Related papers: Phase Transitions in "Small" Systems - A Challenge…
Traditionally, phase transitions are defined in the thermodynamic limit only. We discuss how phase transitions of first order (with phase separation and surface tension), continuous transitions and (multi)-critical points can be seen and…
Non-extensive systems do not allow to go to the thermodynamic limit. Therefore we have to reformulate statistical mechanics without invoking the thermodynamical limit. I.e. we have to go back to Pre-Gibbsian times. We show that Boltzmann's…
Boltzmann's principle S(E,N,V)=k\ln W relates the entropy to the geometric area e^{S(E,N,V)} of the manifold of constant energy in the N-body phase space. From the principle all thermodynamics and especially all phenomena of phase…
Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the N-body phase space with the given total energy. Due to Boltzmann's principle,…
The most complicated phenomena of equilibrium statistics, phase separations and transitions of various order and critical phenomena, can clearly and sharply be seen even for small systems in the topology of the curvature of the…
Phase transitions in nuclei, small atomic clusters and self-gravitating systems demand the extension of thermo-statistics to ``Small'' systems. The main obstacle is the thermodynamic limit. It is shown how the original definition of the…
Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the $N-$body phase space with the given total energy. Due to Boltzmann's principle,…
Boltzmann's principle S(E,N,V...)=ln W(E,N,V...) allows the interpretation of Statistical Mechanics of a closed system as Pseudo-Riemannian geometry in the space of the conserved parameters E,N,V... (the conserved mechanical parameters in…
Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the $N-$body phase space with the given total energy. Due to Boltzmann's principle,…
Boltzmann's principle S(E,N,V)=k*ln W(E,N,V) relates the entropy to the geometric area e^{S(E,N,V)} of the manifold of constant energy in the N-body phase space. From the principle all thermodynamics and especially all phenomena of phase…
Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…
Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the N-body phase space with the given total energy. Due to Boltzmann-Planck's principle,…
Equilibrium phase transitions may be defined as nonanalytic points of thermodynamic functions, e.g., of the canonical free energy. Given a certain physical system, it is of interest to understand which properties of the system account for…
This paper presents an in-depth analysis of the anatomy of both thermodynamics and statistical mechanics, together with the relationships between their constituent parts. Based on this analysis, using the renormalization group and…
A geometric foundation thermo-statistics is presented with the only axiomatic assumption of Boltzmann's principle S(E,N,V)=k\ln W. This relates the entropy to the geometric area e^{S(E,N,V)/k} of the manifold of constant energy in the…
It is discussed how phase transitions of first order (with phase separation and surface tension), continuous transitions and (multi)-critical points can be defined and classified for finite systems from the topology of the energy surface…
A new formulation of statistical mechanics is put forward according to which a random variable characterizing a macroscopic body is postulated to be infinitely divisible. It leads to a parametric representation of partition function of an…
We show that under rather general assumptions on the form of the entropy function, the energy balance equation for a system in thermodynamic equilibrium is equivalent to a set of nonlinear equations of hydrodynamic type. This set of…
Equilibrium phase transitions usually emerge from the microscopic behavior of many-body systems and are associated to interesting phenomena such as the generation of long-range order and spontaneous symmetry breaking. They can be defined…
It is shown that the von Neumann entropy, a measure of quantum entanglement, does have its classical counterpart in thermodynamic systems, which we call partial entropy. Close to the critical temperature the partial entropy shows perfect…