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In this paper, a statistical physical derivation of thermodynamically consistent fluid mechanical equations is presented for non-isothermal viscous molecular fluids. The coarse-graining process is based on (i) the adiabatic expansion of the…

Statistical Mechanics · Physics 2024-04-18 Gyula I. Tóth

The celebrated van der Waals model describes simple fluids in the thermodynamic limit and predicts the existence of a critical point associated to the gas-liquid phase transition. However the behaviour of critical isotherms according to the…

Statistical Mechanics · Physics 2015-05-04 Adriano Barra , Antonio Moro

The general Ericksen-Leslie system for the flow of nematic liquid crystals is reconsidered in the non-isothermal case aiming for thermodynamically consistent models. The non-isothermal model is then investigated analytically. A fairly…

Analysis of PDEs · Mathematics 2015-04-07 Matthias Hieber , Jan Pruess

In this work, the van der Waals fluid model, a diffuse-interface model for liquid-vapor two-phase flows, is numerically investigated. The thermodynamic properties of the van der Waals fluid are first studied. Dimensional analysis is…

Computational Physics · Physics 2018-09-05 Ju Liu

This work presents a pedagogical derivation of the thermodynamics of a van der Waals fluid by explicitly incorporating pairwise molecular interactions and the finite size of particles into the statistical-mechanical description. Starting…

Statistical Mechanics · Physics 2026-01-09 J. L. Cardoso , V. G. Ibarra-Sierra , J. C. Sandoval-Santana , A. Kunold

At thermal equilibrium, intensive quantities like temperature and pressure have to be uniform throughout the system, restricting inhomogeneous systems composed of different phases. The paradigmatic example is the coexistence of vapor and…

Statistical Mechanics · Physics 2021-01-26 Thomas Speck

A class of variational schemes for the hydrodynamic-electrodynamic model of lossless free-electron gas in a quasineutral background is developed for high-quality simulations of surface plasmon polaritons. The Lagrangian density of lossless…

Computational Physics · Physics 2019-02-27 Qiang Chen , Lifei Geng , Xiang Chen , Xiaojun Hao , Chuanchuan Wang , Xiaoyang Wang

In this study, we demonstrate the generalizability of graph neural networks in predicting the dynamic heterogeneity of model glass-forming liquids across different temperatures. While previous approaches have often been limited to making…

Soft Condensed Matter · Physics 2026-03-17 Hidemasa Bessho , Takeshi Kawasaki , Hayato Shiba

Fluctuation-Dissipation Relations (FDR) for a Maxwell fluid are computed via the GENERIC formalism. This formalism is determined by four building blocks, two ``potentials'' (total energy and entropy) and two ``matrices'' which determine the…

Fluid Dynamics · Physics 2007-05-23 F. Vazquez , M. A. Olivares-Robles , S. Delgado

We take up the investigation we left in the future-work stack in Giordano \textit{et al.} [``Fluid statics of a self-gravitational isothermal sphere of van der Waals' gas,'' Phys. Fluids \textbf{36}, 056127 (2024)], in which we pointed out…

Astrophysics of Galaxies · Physics 2025-01-27 Domenico Giordano , Pierluigi Amodio , Felice Iavernaro , Francesca Mazzia

A gaussian distribution of binding energies, but conditioned to exploit generally available information on packing in liquids, provides a statistical-thermodynamic theory of liquid water that is structurally non-committal, molecularly…

Biological Physics · Physics 2007-05-23 J. K. Shah , D. Asthagiri , L. R. Pratt , M. E. Paulaitis

We present a systematic derivation of thermodynamically consistent hydrodynamic phase field models for compressible viscous fluid mixtures using the generalized Onsager principle. By maintaining momentum conservation while enforcing mass…

Numerical Analysis · Mathematics 2018-09-25 Xueping Zhao , Tiezheng Qian , Qi Wang

Based on a rigorous thermodynamic framework, this work develops a two-fluid magnetohydrodynamic model grounded in the Helmholtz free energy formalism. The model maintains full thermodynamic consistency by simultaneously satisfying energy…

Plasma Physics · Physics 2025-11-07 Ting Xiao , Qiaolin He

We develop a unified continuum modeling framework for viscous fluids and hyperelastic solids using the Gibbs free energy as the thermodynamic potential. This framework naturally leads to a pressure primitive variable formulation for the…

Computational Physics · Physics 2020-03-03 Ju Liu , Alison L. Marsden

This paper is concerned with a diffuse interface model for the gas-liquid phase transition. The model consists the compressible Navier-Stokes equations with van der Waals equation of state and a modified Allen-Cahn equation. The global…

Analysis of PDEs · Mathematics 2018-10-02 Qiaolin He , Ming Mei , Xiaoding Shi , Xiaoping Wang

A generalized Van der Waals approach is developed for anisotropic fluids in disordered porous media. As the reference system a hard spherocylinder fluid in a disordered porous medium is considered and described in the framework of the…

Soft Condensed Matter · Physics 2020-03-05 M. F. Holovko , V. I. Shmotolokha

We present a linear, second order fully discrete numerical scheme on a staggered grid for a thermodynamically consistent hydrodynamic phase field model of binary compressible fluid flow mixtures derived from the generalized Onsager…

Numerical Analysis · Mathematics 2019-07-24 Xueping Zhao , Qi Wang

Thermodynamically consistent models for two-phase flow in porous media have attracted significant attention in recent years. In this paper, we prove the existence, uniqueness and regularity of the weak solution to such a recent model…

Analysis of PDEs · Mathematics 2026-02-05 Huangxin Chen , Jisheng Kou , Haitao Leng , Shuyu Sun , Hai Zhao

The properties of dense granular systems are analyzed from a hydrodynamical point of view, based on conservation laws for the particle number density and linear momentum. We discuss averaging problems associated with the nature of such…

Materials Science · Physics 2015-06-24 Clara Saluena , Sergei E. Esipov , Thorsten Poeschel

The presented paper is an attempt to investigate the dynamical states of an hydrodynamical isothermal turbulent self-gravitating system using some powerful tools of the classical thermodynamics. Our main assumption, inspired by the work of…

Astrophysics of Galaxies · Physics 2023-11-21 Sava Donkov , Ivan Zh. Stefanov , Todor V. Veltchev