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A simple model of the two-state ratchet type is proposed for molecular chemical engines that convert chemical free energy into mechanical work and vice versa. The engine works by catalyzing a chemical reaction and turning a rotor.…

Statistical Mechanics · Physics 2018-05-22 Kazuo Sasaki , Ryo Kanada , Satoshi Amari

An equilibrium reversible cycle with a certain engine to transduce the energy of any chemical reaction into mechanical energy is proposed. The efficiency for chemical energy transduction is also defined so as to be compared with Carnot…

Soft Condensed Matter · Physics 2009-10-30 Tatsuo Shibata , Shin-ichi Sasa

We study the energetics of isothermal ratchets which are driven by a chemical reaction between two states and operate in contact with a single heat bath of constant temperature. We discuss generic aspects of energy transduction such as…

Statistical Mechanics · Physics 2009-10-31 Andrea Parmeggiani , Frank Jülicher , Armand Ajdari , Jacques Prost

Similarly to gear systems in vehicles, most chemical reaction networks (CRNs) involved in energy transduction have at their disposal multiple transduction pathways, each characterized by distinct efficiencies. We conceptualize these…

Molecular Networks · Quantitative Biology 2025-07-24 Massimo Bilancioni , Massimiliano Esposito

We discuss a problem of optimization of the energetic efficiency of a simple rocked ratchet. We concentrate on a low-temperature case in which the particle's motion in a ratchet potential is deterministic. We show that the energetic…

Statistical Mechanics · Physics 2009-10-31 I. M. Sokolov

It is known that an engine with ideal efficiency ($\eta =1$ for a chemical engine and $e = e_{\rm Carnot}$ for a thermal one) has zero power because a reversible cycle takes an infinite time. However, at least from a theoretical point of…

Chemical Physics · Physics 2016-11-22 Jesper Koning , Joseph O. Indekeu

Efficiency of generation of net unidirectional current in an adiabatically driven symmetric periodic potential system is studied. The efficiency shows a maximum, in the case of an inhomogeneous system with spatially varying periodic…

Soft Condensed Matter · Physics 2016-08-31 Debasis Dan , Mangal C. Mahato , A. M. Jayannavar

The energetic efficiencies of rocked ratchets reported in the literature typically lie in the sub-percent range. We discuss the problem of optimization of the energetic efficiency of a ratchet, and show that considerably higher efficiencies…

Statistical Mechanics · Physics 2007-05-23 I. M. Sokolov

In this paper we investigate the use of path-integral formalism and the concepts of entropy and traffic in the context of molecular motors. We show that together with time-reversal symmetry breaking arguments one can find bounds on…

Statistical Mechanics · Physics 2015-05-13 Eliran Boksenbojm , Bram Wynants

We investigate the model of "reversible ratchet" with interacting particles, introduced by us earlier [Europhys. Lett. 84, 50009 (2008)]. We further clarify the effect of efficiency enhancement due to interaction and show that it is of…

Statistical Mechanics · Physics 2015-03-19 Frantisek Slanina

The efficiency of different types of Brownian motors is calculated analytically and numerically. We find that motors based on flashing ratchets present a low efficiency and an unavoidable entropy production. On the other hand, a certain…

Statistical Mechanics · Physics 2009-10-31 J. M. R. Parrondo , J. M. Blanco , F. J. Cao , R. Brito

In thermodynamics, there exists a conventional belief that "the Carnot efficiency is reachable only when a process is reversible." However, there is no theorem proving that the Carnot efficiency is unattainable in an irreversible process.…

Statistical Mechanics · Physics 2017-09-15 Jae Sung Lee , Hyunggyu Park

In this work we include, for the Carnot cycle, irreversibilities of linear finite rate of heat transferences between the heat engine and its reservoirs, heat leak between the reservoirs and internal dissipations of the working fluid. A…

Classical Physics · Physics 2015-06-26 G Aragon-Gonzalez , A. Canales-Palma , A. Leon-Galicia , J. R. Morales-Gomez

Thermal ratchets can extract useful work from random fluctuations. This is common in the molecular scale, such as motor proteins, and has also been used to achieve directional transport in microfluidic devices. In this work, we use the…

Soft Condensed Matter · Physics 2022-11-08 Gouri Patil , Pranay Mandal , Ambarish Ghosh

Vehicle power-trains use a variable transmission (multiple gear-ratios) to minimize motor size and maximize efficiency while meeting a wide-range of operating points. Robots could similarly benefit from variable transmission to save weight…

Robotics · Computer Science 2022-05-31 Alexandre Girard , H. Harry Asada

Molecular motors transduce chemical energy obtained from hydrolizing ATP into mechanical work exerted against an external force. We calculate their efficiency at maximum power output for two simple generic models and show that the…

Statistical Mechanics · Physics 2009-11-13 Tim Schmiedl , Udo Seifert

The aim of this paper is to determine lost works in a molecular engine and compare results with macro (classical) heat engines. Firstly, irreversible thermodynamics are reviewed for macro and molecular cycles. Secondly, irreversible…

Statistical Mechanics · Physics 2021-11-09 Umberto Lucia , Emin Açıkkalp

We consider the transport of rigid objects with internal structure in a flashing ratchet potential by investigating the overdamped behavior of a rod-like chain of evenly spaced point particles. In 1D, analytical arguments show that the…

Statistical Mechanics · Physics 2009-11-11 Erin M. Craig , Martin J. Zuckermann , Heiner Linke

Biomolecular machines transduce free energy from one form to another to fulfill many important roles inside cells, with dissipation required to achieve directed progress. We investigate how to break time-reversal symmetry at a given…

Statistical Mechanics · Physics 2019-07-03 Arshia Zarrin , David A. Sivak , Aidan I. Brown

The Carnot engine sets an upper limit to the efficiency of a practical heat engine. An arbitrary irreversible engine is sometimes believed to behave closely as the Curzon-Ahlborn engine. Efficiency of the latter is obtained commonly by…

Chemical Physics · Physics 2016-06-17 Kamal Bhattacharyya
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