Related papers: Entanglements in a Quiescent and Sheared Polymer M…
Understanding how entanglements affect the behaviour of polymeric complex fluids is an open challenge in many fields. To elucidate the nature and consequence of entanglements in dense polymer solutions, we propose a novel method: a…
Molecular dynamics simulations are used to investigate the conformations of a single polymer chain, represented by the Kremer-Grest bead-spring model, in a solution with a Lennard-Jones liquid as the solvent when the interaction strength…
What happens when one of the parameters governing the dynamics of a long-range interacting system of particles in thermal equilibrium is abruptly changed (quenched) to a different value? While a short-range system, under the same…
We investigate the molecular origin of shear-thinning in melts of flexible, semiflexible and rigid oligomers with coarse-grained simulations of a sheared melt. Alignment, stretching and tumbling modes or suppression of the latter all…
Shear thickening is a type of non-Newtonian behavior in which the stress required to shear a fluid increases faster than linearly with shear rate. Many concentrated suspensions of particles exhibit an especially dramatic version, known as…
We investigate the behavior of colloidal suspensions with different volume fractions confined between parallel walls under a range of steady shears. We model the particles using molecular dynamics (MD) with full hydrodynamic interactions…
We develop a model in which presence of entanglement in a quantum system can be confirmed through coarse observations of the environment surrounding the system. This counter-intuitive effect becomes possible when interaction between the…
Control of frictional interactions among liquid-suspended particles has led to tunable, strikingly non-Newtonian rheology via the formation of strong flow constraints as particles come into close proximity under shear. Typically, these…
The reversible aggregates formation in a shear thickening, concentrated colloidal suspension is investigated through speckle visibility spectroscopy, a dynamic light scattering technique recently introduced [P.K. Dixon and D.J. Durian,…
As dense granular materials are sheared, a shear band and an anisotropic force network form. The approach to steady state behavior depends on the history of the packing and the existing force and contact network. We present experiments on…
The rheological behavior of ring-linear polymer blends under uniaxial elongational flow has remained a subject of intense debate, particularly regarding the emergence of stress overshoot. Herein, we employ coarse-grained molecular dynamics…
Multiparticle entangled states generated via interaction between narrow-band light and an ensemble of identical two-level atoms are considered. Depending on the initial photon statistics, correlation between atoms and photons can give rise…
Three series of tensile relaxation tests are performed on isotactic polypropylene at room temperature in the vicinity of the yield point. In the first series of experiments, injection-molded samples are used without thermal pre-treatment.…
A temporal response of two interacting particles to a quench of the coupling strength in one-dimensional harmonic and anharmonic traps is explored. The coupling strength is changed from repulsive to attractive interactions and vice versa.…
Observations are reported on isotactic polypropylene (i) in a series of tensile tests with a constant strain rate on specimens annealed for 24 h at various temperatures in the range from 110 to 150 C and (ii) in two series of creep tests in…
In the previous paper, we adopted the method using quantum mutual entropy to measure the degree of entanglement in the time development of the Jaynes-Cummings model. In this paper, we formulate the entanglement in the time development of…
Nonequilibrium molecular dynamics simulations are used to study the shear thinning behavior of immiscible symmetric polymer blends. The phase separated polymers are subjected to a simple shear flow imposed by moving a wall parallel to the…
We provide an analytical investigation of the entanglement dynamics for a system composed of an arbitrary number of qubits dissipating into a common environment. Specifically we consider initial states whose evolution remains confined on…
The shear rate dependence of the slip length in thin polymer films confined between atomically flat surfaces is investigated by molecular dynamics simulations. The polymer melt is described by the bead-spring model of linear flexible…
The effects of entanglement in solutions and melts of unknotted ring polymers have been addressed by several theoretical and numerical studies. The system properties have been typically profiled as a function of ring contour length at fixed…