Related papers: Towards a Solution of the Polycyclic Aromatic Hydr…
The chemistry of astronomical hydrocarbons, responsible for the well-known infrared emission features detected in a wide variety of targets, remains enigmatic. Here we focus on the group of young intermediate-mass Herbig Ae stars. We have…
We examine polycyclic aromatic hydrocarbon (PAH), dust and atomic/molecular emission toward the Galactic bulge using Spitzer Space Telescope observations of four fields: C32, C35, OGLE and NGC 6522. These fields are approximately centered…
We map the distribution and properties of the Milky Way's interstellar medium as traced by diffuse interstellar bands (DIBs) detected in near-infrared stellar spectra from the SDSS-III/APOGEE survey. Focusing exclusively on the strongest…
We report the first spectroscopic observations of a background star seen through the region between the ionization front and the dissociation front of the nebula IC 63. This photodissociation region (PDR) exhibits intense extended red…
We divide some of the observed diffuse interstellar bands (DIBs) into families which appear to have spectral structures of single species. Three different methods are applied to separate such families, exploring the best approach for future…
The gas-phase abundances of deuterium (D) in the local interstellar medium (ISM) exhibit considerable regional variations. Particularly, in some regions the gas-phase D abundances are substantially lower than the primordial D abundance…
Deuterium (D) was exclusively generated in the Big Bang and the standard Big Bang Nucleosynthesis (BBN) model predicts a primordial abundance of D/H~26ppm. As the Galaxy evolves, D/H gradually decreases because of astration. The Galactic…
Interstellar space hosts nanometre- to micron-sized dust grains. The carbonaceous-rich component of these grain populations emits in infrared bands, observed remotely for decades with telescopes and satellites. They are a key ingredient of…
Large fullerenes and fullerene-based molecules have been proposed as carriers of diffuse interstellar bands (DIBs). The recent detection of the most common fullerenes (C60 and C70) around some planetary nebulae (PNe) now enable us to study…
We present the synthesis and laboratory rotational spectroscopy of the 7-ring polycyclic aromatic hydrocarbon (PAH) cyanocoronene (C$_{24}$H$_{11}$CN) using a laser-ablation assisted cavity-enhanced Fourier transform microwave spectrometer.…
The detection of a new 16.4 micron emission feature in the ISO-SWS spectra of NGC 7023, M17, and the Orion Bar is reported. Previous laboratory experiments measured a mode near this wavelength in spectra of PAHs (Polycyclic Aromatic…
Analysis of high spectral resolution observations of the $\lambda$6614 diffuse interstellar band (DIB) line profile show systematic variations in the positions of the peaks in the substructure of the profile. These variations -- shown here…
Mid-infrared (IR) observations of polycyclic aromatic hydrocarbons (PAHs) and molecular hydrogen emission are a potentially powerful tool to derive physical properties of dense environments irradiated by intense UV fields. We present new,…
We investigate the emission properties of polycyclic aromatic hydrocarbons (PAHs) in various metallicity environments with the Infrared Spectrograph on board Spitzer. Local giant HII regions are used as references as they enable access to…
The carriers of the diffuse interstellar bands (DIBs) still remain an unknown commodity. Both dust and molecules have been suggested as carriers but none proposed have yet been able to explain the nature and the diversity of the DIBs.…
In this brief review of recent work relating the DIBs to other gas-phase constituents of the ISM, we explore correlations between DIB equivalent widths and the column densities of various atomic and molecular species, drawn from a large…
Despite its biogeneic and astrochemical importance, sulfur (S), the 10th most abundant element in the interstellar medium (ISM) with a total abundance of S/H~2.2E-5, largely remains undetected in molecular clouds. Even in the diffuse ISM…
The aromatic infrared bands (AIBs) observed in the mid infrared spectrum are attributed to Polycyclic Aromatic Hydrocarbons (PAHs). We observe the NGC 7023-North West (NW) PDR in the mid-infrared (10 - 19.5 micron) using the Infrared…
Using the Mid-Infrared Spectrometer on board the Infrared Telescope in Space and the low-resolution grating spectrometer (PHT-S) on board the Infrared Space Observatory, we obtained 820 mid-infrared (5 to 12 $\mu$m) spectra of the diffuse…
The nature of the Diffuse Interstellar Band (DIB) carriers is perhaps the most studied, longest standing, unresolved problem in astronomy. While four bands have been associated with the fullerene cation (C^+_60) the vast majority (> 550)…