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A major advance in density-matrix renormalization group (DMRG) calculations has been achieved by the invention of highly efficient DMRG techniques for the simulation of real-time dynamics of strongly correlated quantum systems in one…

Strongly Correlated Electrons · Physics 2007-05-23 U. Schollwoeck , S. R. White

This paper presents a systematic approach to derive physical bounds for Positive Real (PR) functions directly in the Time-Domain (TD). The theory is based on Cauer's representation of an arbitrary PR function together with associated sum…

Mathematical Physics · Physics 2024-02-08 Sven Nordebo , Martin Stumpf

We present a general method based on nonlinear response theory to obtain effective interactions between ions in an electron gas which can also be applied to other systems where an adiabatic separation of time-scales is possible. Nonlinear…

Materials Science · Physics 2007-10-05 Simon Gravel , N. W. Ashcroft

Electron-positron interactions have been utilized in various fields of science. Here we develop time-dependent multi-component density functional theory to study the coupled electron-positron dynamics from first principles. We prove that…

Chemical Physics · Physics 2018-10-03 Yasumitsu Suzuki , Satoshi Hagiwara , Kazuyuki Watanabe

When ions move through solids, they interact with the solid's constituent atoms and cause them to vibrate around their equilibrium points. This vibration, in turn, modifies the potential landscape through which the mobile ions travel.…

Materials Science · Physics 2024-07-03 A. Rodin , B. A. Olsen , A. Ustyuzhanin , A. Maevskiy , K. Noori

We present an accurate free-energy functional for liquid water written in terms of a set of effective potential fields in which fictitious noninteracting water molecules move. The functional contains an \emph{exact} expression of the…

Soft Condensed Matter · Physics 2011-04-19 Johannes Lischner , T. A. Arias

We present for static density functional theory and time-dependent density functional theory calculations an all-electron method which employs high-order hierarchical finite element bases. Our mesh generation scheme, in which structured…

Materials Science · Physics 2009-08-06 Lauri Lehtovaara , Ville Havu , Martti Puska

We present an accurate local density-functional for electronic-structure calculations within the density functional theory (DFT). The functional is derived by analyzing the structure of the standard perturbative expansion of the correlation…

Materials Science · Physics 2024-11-28 Mario Benites , Angel Rosado , Efstratios Manousakis

Linear response calculations based on the time-dependent density-functional theory are presented. Especially, we report results of the finite amplitude method which we have recently proposed as an alternative and feasible approach to the…

We extend density matrix embedding theory to periodic systems, resulting in an electronic band structure method for solid-state materials. The electron correlation can be captured by means of a local impurity model using various choices of…

Strongly Correlated Electrons · Physics 2019-09-27 Hung Q. Pham , Matthew R. Hermes , Laura Gagliardi

The Thomas-Fermi (TF) approximation for the static dielectric constant of a three-dimensional electron liquid can be derived from minimizing the TF local-density approximation for the kinetic-energy functional. Here we show that this…

Materials Science · Physics 2009-11-11 A. P. Favaro , Joao Vitor Batista Ferreira , K. Capelle

We present an accurate and efficient framework for real-space Hubbard-corrected density functional theory. In particular, we obtain expressions for the energy, atomic forces, and stress tensor suitable for real-space finite-difference…

Computational Physics · Physics 2025-10-20 Sayan Bhowmik , Andrew J. Medford , Phanish Suryanarayana

Dynamical systems often contain oscillatory forces or depend on periodic potentials. Time or space periodicity is reflected in the properties of these systems through a dependence on the parameters of their periodic terms. In this paper we…

Statistical Mechanics · Physics 2015-02-17 Jesús Casado-Pascual , José A. Cuesta , Niurka R. Quintero , Renato Alvarez-Nodarse

Investigating nanoplasmonics using time-dependent approaches permits shedding light on the dynamic optical properties of plasmonic structures, which are intrinsically connected with their potential applications in photochemistry and…

Mesoscale and Nanoscale Physics · Physics 2024-06-18 Piero Lafiosca , Luca Nicoli , Silvio Pipolo , Stefano Corni , Tommaso Giovannini , Chiara Cappelli

Simulating electron-ion dynamics using time-dependent density functional theory within an Ehrenfest dynamics scheme can be done in two ways that are in principle exact and identical: propagating time-dependent electronic Kohn-Sham equations…

Chemical Physics · Physics 2021-07-01 Lionel Lacombe , Neepa T. Maitra

We present an efficient real space formalism for hybrid exchange-correlation functionals in generalized Kohn-Sham density functional theory (DFT). In particular, we develop an efficient representation for any function of the real space…

Computational Physics · Physics 2024-06-26 Xin Jing , Phanish Suryanarayana

We prove that the electron density function of a real physical system can be uniquely determined by its values on any finite subsystem. This establishes the existence of a rigorous density-functional theory for any open electronic system.…

Quantum Physics · Physics 2007-05-23 Xiao Zheng , Fan Wang , GuanHua Chen

We present two methods of calculating the spatial entanglement of an interacting electron system within the framework of density-functional theory. These methods are tested on the model system of Hooke's atom for which the spatial…

Quantum Physics · Physics 2015-03-13 J. P. Coe , A. Sudbery , I. D'Amico

We present a new time-dependent Density Functional approach to study the relaxational dynamics of an assembly of interacting particles subject to thermal noise. Starting from the Langevin stochastic equations of motion for the velocities of…

Statistical Mechanics · Physics 2016-08-31 Umberto Marini Bettolo Marconi , Pedro Tarazona

The Liouville-Lanczos approach to linear-response time-dependent density-functional theory is generalized so as to encompass electron energy-loss and inelastic X-ray scattering spectroscopies in periodic solids. The computation of virtual…

Materials Science · Physics 2015-06-16 Iurii Timrov , Nathalie Vast , Ralph Gebauer , Stefano Baroni