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We describe a global optimization technique using `basin-hopping' in which the potential energy surface is transformed into a collection of interpenetrating staircases. This method has been designed to exploit the features which recent work…

Condensed Matter · Physics 2007-05-23 David Wales , Jonathan Doye

Recently, Locatelli and Schoen proposed a transformation of the potential energy that aids the global optimization of Lennard-Jones clusters with non-icosahedral global minima. These cases are particularly difficult to optimize because the…

Condensed Matter · Physics 2007-05-23 Jonathan Doye

Anticipating the low energy arrangements of atoms in space is an indispensable scientific task. Modern stochastic approaches to searching for these configurations depend on the optimisation of structures to nearby local minima in the energy…

Materials Science · Physics 2019-02-07 Chris J. Pickard

It has previously been proven that finding the globally minimum energy configuration of an atomic cluster belongs in the class of NP-hard problems. However, this proof is limited only to homonuclear clusters. This paper presents a new proof…

Atomic and Molecular Clusters · Physics 2007-05-23 G. W. Greenwood

A new strategy for global geometry optimization of clusters is presented. Important features are a restriction of search space to favorable nearest-neighbor distance ranges, a suitable cluster growth representation with diminished…

chem-ph · Physics 2009-10-28 Bernd Hartke

Locating the global minimum of a complex potential energy surface is facilitated by considering a homotopy, namely a family of surfaces that interpolate continuously from an arbitrary initial potential to the system under consideration.…

Computational Physics · Physics 2009-11-07 J. S. Hunjan , S. Sarkar , R. Ramaswamy

The global minima of clusters bound by a Dzugutov potential form non-compact polytetrahedral clusters mainly composed of interpenetrating and face-sharing 13-atom icosahedra. As the size increases, these icosahedral units first form linear…

Condensed Matter · Physics 2007-05-23 Jonathan Doye , David Wales , Sergei Simdyankin

We present a method for reliably determining the lowest energy structure of an atomic cluster in an arbitrary model potential. The method is based on a genetic algorithm, which operates on a population of candidate structures to produce new…

mtrl-th · Physics 2009-10-28 D. M. Deaven , K. M. Ho

We introduce a method for global optimization of the structure of atomic systems that uses additional atoms with fractional existence. The method allows for movement of atoms over long distances bypassing energy barriers encountered in the…

Adaptive quantum design identifies the best broken-symmetry configurations of atoms and molecules that enable a desired target function response. In this work, numerical optimization is used to design atomic clusters with specified…

Strongly Correlated Electrons · Physics 2009-11-10 Jason Thalken , Yu Chen , A. F. J. Levi , Stephan Haas

We introduce a computational method to optimize target physical properties in the full configuration space regarding atomic composition, chemical stoichiometry, and crystal structure. The approach combines the universal potential of the…

Materials Science · Physics 2025-03-03 Guanjian Cheng , Xin-Gao Gong , Wan-Jian Yin

Theoretical design of global optimization algorithms can profitably utilize recent statistical mechanical treatments of potential energy surfaces (PES's). Here we analyze the basin-hopping algorithm to explain its success in locating the…

Statistical Mechanics · Physics 2007-05-23 Jonathan Doye , David Wales , Mark Miller

Modelling and understanding properties of materials from first principles require knowledge of the underlying atomistic structure. This entails knowing the individual identity and position of all involved atoms. Obtaining such information…

Chemical Physics · Physics 2023-07-06 Mads-Peter Verner Christiansen , Nikolaj Rønne , Bjørk Hammer

The implementation of adaptive genetic algorithms (AGA) for optimization problems has proven to be superior than many other methods due to its nature of producing more robust and high quality solutions. Considering the complexity involved…

Computational Physics · Physics 2024-11-28 Brandon Willnecker , Mervlyn Moodley

A new atomic cluster structure corresponding to the global minimum of the 98-atom Lennard-Jones cluster has been found using a variant of the basin-hopping global optimization algorithm. The new structure has an unusual tetrahedral symmetry…

Condensed Matter · Physics 2007-05-23 Robert Leary , Jonathan Doye

A new concept of the molecular structure optimization method based on quantum dynamics computations is presented. Nuclei are treated as quantum mechanical particles, as are electrons, and the many-body wave function of the system is…

Global changes of states are of crucial importance in optimization algorithms. We review some heuristic algorithms in which global updates are realized by a sort of real-space renormalization group transformation. Emphasis is on the…

Disordered Systems and Neural Networks · Physics 2009-10-31 Naoki Kawashima

Several commonly observed physical and biological systems are arranged in shapes that closely resemble an honeycomb cluster, that is, a tessellation of the plane by regular hexagons. Although these shapes are not always the direct product…

Optimization and Control · Mathematics 2025-01-10 Marco Caroccia , Kenneth DeMason , Francesco Maggi

We introduce a global optimization approach for binary clusters that for a given cluster size is able to directly search for the structure and composition that has the greatest stability. We apply this approach to binary Lennard-Jones…

Other Condensed Matter · Physics 2007-05-23 Jonathan P. K. Doye , Lars Meyer

Associative memory Hamiltonian structure prediction potentials are not overly rugged, thereby suggesting their landscapes are like those of actual proteins. In the present contribution we show how basin-hopping global optimization can…

Biomolecules · Quantitative Biology 2009-11-13 Michael C. Prentiss , David J. Wales , Peter G. Wolynes
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