be governed by the same universality class. On the other hand, self-avoiding walks interacting via nearest-neighbour contacts…
Understanding and computing the entropic forces exerted by polymer chains under confinement is important for many reasons, from research to applications. However, extracting properties related to the free energy, such as the force (or…
Effective colloid-colloid interactions can be tailored through the addition of a complex cosolute. Here we investigate the case of a cosolute made by self-assembling patchy particles. Depending on the valence, these particles can form…
The effective interaction between two planar walls immersed in a fluid is investigated by use of Density Functional Theory in the super-critical region of the phase diagram. A hard core Yukawa model of fluid is studied with special…
A method for measuring the pair interaction potential between colloidal particles by extrapolation measurement of collective structure to infinite dilution is presented and explored using simulation and experiment. The method is…
An outstanding problem in statistical mechanics is the determination of whether prescribed functional forms of the pair correlation function $g_2(r)$ [or equivalently, structure factor $S(k)$] at some number density $\rho$ can be achieved…
Self-avoiding walks self-interacting via nearest neighbours (ISAW) and self-avoiding trails interacting via multiply-visited sites (ISAT) are two models of the polymer collapse transition of a polymer in dilute solution. On the square…
We study the thermodynamics of an exactly solvable model of a self-interacting partially directed self-avoiding walk (DSAW) in two dimensions, when a force is applied on one end of the chain. The critical force for the unfolding is…
We model a set of point-to-point transports on a network as a system of polydisperse interacting self-avoiding walks (SAWs) over a finite square lattice. The ends of each SAW may be located both at random, uniformly distributed, positions…
It has been recently argued that interacting self-avoiding walks (ISAW) of length $ \ell , $ in their low temperature phase (i.e. below the $ \Theta $-point) should have a partition function of the form: $$ Q_{\ell} \sim \mu^{ \ell}_ 0\mu^{…
The role of solvent quality in determining the universal material properties of dilute polymer solutions undergoing steady simple shear flow is examined. A bead-spring chain representation of the polymer molecule is used, and the influence…
We study the dynamics of polymer chains in a bath of self-propelled particles (SPP) by extensive Langevin dynamics simulations in a two dimensional system. Specifically, we analyse the polymer looping properties versus the SPP activity and…
As first explained by the classic Asakura-Oosawa (AO) model, effective attractive forces between colloidal particles induced by depletion of nonadsorbing polymers can drive demixing of colloid-polymer mixtures into colloid-rich and…
The density crossover scaling of various thermodynamic properties of solutions and melts of self-avoiding and highly flexible polymer chains without chain intersections confined to strictly two dimensions is investigated by means of…