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In this paper we propose a framework allowing to compute the effective interactions between two anisotropic macromolecules, thereby generalizing the DLVO theory to non spherical finite size colloids. We show in particular that the effective…

Soft Condensed Matter · Physics 2009-11-10 David Chapot , Lyderic Bocquet , Emmanuel Trizac

We solve the nonlinear Poisson-Boltzmann equation for two parallel and likely charged plates both inside a symmetric elecrolyte, and inside a 2 : 1 asymmetric electrolyte, in terms of Weierstrass elliptic functions. From these solutions we…

Classical Physics · Physics 2013-05-29 Xiangjun Xing

Interaction between two interpenetrating spherically symmetric charge distributions has been calculated. Limited range terms appear in addition to the Coulomb potential. Its strength increases and range decreases with reducing sizes of the…

Nuclear Theory · Physics 2009-03-20 A. Mukherji

Monopole-like electrostatic interactions are ubiquitous in biology and condensed matter, but they are often screened by counter-ions and cannot be switched from attractive to repulsive. In colloidal science, where the prime goal is to…

Soft Condensed Matter · Physics 2020-01-06 Ye Yuan , Qingkun Liu , Bohdan Senyuk , Ivan I. Smalyukh

The screening of plate-plate interactions by counterions is an age-old problem. We revisit this classic question when counterions exhibit a distribution of charges. While it is expected that the long-distance regime of interactions is…

Statistical Mechanics · Physics 2018-01-08 M. Trulsson , L. Samaj , E. Trizac

We study the charge-density dynamics within the two-dimensional extended Hubbard model in the presence of long-range Coulomb interaction across the metal-insulator transition point. To take into account strong correlations we start from…

Strongly Correlated Electrons · Physics 2014-12-24 E. G. C. P. van Loon , H. Hafermann , A. I. Lichtenstein , A. N. Rubtsov , M. I. Katsnelson

The mechanisms of electrostatic interactions between two charged dielectric spheres inside a polarizable medium have been investigated, in terms of hypothetical effective dipoles that depict how the positive and negative charge in each…

Soft Condensed Matter · Physics 2025-02-06 Yanyu Duan , Zecheng Gan , Ho-Kei Chan

We argue that Coulomb blockade phenomena are a useful probe of the cross-over to strong correlation in quantum dots. Through calculations at low density using variational and diffusion quantum Monte Carlo (up to r_s ~ 55), we find that the…

Mesoscale and Nanoscale Physics · Physics 2009-08-11 A. D. Guclu , A. Ghosal , C. J. Umrigar , H. U. Baranger

We describe a method to simulate the dynamics of charged colloidal particles suspended in a liquid containing dissociated ions and salt ions. Regimes of prime current interest are those of large volume fraction of colloids, highly charged…

Soft Condensed Matter · Physics 2008-01-28 J. Dobnikar , D. Haložan , M. Brumen , H. -H. von Grünberg , R. Rzehak

The bare Coulomb interaction between two like-charges is repulsive. When these charges are immersed in an electrolyte, the thermal fluctuations of the ions turn the bare Coulomb interaction into an effective interaction between the two…

Statistical Mechanics · Physics 2023-03-15 Gabriel Tellez

Interplay of Coulomb interaction energy, free ion entropy, and conformational elasticity is a fascinating aspect in polyelectrolytes (PEs). We develop a theory for complexation of two oppositely charged PEs, a process known to be the…

Soft Condensed Matter · Physics 2022-09-15 Soumik Mitra , Arindam Kundagrami

The spectrum of an exactly solvable non-relativistic system of a charged particle interacting with a quantized electromagnetic mode is studied with various polarizations. Quasiparticle dispersion relations can be derived from the…

Quantum Physics · Physics 2017-06-13 P. Mati

In an attempt to quantify the role of polydispersity in colloidal suspensions, we present an efficient implementation of the renormalized jellium model for a mixture of spherical charged colloids. The different species may have different…

Soft Condensed Matter · Physics 2016-11-23 María Isabel García de Soria , Carlos E. Álvarez , Emmanuel Trizac

We investigate effective interactions between a colloidal particle, immersed in a binary mixture of smaller spheres, and a semipermeable membrane. The colloid is modeled as a big hard sphere and the membrane is represented as an infinitely…

Soft Condensed Matter · Physics 2007-05-23 Pawel Bryk

We derive effective interaction potentials between hard, spherical colloidal particles and star-branched polyelectrolytes of various functionalities and smaller size than the colloids. The effective interactions are based on a…

Soft Condensed Matter · Physics 2007-05-23 M. Konieczny , C. N. Likos

Dipolar interactions govern the structure and dynamics of many soft-matter systems, from molecular to colloids assemblies. When dipole moments are induced by an external field, mutual interactions lead to a many-body magnetization response…

Soft Condensed Matter · Physics 2026-01-30 Lucas H. P. Cunha

Strong coupling phenomena, such as the like charged macroions attraction, opposite charged macroions repulsion, charge renormalization or charge inversion, are known to be mediated by multivalent counterions. Most theories treat the…

Soft Condensed Matter · Physics 2016-02-03 Sandipan Dutta , Y. S. Jho

The structural properties of strongly coupled ions in dense plasmas with moderately to strongly degenerate electrons are investigated in the framework of the one-component plasma model of ions interacting through a screened pair interaction…

Plasma Physics · Physics 2018-09-10 Zh. A. Moldabekov , S. Groth , T. Dornheim , H. Kaehlert , M. Bonitz , T. S. Ramazanov

We study, using Monte Carlo simulations, the interaction between charged colloidal particles confined to the air-water interface. The dependence of force on ionic strength and counterion valence is explored. For 1:1 electrolyte, we find…

Soft Condensed Matter · Physics 2018-02-05 Matheus Girotto , Alexandre P. dos Santos , Yan Levin

Hot, dense plasmas exhibit screened Coulomb interactions, resulting from the collective effects of correlated many-particle interactions. In the lowest particle correlation order (pair-wise correlations), the interaction between charged…

Atomic Physics · Physics 2016-11-29 R. K. Janev , Song Bin Zhang , Jian Guo Wang