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A comparative analysis of two concepts aimed at microscopic substantiation of thermodynamics and kinetics has been performed. The first concept is based on the idea of microscopic reversibility of the dynamics of a system of particles,…

Statistical Mechanics · Physics 2024-02-28 A. Yu. Zakharov

Information dynamics is an emerging description of information processing in complex systems which describes systems in terms of intrinsic computation, identifying computational primitives of information storage and transfer. In this paper…

Statistical Mechanics · Physics 2018-10-03 Richard E. Spinney , Joseph T. Lizier , Mikhail Prokopenko

Thermodynamics is based on the notions of energy and entropy. While energy is the elementary quantity governing physical dynamics, entropy is the fundamental concept in information theory. In this work, starting from first principles, we…

Statistical Mechanics · Physics 2017-10-25 Bernhard Altaner

Entropy is one of the key thermodynamic variables reflecting changes in the state of matter. Unlike other thermodynamic variables, it is well-defined also for nonequilibrium steady states through its relation to information. Applying this…

Statistical Mechanics · Physics 2026-04-15 Haim Diamant , Gil Ariel

When a small dynamical system that is initially in contact with a heat bath is detached from this heat bath and then caused to undergo a quasi-static adiabatic processes, the statistical distribution of the system's energy differs from that…

Statistical Mechanics · Physics 2007-05-23 K. Sato , K. Sekimoto , T. Hondou , F. Takagi

A microscopic definition of the thermodynamic entropy in an isolated quantum system must satisfy (i) additivity, (ii) extensivity and (iii) the second law of thermodynamics. We show that the diagonal entropy, which is the Shannon entropy in…

Statistical Mechanics · Physics 2015-03-30 Tatsuhiko N. Ikeda , Naoyuki Sakumichi , Anatoli Polkovnikov , Masahito Ueda

The mechanism of irreversible dynamics in the systems with mixing is analyzed. The procedure of splitting of system on equilibrium subsystems and studying of dynamics of one of them under condition of its interaction with other subsystems…

Statistical Mechanics · Physics 2007-05-23 V. M. Somsikov

There is a relation between the irreversibility of thermodynamic processes as expressed by the breaking of time-reversal symmetry, and the entropy production in such processes. We explain on an elementary mathematical level the relations…

Statistical Mechanics · Physics 2007-05-23 C. Maes , K. Netocny

In stochastic thermodynamics, the entropy production of a thermodynamic system is defined by the irreversibility measured by the logarithm of the ratio of the path probabilities in the forward and reverse processes. We derive the relation…

Statistical Mechanics · Physics 2018-03-14 Hyun-Myung Chun , Jae Dong Noh

Macroscopic many-body systems always exhibit irreversible behaviors together with the entropy increase. However, the underlying microscopic dynamics of the many-body system, either the (quantum) von Neumann or (classical) Liouville…

Statistical Mechanics · Physics 2019-02-04 Sheng-Wen Li

The literature on dynamical systems has, for the most part, considered self-oscillators (i.e., systems capable of generating and maintaining a periodic motion at the expense of an external energy source with no corresponding periodicity)…

Classical Physics · Physics 2017-09-26 Carlos D. Díaz-Marín , Alejandro Jenkins

For macroscopic systems, the second law of thermodynamics establishes an inequality between the amount of work performed on a system in contact with a thermal reservoir, and the change in its free energy. For microscopic systems, this…

Statistical Mechanics · Physics 2010-02-08 Eliran Boksenbojm , Bram Wynants , Christopher Jarzynski

We show that the equations which describe irreversible evolution of a system can be derived from a variational principle. We suggest a Lagrangian, which depends on the properties of the normal and the so-called "mirror-image" system. The…

Statistical Mechanics · Physics 2015-02-10 K. S. Glavatskiy

We examine stochastic processes that are used to model nonequilibrium processes (e.g, pulling RNA or dragging colloids) and so deliberately violate detailed balance. We argue that by combining an information-theoretic measure of…

Statistical Mechanics · Physics 2009-11-13 R. A. Blythe

Time-asymmetric behavior as embodied in the second law of thermodynamics is observed in {\it individual macroscopic} systems. It can be understood as arising naturally from time-symmetric microscopic laws when account is taken of a) the…

Statistical Mechanics · Physics 2007-09-06 Joel L. Lebowitz

Understanding how biological homochirality emerged remains a challenge for the researchers interested in the origin of life. During the last decades, stable non-racemic steady states of nonequilibrium chemical systems have been discussed as…

Biomolecules · Quantitative Biology 2010-06-15 Raphael Plasson , Hugues Bersini

We discuss the reversible-irreversible transition in low-Reynolds hydrodynamic systems driven by external cycling actuation. We introduce a set of models with no auto-organisation, and show that a sharp crossover is obtained between a…

Statistical Mechanics · Physics 2008-12-11 Gustavo During , Denis Bartolo , Jorge Kurchan

Active systems evade the rules of equilibrium thermodynamics by constantly dissipating energy at the level of their microscopic components. This energy flux stems from the conversion of a fuel, present in the environment, into sustained…

Soft Condensed Matter · Physics 2022-03-15 Étienne Fodor , Robert L. Jack , Michael E. Cates

On the standard microscopic model of friction we confirm the common belief that the irreversible entropy production originates from the increase of Shannon information. We reveal that the reversible microscopic dynamics would continuously…

Chemical Physics · Physics 2016-09-08 Lajos Diosi

In this contribution we prove that the entropy of an N-body isolated system can not decrease and the entropy production should be non-negative provided the system possesses an equilibrium state. We define the entropy as a functional of the…

Statistical Mechanics · Physics 2007-05-23 A. Perez-Madrid