Related papers: Formation of Interstellar Ices Behind shock Waves
We present the modeling results of deuterium fractionation of water ice, H2, and the primary deuterium isotopologues of H3+ adopting physical conditions associated with the star and planet formation process. We calculated the deuterium…
The reactivity of interstellar carbon atoms (C) on the water-dominated ices is one of the possible ways to form interstellar complex organic molecules (iCOMs). In this work, we report a quantum chemical study of the coupling reaction of C…
Many interstellar complex organic molecules (COMs) are believed to be produced on the surfaces of icy grains at low temperatures. Atomic carbon is considered responsible for the skeletal evolution processes, such as C-C bond formation, via…
Computational models of interstellar gas-grain chemistry have historically adopted a single dust-grain size of 0.1 micron, assumed to be representative of the size distribution present in the interstellar medium. Here, we investigate the…
Deposition of water on aerosol particles contributes to ice cloud formation in the atmosphere with implications for the water cycle and climate on Earth. The heterogeneous ice nucleation process is influenced by physico-chemical properties…
We investigate the evolution of grains composed of an ice shell surrounding an olivine core as they pass through a spiral shock in a protoplanetary disk. We use published three-dimensional radiation-hydrodynamics simulations of massive…
A brief introduction and overview of the astrochemistry of dust, ice and gas and their interplay is presented, aimed at non-specialists. The importance of basic chemical physics studies of critical reactions is illustrated through a number…
Formation and evolution of water in the Solar System and the origin of water on Earth constitute one of the most interesting questions in astronomy. The prevailing hypothesis for the origin of water on Earth is by delivery through…
Water is detected in environments representing every stage of star and solar system formation, but its chemical evolution throughout these stages remains poorly constrained. Deuterium ratios offer a means of probing chemical links between…
The life-cycle of cosmic dust grains is far from being understood and the origin and evolution of interstellar medium (ISM) grains is still under debate. In the ISM, the cosmic dust destruction rate is faster than the production rate by…
The processes that govern the evolution of dust and water (in the form of vapor or ice) in protoplanetary disks are intimately connected. We have developed a model that simulates dust coagulation, dust dynamics (settling, turbulent mixing),…
Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…
The wavelength dependences of interstellar extinction and polarization, supplemented by observed elemental abundances and the spectrum of infrared emission from dust heated by starlight, strongly constrain dust models. One dust model that…
The observed gas-phase molecular inventory of hot cores is believed to be significantly impacted by the products of chemistry in interstellar ices. In this study, we report the construction of a full macroscopic Monte Carlo model of both…
A new mechanism for the formation of cometary tails behind dense clouds or globules is discussed. Numerical hydrodynamical models show that when a dense shell of swept-up matter overruns a cloud, material in the shell is focussed behind the…
Identifying the source of Earth's water is central to understanding the origins of life-fostering environments and to assessing the prevalence of such environments in space. Water throughout the solar system exhibits deuterium-to-hydrogen…
The formation of interstellar water has been commonly accepted to occur on the surfaces of icy dust grains in dark molecular clouds at low temperatures (10-20 K), involving hydrogenation reactions of oxygen allotropes. As a result of the…
The deuterium enrichment in molecules in dark molecular cloud cores and starforming regions is usually attributed to gas-phase chemistry. Here we examine the effects of surface and mantle chemical reactions on the deuteration of species. We…
We investigate the thermal and dynamical evolution of primordial gas clouds in the universe after decoupling. Comparing the time-scale of dynamical evolution with that of fragmentation, we can estimate the typical fragmentation scale. We…
For the first time, we report a unified microscopic-macroscopic Monte Carlo simulation of gas-grain chemistry in cold interstellar clouds in which both the gas-phase and the grain surface chemistry are simulated by a stochastic technique.…